GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.     

Structural similarity and variety at the tips in a wide range of strike–slip faults: a review

Strike–slip faults are often accompanied by a variety of structures, particularly at their tips. The zones of additional fracturing are classified as tip‐damage zones. These zones can be subdivided into several different damage patterns based on the nature and orientation of faults and fractures developed. Damage zones at the ends of small strike–slip faults (mode II tips) develop wing cracks, horsetail splays, antithetic faults, synthetic branch faults and solution surfaces. Similar tip‐damage patterns are also commonly observed at larger (regional) scales, but with a dominance of faulting over tensile cracks and solution surfaces. Wing cracks and horsetail splays developed at small‐scale faults are replaced by normal faults in large‐scale faults. Antithetic faults and synthetic branch faults are observed at small and large scales. Thrust faults are developed at large scales, in a similar pattern to solution surfaces at a small scale. All these structures may show slightly different angular relationships to the master fault at small and large scale, but develop in response similar stress distribution and mechanics around the fault. Thus, mode II tip‐damage zones show similar patterns over a wide range of fault scales.     

Estimation of surface roughness (z0) over a stabilizing coastal dune field based on vegetation and topography

Accurate knowledge of the surface roughness and the resultant wind speed are important for many applications, such as climatic models, wind power meteorology, agriculture and erosion hazards, especially on sand dunes in arid and semi‐arid environments, where vegetation cover is scarce. In this study we aimed at quantifying the effects of vegetation cover and topography on surface roughness over a stabilizing dune field on the southern coast of Israel. Forty‐six wind measurements were made at various distances from the coastline, ranging from 10 to 2800 m, and z₀ values were calculated from the wind measurements based on the ratio between the wind gust and the average wind speed. We estimated vegetation cover using the soil adjusted vegetation index (SAVI) from Landsat satellite images for the upwind sector at various lengths, ranging from 15 to 400 m, and based on digital elevation models and differential GPS field measurements we calculated the topographic variable of the relative heights of the stations. z₀ values were positively correlated with the winter SAVI values (r = 0·87 at an upwind length of 200 m) and negatively correlated with the relative height (r = ?0·68 at an upwind length of 200–400 m for the inland dune stations). Using these variables we were able to create a map of estimated z₀ values having an accuracy of over 64%. Such maps provide a better understanding of the spatial variability in both wind speed and sand movement over coastal dune areas. Copyright © 2007 John Wiley & Sons, Ltd.     

Evaluation of Sludge Digester Effluent as Feeding Solution for the Enrichment of Anammox Bacteria

The aim of this study is to evaluate the feasibility of sludge digester effluent as feeding solution to enrich anaerobic ammonium oxidation (anammox) bacteria. The performance of the two parallel pilot scale‐upflow packed bed anammox reactors (UPBAn1 and UPBAn2) are examined in terms of the enrichment of anammox bacteria. The control experiment is set up conducting synthetic wastewater as feeding solution in the UPBAn1 reactor whereas, the sludge digester effluent is fed to the nitritation reactor and then the partially nitrated digester effluent to the UPBAn2 reactor. Anammox activities are evaluated by mass balances based on ammonium (NH₄⁺), nitrite (NO₂^?), and nitrate (NO₃^?) analysis and NRR. Microbial community of anammox bacteria is analyzed using real‐time polymerase chain reaction (PCR). The results demonstrate that UPBAn 1 and UPBAn2 reactors are successfully enriched on days 64 and 40 with NRRs of 19.54 and 19.43 g N m^?3 per day, respectively. This study reveals that both synthetic wastewater and digester effluent are suitable for the enrichment of anammox bacteria; however, digester effluent as feeding solution for enrichment of anammox bacteria based on the ease of process control and process stability is more advisable.     

A semi‐distributed parallel‐type linear reservoir rainfall‐runoff model and its application in Taiwan

The main purpose of this paper is to introduce a semi‐distributed parallel surface rainfall‐runoff conceptual model. In this paper, a general solution of the instantaneous unit hydrograph (IUH) has been derived successfully for N linearly connected reservoirs, each having a different storage constant. The solution is a function of geomorphologic parameters, meteorologic factors and roughness coefficients. The model also takes into account the hydrologic response which is influenced by outflow downstream of a reservoir. For calibration, the shuffled complex evolution (SCE) algorithm is used to search for the global optimal parameters of the model. Because of the parallel structure, the mean roughness parameter of the channel becomes a “conceptual” parameter without a real physical meaning. To evaluate the adaptability of the model adopted, three watersheds around the city of Taipei in Taiwan were chosen to test the effectiveness of the model. The study provides an appropriate rainfall‐runoff model for planning flood mitigation in Taiwan. Copyright © 1999 John Wiley & Sons, Ltd.     

Identification of modal parameters of non‐classically damped linear structures under multi‐component earthquake loading

A method for parametric system identification of classically damped linear system in frequency domain is adopted and extended for non‐classically damped linear systems subjected up to six components of earthquake ground motions. This method is able to work in multi‐input/multi‐output (MIMO) case. The response of a two‐degree‐of‐freedom model with non‐classical damping, excited by one‐component earthquake ground motion, is simulated and used to verify the proposed system identification method in the single‐input/multi‐output case. Also, the records of a 10 storey real building during the Northridge earthquake is used to verify the proposed system identification method in the MIMO case. In this case, at first, a single‐input/multi‐output assumption is considered for the system and modal parameters are identified, then other components of earthquake ground motions are added, respectively, and the modal parameters are identified again. This procedure is repeated until all four components of earthquake ground motions which are measured at the base level of the building are included in the identification process. The results of identification of real building show that consideration of non‐classical damping and inclusion of the multi‐components effect of earthquake ground motions can improve the least‐squares match between the finite Fourier transforms of recorded and calculated acceleration responses. Copyright © 2006 John Wiley & Sons, Ltd.     

Analysis of the weightiness of site effects on reinforced concrete (RC) building seismic behaviour: The Adra town example (SE Spain)

The damage distribution in Adra town (south‐eastern Spain) during the 1993 and 1994 Adra earthquakes (5.0 magnitude), that reached a maximum intensity degree of VII (European Macroseismic Scale (EMS scale)), was concentrated mainly in the south‐east zone of the town and the most relevant damage occurred in reinforced concrete (RC) buildings with four or five storeys. In order to evaluate the influence of ground condition on RC building behaviour, geological, geomorphological and geophysical surveys were carried out, and a detailed map of ground surface structure was obtained. Short‐period microtremor observations were performed in 160 sites on a 100m × 100m dimension grid and Nakamura's method was applied in order to determine a distribution map of soil predominant periods. Shorter predominant periods (0.1–0.3 s) were found in mountainous and neighbouring zones and larger periods (greater than 0.5 s) in thicker Holocene alluvial fans. A relationship T = (0.049 ± 0.001)N, where T is the natural period of swaying motion and N is the number of storeys, has been empirically obtained by using microtremor measurements at the top of 38 RC buildings (ranging from 2 to 9 storeys). 1‐D simulation of strong motion on different soil conditions and for several typical RC buildings were computed, using the acceleration record in Adra town of the 1993 earthquake. It is noteworthy that all the aforementioned results show the influence of site effects in the degree and distribution of observed building damage. Copyright © 2007 John Wiley & Sons, Ltd.