Chemical studies of copper-organic complexes isolated from estuarine waters using C18 reverse-phase liquid chromatography

Dissolved organic matter (DOM) and dissolved copper-organic complexes were isolated from the estuarine waters of Narragansett Bay, RI, using reverse-phase liquid chromatography employing C₁₈ Sep-Pak cartridges (Waters Associates). The cartridges were found to have a constant retention efficiency for processing ? 1-l volumes of seawater. Fractionation of the isolated material, by sequential elution of the Sep-Pak with water: methanol mixtures of increasing organic solvent concentration, yielded a fraction of the organic matter with a specific copper activity six times greater than the overall activity for the isolated DOM. Analysis of this fraction by high performance liquid chromatography suggested that the organic components are of intermediate polarity and have appreciable aromatic character.An investigation of the protonation characteristics of the isolated complexes indicated that most of the copper is associated with a broad range of acidic sites on the DOM. Analysis by electron paramagnetic resonance spectroscopy confirmed the organic association of the isolated copper and also suggested the presence of several types of binding sites which probably involve oxygen donor ligands.Studies of the exchange of ⁶⁴Cu with these binding sites on the isolated DOM indicated that 70% of the sites undergo rapid exchange with copper in seawater while 20% of these sites did not exchange in a 24-h time period.     

The Nuclear Stellar Cluster in NGC 1068

We present new near-infrared integral field spectroscopy and adaptive optics imaging of the nucleus of NGC 1068. Using the stellar CO absorption features in the H and K bands, we have identified a moderately extincted stellar core centered on the nuclear position and of intrinsic size ~50 pc. We show that this nuclear stellar core is probably 5-16 × 108 years in age and contributes at least 7% of the total nuclear luminosity of ~1 × 1011 L⊙. This revised version was published online in July 2006 with corrections to the Cover Date.     

Three recent larger earthquakes offshore Norway

Three earthquakes of magnitude around 5 occurred offshore western Norway on 5th February, 1986, on 8th August, 1988, and on 23rd January, 1989. These earthquakes, representing the highest seismic activity level in this area for at least 30 years, were all felt by people over most of southern and central Norway. Focal-mechanism solutions for these earthquakes indicate thrust faulting along N-S to NNE-SSW striking fault planes, in response to NW-SE compressional stress, most probably of plate tectonic origin.
A number of high-quality digital recordings of the ground motions at various distances from these and other recent earthquakes in Norway have shown that source spectral as well as wave attenuation characteristics in this area are reasonably consistent with what has been derived from other intraplate areas.     

An improved lunar moment of inertia determination: a proposed strategy

The current error of 0.0025 on the lunar homogeneity parameterI/MR ² is dominated by the uncertainties in theC ₂₀ andC ₂₂ gravity harmonics. This error level is equivalent to a 4.20 gm cm^–3 density uncertainty for a lunar interior model having a core 300 km in radius. Covariance analyses are performed using Doppler data from the relay satellite of the proposed Lunar Polar Orbiter mission to determine an optimum reduction strategy which obtains an order of magnitude improvement in the gravity estimates. Error studies show the long-arc reduction method obtains results which are an order of magnitude more accurate than the short-arc technique. The nominal 4000 km circular orbit of the relay satellite is very sensitive to the unmodeled effects of gravity harmonics of degree 5 through 9. Results from this orbital geometry indicate that it may not be possible to achieve the desired order of magnitude accuracy improvement. A modified orbit having the identical orbital conditions as the nominal one, but with a larger semi-major axis of 7000 km is studied. Results show the desired order of magnitude improvement can be achieved when a complete fourth degree and order model and some fifth and sixth degree terms are estimated while considering the unmodeled effects of the remaining harmonics through degree and order eight. Studies also show a 50% additional improvement inC ₂₂ can be achieved if differential differenced Doppler is also processed with the direct Doppler. The improved uncertainty inI/MR ² reduces the core density error from 4.20 gm cm^–3 to 0.1 gm cm^–3 for the case of a lunar density model having a 300 km core radius.Contribution #2885 of the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A.     

12,000-Year, preliminary results of the stable nitrogen and carbon isotope record from the Empakai Crater lake sediments, Northern Tanzania

The stable isotope compositions of organic carbon and nitrogen, the contents of organic carbon and nitrogen and C/N ratios for two cores recovered from the Empakai Crater at water depths of 11 and 20 m are used to document climatic changes in northern Tanzania. Eight ¹⁴C AMS dates determined on total organic matter (OM) indicate that the sedimentation rate in this lake is about 30 cm/ka for the late Pleistocene to early Holocene period. There are differences in the δ¹³C values of organic carbon between the two cores, which may be a result of differences in location from the present shoreline and of different water depths. In the deeper-water core the δ¹³C values show a general downcore decrease to the base of the core with a sharp change to lower values of about 4‰ at a depth of 100 cm (8.7 ka). The general trend of downcore decrease in ¹³C values can be attributed either to a systematic decrease in the relative proportion of C₄ type of OM, owing to an increase in precipitation and change in vegetation cover from grassland to forest, or to utilization of isotopically enriched carbon during photosynthesis. The δ¹⁵N values show a general downcore increase with again a sharp change of about 5‰ to lower values at about 8.7 ka. A sharp change of about 5‰ and 4‰ to more depleted values at a depth of 100 cm of both ¹⁵N and ¹³C, respectively, suggests either hiatus or abrupt change in climatic condition from wetter conditions to drier conditions. There is enhanced preservation of OM in the lake as depicted by high mean values of organic carbon and nitrogen at both sites.     

