Modeling Seismic Attributes of Pn Waves using the Spectral-Element Method

To investigate the nature of Pn propagation, we have implemented the spectral-element method (SEM) for vertically and laterally varying media with and without attenuation. As a practical measure, essential features of the Pn waves are distilled into seismic attributes including arrival times, amplitudes and pulse frequencies. To validate the SEM simulations, we first compare the SEM results with reflectivity calculations of Braile and Smith (Geophys. J.R. Astr. Soc. 40, 145–176, 1975) and then to the asymptotic results of ?erveny and Ravindra (Theory of Seismic Headwaves, University of Toronto Press, pp. 235–250, 1971). Models with random, laterally varying Moho structures are then simulated, where the amplitude and pulse frequency characteristics are found to be stable to small Moho interface perturbations. SEM calculations for models with different upper-mantle velocity gradients are next performed where it is found that interference effects can strongly influence the Pn amplitudes and pulses frequencies. For larger-scale, laterally varying structures, SEM models similar to that found along the Hi-CLIMB array in Tibet are then performed. It is observed that large-scale structures, along with small-scale structures, upper-mantle velocity gradients and attenuation, can all significantly affect the Pn attributes. Ambiguities between upper-mantle velocity gradients and attenuation are also found when using Pn amplitudes and pulse frequency attributes. These ambiguities may be resolved, to some degree, by using the curvature of the travel times at longer regional distance, however, this would also be complicated by lateral variability.     

Zircon U-Pb geochronology and geochemistry of Late Devonian–Carboniferous granitoids in NW Iran: implications for the opening of Paleo-Tethys

ABSTRACT

We present zircon U-Pb crystallization ages combined with bulk rock major and trace element geochemistry and Sr-Nd-Pb and zircon in-situ Hf isotopic compositions of the Amand and Moro granitoid intrusions in northwest Iran. The Amand and Moro plutons include granite and syeno-diorite with LA-ICP-MS U-Pb zircon ages of 367 ± 6.8 Ma and 351 ± 1.3 Ma, respectively, representative of Late Devonian-Early Carboniferous magmatic activity in NW Iran. Geochemical characteristics such as typical enrichments in alkalis, Nb, Zr, Ga and Y, depletion in P and Sr and fractionated REE patterns with high Ga/Al ratios and Eu negative anomalies are consistent with A-type magmatic signatures. The granitoids are classified as A₂-type and within-plate granitoids. The bulk rock geochemistry (enrichments in Th, Nb and, high Th/Yb, Zr/Y ratios) along with low variation of ¹⁴³Nd/¹⁴⁴Nd_(i) and ⁸⁷Sr/⁸⁶Sr_(i) ratios and positive zircon εHf_(t) support the role of a mantle plume component for the evolution of the Amand and Moro A-type granitoids in an extensional tectonic environment. In fitting with wider regional knowledge, this magmatism occurred during Paleo-Tethys opening in northern Gondwana.     

Prediction of riverine suspended sediment discharge using fuzzy logic algorithms, and some implications for estuarine settings

The ability of fuzzy logic algorithms to model relationships between stream flow and suspended sediment discharge was investigated using daily measurements of stream flow and suspended sediment discharge for the Escanaba River mouth station, situated on the shore of Lake Michigan and operated by the US Geological Survey. Three different configurations of inputs were applied, whereby the inputs were fuzzified into fuzzy subsets of variables by means of triangular membership functions. The relationships between inputs and suspended sediment discharge (output) were represented by a set of fuzzy rule expressed in IF–THEN format. The weighted average method served for defuzzification. The commonly used sediment rating curve was also applied to the data, and its performance compared with that of the three models by means of statistical analyses. For all three models, suspended sediment discharge predicted by the fuzzy logic algorithm was in satisfactory agreement with observations. Furthermore, the fuzzy logic algorithms performed better than the sediment rating curve, particularly at higher rates of suspended sediment discharge (in this study, more than 50  × 10⁶ g/day). Considered collectively, the use of fuzzy logic algorithms is suggested as a simple and effective approach for better prediction of suspended sediment discharge, also for estuaries.     

