Rapid Analysis of 1,4‐Dioxane in Groundwater by Frozen Micro‐Extraction with Gas Chromatography/Mass Spectrometry

An innovative micro‐extraction of aqueous samples coupled with gas chromatography/mass spectrometry in selected ion‐monitoring mode (GC/MS‐SIM) was developed to selectively analyze for 1,4‐dioxane with low part‐per‐billion detection sensitivity. Recoveries of 1,4‐dioxane ranged from 93% to 117% for both spiked laboratory reagent water and natural groundwater matrices, the later having elevated organic carbon content (8.34 ± 0.31 mg/L as total organic carbon). We observed that freezing the aqueous sample along with the extraction solvent enhanced the extraction efficiency, minimized physical interferences, and improved sensitivity resulting in a limit of detection for 1,4‐dioxane to approximately 1.6 μg/L. This method substantially reduces the labor, time, reagents and cost, and uses instruments that are commonly found in analytical laboratories. This method requires a relatively small sample volume (200 μL), and can be considered a green analytical method as it minimizes the use of toxic solvents and the associated laboratory wastes.     

Multi-method assessment of connectivity between surface water and shallow groundwater: the case of Limarí River basin,north-central Chile

A study that tests the applicability and consistency of independent but complementary approaches in the assessment of interactions between surface water and shallow groundwater within a water-stressed basin is described. The mostly agricultural Limarí basin in arid north-central Chile was chosen as a suitable case study. The analyses involved: (1) a connectivity index method, (2) hydrochemistry, and (3) water isotopic geochemistry. Chemical and isotopic data were obtained from two sampling campaigns conducted in April (fall) and December (summer) of 2011 in 22 sampling locations, which included surface water and groundwater. The results obtained by each of the methodologies were mutually consistent and indicate high connectivity conditions. Additionally, the relative contribution by different sources was assessed through end-member mixing analysis, and for reaches of the river that showed gaining conditions, the contribution of groundwater inflow to stream discharge was estimated. It is suggested that this multi-method approach is useful for the characterization of surface-water–groundwater interactions, since it at least represents a suitable starting point for obtaining basic information on these relationships. Thus, it may become the base for further studies in arid and semi-arid basins facing water management challenges.     

Radiological characterization of granitoid outcrops and dimension stones of the Variscan Corsica-Sardinia Batholith

This study focuses on the radiological characterization of granitoid outcrops and dimension stones using in situ gamma-ray spectrometry. Extensive measurements were performed on 210 granitoid outcrops of the Corsica-Sardinia Batholith. The large statistical sample allowed us to improve the analysis by considering a log-normal distribution of radioelements and propagating the uncertainties using Monte Carlo method. The activity concentrations of ⁴⁰K, ²²⁶Ra (²³⁸U) and ²³²Th in C-SB area were 1,177 _?304 ⁺⁴⁰⁸ , 60 _?23 ⁺³⁶ and 69 _?25 ⁺³⁸  Bq/kg (at 1σ uncertainty). The median abundance of K, U and Th on the Variscan C-SB was higher than the average values of the upper continental crust and was comparable with Variscan belt. This corresponds to an outdoor absorbed dose rate of 124 _?26 ⁺³³  nGy/h at 1σ uncertainty which is 3σ higher than the population-weighted average absorbed dose rate (60 nGy/h). Seven commercial granites (Rosa Beta, Ghiandone, Giallo San Giacomo, Rosa Cinzia, Grigio Malaga, Bianco Sardo and Grigio Perla) were investigated to characterize their radiological hazard through 147 measurements taken in 73 extractive quarries. All of the commercial granites were categorized as A2 material based on their activity concentration indices, excluding (at the 3σ level) any restriction on their utilization as superficial materials. Rosa Beta, Grigio Malaga, Grigio Perla and Bianco Sardo can also be used as bulk materials as they can be included in the A1 category. In the case of Ghiandone, Giallo San Giacomo and Rosa Cinzia, we are confident of an A1 classification only at the 1σ level.     