Uncertainty estimation of the global temperature trends for multiple radiosondes, reanalyses, and CMIP3/IPCC climate model simulations

Based on three groups of datasets that include radiosondes, reanalyses, and climate model simulations (e.g., Coupled Model Intercomparison Project, CMIP3) from 1979 to 2008, the interannual variability, global temperature trends, and their uncertainty using ensemble spread among intra-group and inter-group datasets have been discussed. The results show that the interannual temperature variability increased from the troposphere to stratosphere, and the maximum occurs around 50?hPa. The CMIP3 climate models have the largest discrepancy in the stratosphere. The intra-group correlations at 500?hPa generally show high similarity within each data group while the inter-group correlations between reanalyses and the CMIP3 climate model simulations indicate lesser similarity. In contrast, the inter-group correlation at 50?hPa is improved except with the Japanese 25-year Reanalysis Project (JRA-25) dataset, and the Twentieth Century Reanalysis (20CR) reanalysis shows a weak cross correlation. The global temperature trends are highly dependent on the individual data sources. Compared to the radiosondes, the reanalyses show a large ensemble spread of trends in the stratosphere, and the CMIP3 climate model simulations have a large ensemble spread in the height of the crossover point where tropospheric warming changes into stratospheric cooling. The largest ensemble spread among the reanalyses in the stratosphere is mainly from the large discrepancy in the JRA-25 reanalysis after 1998 and a relatively weak anomaly in the 20CR before 1986. The largest ensemble spread among the CMIP3 climate models in the troposphere is related to the influence of both volcanic eruptions and El Ni?o/La Ni?a–Southern Oscillation events. The strong anomalies corresponding to the volcanic eruptions of El Chichon in 1982 and Mt Pinatubo in 1991 are clearly identified in the stratosphere. These volcanic eruptions reduced the warming in the troposphere and strengthened the cooling in the stratosphere during the most recent 30?years.     

Seasonality change and the third millennium BP rainforest crisis in southern Cameroon (Central Africa)

The third millennium BP crisis of the central African rainforest is not sufficiently understood. The low resolution of most pollen profiles and a large plateau of the calibration curve aggravate the exact dating of the event, and its causal climatic parameters are debated. We present a high-resolution pollen profile from the swamp site Nyabessan in the southern Cameroonian rainforest, covering the period 3100-2300 cal yr BP. Between 3100 and 2500 cal yr BP, the climate was favourable for a regional evergreen forest with Caesalpiniaceae and Lophira and a local Raphia swamp forest. Around 2500/2400 cal yr BP, a significant decrease of mature forest and swamp forest taxa and an increase of pioneers indicate that the rain forest was seriously disturbed and replaced by secondary formations. The dominance of Trema orientalis, a pioneer well adapted to seasonal desiccation, points to a much more accentuated seasonality after 2500 cal yr BP, which seems to be linked to a southwards shift of the ITCZ during the northern hemisphere winter months. We propose that the rain forest crisis between 2500 and 2200 cal BP created favourable conditions for farming and paved the way for a major expansion of Bantu speaking populations.     

The topography of Iapetus' leading side

We have used Cassini stereo images to study the topography of Iapetus' leading side. A terrain model derived at resolutions of 4-8 km reveals that Iapetus has substantial topography with heights in the range of −10 km to +13 km, much more than observed on the other middle-sized satellites of Saturn so far. Most of the topography is older than 4 Ga [Neukum, G., Wagner, R., Denk, T., Porco, C.C., 2005. Lunar Planet. Sci. XXXVI. Abstract 2034] which implies that Iapetus must have had a thick lithosphere early in its history to support this topography. Models of lithospheric deflection by topographic loads provide an estimate of the required elastic thickness in the range of 50-100 km. Iapetus' prominent equatorial ridge [Porco, C.C., and 34 colleagues, 2005. Science 307, 1237-1242] reaches widths of 70 km and heights of up to 13 km from their base within the modeled area. The morphology of the ridge suggests an endogenous origin rather than a formation by collisional accretion of a ring remnant [Ip, W.-H., 2006. Geophys. Res. Lett. 33, doi:10.1029/2005GL025386. L16203]. The transition from simple to complex central peak craters on Iapetus occurs at diameters of 11±3 km. The central peaks have pronounced conical shapes with flanking slopes of typically 11° and heights that can rise above the surrounding plains. Crater depths seem to be systematically lower on Iapetus than on similarly sized Rhea, which if true, may be related to more pronounced crater-wall slumping (which widens the craters) on Iapetus than on Rhea. There are seven large impact basins with complex morphologies including central peak massifs and terraced walls, the largest one reaches 800 km in diameter and has rim topography of up to 10 km. Generally, no rings are observed with the basins consistent with a thick lithosphere but still thin enough to allow for viscous relaxation of the basin floors, which is inferred from crater depth-to-diameter measurements. In particular, a 400-km basin shows up-domed floor topography which is suggestive of viscous relaxation. A model of complex crater formation with a viscoplastic (Bingham) rheology [Melosh, H.J., 1989. Impact Cratering. Oxford Univ. Press, New York] of the impact-shocked icy material provides an estimate of the effective cohesion/viscosity at . The local distribution of bright and dark material on the surface of Iapetus is largely controlled by topography and consistent with the dark material being a sublimation lag deposit originating from a bright icy substrate mixed with the dark components, but frost deposits are possible as well.