Composition, porosity, and reservoir potential of the Middle Jurassic Kashafrud Formation, northeast Iran

In the Kopet-Dagh Basin of Iran, deep-sea sandstones and shales of the Middle Jurassic Kashafrud Formation are disconformably overlain by hydrocarbon-bearing carbonates of Upper Jurassic and Cretaceous age. To explore the reservoir potential of the sandstones, we studied their burial history using more than 500 thin sections, supplemented by heavy mineral analysis, microprobe analysis, porosity and permeability determination, and vitrinite reflectance.The sandstones are arkosic and lithic arenites, rich in sedimentary and volcanic rock fragments. Quartz overgrowths and pore-filling carbonate cements (calcite, dolomite, siderite and ankerite) occluded most of the porosity during early to deep burial, assisted by early compaction that improved packing and fractured quartz grains. Iron oxides are prominent as alteration products of framework grains, probably reflecting source-area weathering prior to deposition, and locally as pore fills. Minor cements include pore-filling clays, pyrite, authigenic albite and K-feldspar, and barite. Existing porosity is secondary, resulting largely from dissolution of feldspars, micas, and rock fragments, with some fracture porosity. Porosity and permeability of six samples averages 3.2% and 0.0023 mD, respectively, and 150 thin-section point counts averaged 2.7% porosity. Reflectance of vitrinite in eight sandstone samples yielded values of 0.64-0.83%, in the early mature to mature stage of hydrocarbon generation, within the oil window.Kashafrud Formation petrographic trends were compared with trends from first-cycle basins elsewhere in the world. Inferred burial conditions accord with the maturation data, suggesting only a moderate thermal regime during burial. Some fractures, iron oxide cements, and dissolution may reflect Cenozoic tectonism and uplift that created the Kopet-Dagh Mountains. The low porosity and permeability levels of Kashafrud Formation sandstones suggest only a modest reservoir potential. For such tight sandstones, fractures may enhance the reservoir potential.     

Textural evidences for dissolution of silica-rich rocks of the Ypresian phosphatic series,Gafsa-Metlaoui basin,southwestern Tunisia: implication of biogenic silica supply on genesis of fibrous clays

The present work aimed to determine the mineralogical composition of Ypresian series and to clarify the influence of the dissolution of siliceous frustules on the genesis of fibrous clay minerals. The specimens sampled from CPG trench are mainly constituted of silica-rich rocks at Mides area located at the western part of Gafsa-Metlaoui basin. The samples were investigated using X-ray diffraction (XRD) and scanning electron microscopy (SEM) in order to determine texture of constituents. The data obtained indicate that the bulk rock samples are mainly made up of opal CT and clay minerals. The latter consists of palygorskite-sepiolite minerals associated with smectite and few amount of illite. The trend of mineralogical composition indicates that fibrous clay minerals are more concentrated at the upper part. SEM observations indicated that palygorskite mineral appears as thread-like facies, which surround foliated texture of smectite in the lower part of the Mides section, although with the low Mg activity confirmed by the absence of dolomite. But, at the upper part of the Mides section, SEM observations revealed the occurrence of siliceous frustules, which have numerous dissolved areas and replacement of carbonate tests by silica. The dissolution saturated the depositional environment with silica which is required for the formation of palygorskite and sepiolite minerals, in addition to high Mg activity confirmed by the presence of dolomite in the bulk rock, which is required basically for the formation of sepiolite. Although the genesis mode of palygorskite and sepiolite is similar with very little difference, the genesis of sepiolite needs a high alkalinity than the formation of palygorskite.     

Metals removal during estuarine mixing of Arvand River water with the Persian Gulf water

In the present study, the removal of dissolved and colloidal Cd, Co, Cu, Ni and Zn in Arvand River water during estuarine mixing with the Persian Gulf water is investigated. The flocculation process was investigated for a series of mixtures with salinities ranging from 0.48 to 30.3^. The flocculation rates were indicative of the non-conservative behavior of studied metals during estuarine mixing. Rapid flocculation in the low salinity regimes was observed. The order of the final flocculation rate of metals in the river water was as follows: Co (91.2%)> Cd (86.9%)> Zn (83%)> Cu (75.2%)> Ni (74.3%). Salinity, pH, EC and dissolved oxygen do not govern the flocculation of metals during estuarine mixing. The results of the present investigation show that estuarine processes can be considered as an effective mechanism in self purification of colloidal metals that are anthropogenically introduced into the fresh water ecosystem.     