Constraints on Jupiters from observations of Galactic bulge microlensing events during 2000

We present observations of eight Galactic bulge microlensing events taken with the 1.0-m Jacobus Kapteyn Telescope (JKT) on La Palma during 2000 June and July. The JKT observing schedule was optimized using a prioritizing algorithm to automatically update the target list. For most of these events we have sampled the light curves at times where no information was available from the OGLE alert team. We assume a point-source point-lens (PSPL) model and perform a maximum likelihood fit to both our data and the OGLE data to constrain the event parameters of the fit. We then refit the data assuming a binary lens and proceed to calculate the probability of detecting planets with mass ratio   q = 10⁻³  . We have seen no clear signatures of planetary deviations on any of the eight events and we quantify constraints on the presence of planetary companions to the lensing stars. For two well-observed events, 2000BUL31 and 2000BUL33, our detection probabilities peak at ∼30 and ∼20 per cent respectively for   q = 10⁻³  and   a ∼ R _E  for a  Δχ²  threshold value of 60.     

Future changes of hot extremes in Spain: towards warmer conditions

Natural Hazards - One of the most relevant effects of climate change is its influence on the frequency and intensity of extreme events. The analysis and understanding of these events are of great...     

Late Chiribaya agriculture and risk management along the arid Andean coast of southern Perú, A.D. 1200–1400

Recent investigations at the coastal spring site of Wawakiki in southern Perú have identified an intensive, late pre‐Hispanic agricultural production strategy along a sea cliff some 30 km north of the Ilo River. Excavations identified buried stone‐faced agricultural terraces underlying Spanish colonial and post‐colonial furrows, and long irrigation canals that transported water along steep hill slopes from inland springs. Depositional patterns, cultural debris, and calibrated radiocarbon age ranges suggest the site was farmed most intensively between A.D. 1200 and 1400, a period characterized by prolonged highland drought and recurrent El Niño–induced floods in southern Perú. Farmers transformed this arid coastal promontory into a productive agricultural landscape by exploiting multiple spring sources, steep canals, and stone‐faced terraces in an area where water is a very limited commodity and steep barren hills are highly prone to erosion. Furthermore, high‐relief terrain left much of the agricultural infrastructure well protected from periodic floods. © 2005 Wiley Periodicals, Inc.     

Method for determining dust particle density above the ecliptic plane

A new method for the determination of the particles density variation, with the altitude above the symmetry plane of interplanetary dust from earth-bound measurements is described.     

CLAIRE: First light for a gamma-ray lens

The objective of the R&D project CLAIRE was to prove the principle of a gamma-ray lens for nuclear astrophysics. CLAIRE's Laue diffraction lens has a diameter of 45 cm and a focal length of 277 cm; 556 germanium-silicon crystals are tuned to focus 170 keV photons onto a 1.5 cm diameter focal spot. Laboratory measurements of the individual crystals and the entire lens have been used to validate a numerical model that we use to estimate the lens performance for a source at infinity. During a stratospheric balloon flight on 2001 June 14, CLAIRE was directed at the Crab nebula by a pointing system able to stabilize the lens to within a few arcseconds of the target. In 72 min of valid pointing time, 33 photons from the Crab were detected in the 3 keV bandpass of the lens: CLAIRE's first light! The performance of CLAIRE's gamma-ray lens, namely the peak reflectivity for a polychromatic source (9±1%), has been confirmed by ground data obtained on a 205 meter long test range. CLAIRE's measured performance validates the principle of a Laue lens for nuclear astrophysics, opening the way for a space-borne gamma-ray lens telescope that will achieve one to two orders of magnitude improvement in sensitivity over present technologies.     

Heliographic longitude distribution of the flares associated with type III bursts observed at kilometric wavelengths

We have grouped observed type III solar bursts according to the discrete frequencies of observation in the kilometric wavelength range. For each group we have obtained the bursts' frequency of occurrence as a function of the heliographic longitude of the associated optical flares. We found that flares occurring east of a certain cutoff longitude do not produce bursts observable near the earth below a given frequency. The cutoff on the west is determined by observational limitation for flares beyond the limb. The mean longitude and the extreme eastern end of the longitude distribution both shift to the west as the radio frequency decreases. We interpret these findings in terms of radio wave propagation effects and curved trajectories of the bursts' exciter particles.