Impacts of Depositional Facies and Diagenesis on Reservoir Quality: A Case Study from the Rudist-bearing Sarvak Formation, Abadan Plain, SW Iran

An integrated geological-petrophysical analysis of the rudist-bearing sequence of the Cretaceous Sarvak Formation is given one giant oilfield, and provides an improved understanding of this main reservoir in the Abadan Plain, in the Zagros Basin, SW Iran. The main objective of this study is to evaluate reservoir potential of the Sarvak Formation, and then to utilize the calibrated well log signature to correlate reservoir potential in un-cored wells. Eight main facies are recognized and categori...     

Travel time based approach for the assessment of vulnerability of karst groundwater: the Transit Time Method

Karst aquifers represent important water resources in many parts of the world. Unfortunately, karst aquifers are characterised by high contamination risks. This paper presents a travel time based method for the estimation of karst groundwater vulnerability. It considers (1) physics-based lateral flow within the uppermost weathered zone (epikarst) in a limestone-dominated region and (2) high velocities of vertical infiltration at discrete infiltration points (e.g. sinkholes) or lines (e.g. dry valleys, faults). Consequently, the Transit Time Method honours the actual flow path within the unsaturated zone of a karst aquifer system. A test site in Northern Jordan was chosen for the demonstration of the assessment technique, i.e. the catchment area of the Qunayyah Spring north of the capital Amman. The results demonstrate that zones of highest vulnerability lie within valleys and nearby main fault zones. It also reveals that regions, categorised as protected areas by other methods due to thick unsaturated zones, contribute to a major degree to the total risk.     

Research note: deblended-data reconstruction using generalized blending and deblending models

We introduce a concept of generalized blending and deblending, develop its models and accordingly establish a method of deblended-data reconstruction using these models. The generalized models can handle real situations by including random encoding into the generalized operators both in the space and time domain, and both at the source and receiver side. We consider an iterative optimization scheme using a closed-loop approach with the generalized blending and deblending models, in which the former works for the forward modelling and the latter for the inverse modelling in the closed loop. We applied our method to existing real data acquired in Abu Dhabi. The results show that our method succeeded to fully reconstruct deblended data even from the fully generalized, thus quite complicated blended data. We discuss the complexity of blending properties on the deblending performance. In addition, we discuss the applicability to time-lapse seismic monitoring as it ensures high repeatability of the surveys. Conclusively, we should acquire blended data and reconstruct deblended data without serious problems but with the benefit of blended acquisition.     

Organic Material and Trace Elements of Bituminous Rocks in the Ozank(?)y Field,Ankara,Turkey

Bituminous rocks in the Ozank(?)y(Ankara) field are different from those of the Paleocene- Eocene Mengen and Güineytepe(Bolu) regions in metal enrichment levels.Organic carbon(C_(org)) content of organic material-rich rocks in the Ozank(?)y(Ankara) field is 3.66-40.72% wt averaging 14.34%.The dominant organic materials are algae/amorphous accompanied by minor amount of herbaceous material(The dominant kerogen type is Type-Ⅰwith a limited amount of Type-Ⅱkerogen.). The bituminous rocks in the Ozank(?)y field are enriched in heavy metals such as Ni,Mn,As and Cr.In comparison with the average enrichment values of elements,Ni,Mn,As and Cr in bituminous shales of the Ozank(?)y field are as about 4.38,14.93,10.90 and 5.58 times as average values.The average concentrations of these heavy metals are also as high as 215×10~(-6),828×10~(-6),58.54×10~(-6),and 148×10~(-6) respectively.In addition,sorption properties of clay and organic materials are also important for metal enrichments in the bituminous shales.