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181.
Reassessment of Hydrofluoric Acid Desilicification in the Carius Tube Digestion Technique for Re–Os Isotopic Determination in Geological Samples
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Jie Li Pei‐Pei Zhao Jingao Liu Xuan‐Ce Wang Alexandra Yang Yang Gui‐Qing Wang Ji‐Feng Xu 《Geostandards and Geoanalytical Research》2015,39(1):17-30
In this study, Re and Os isotopes were systematically determined in six geological reference materials (RMs; covering a wide range of lithologies) using the Carius tube (CT) digestion technique with and without hydrofluoric acid desilicification. Our results show that the HF desilicification increased the Re extraction efficiency (by 9–15%) evidenced from basaltic and andesitic rocks (e.g., BHVO‐2, TDB‐1 and AGV‐2). This implies that a small proportion of Re resides in silicate phases. For mafic–ultramafic rocks (e.g., BCR‐2, WGB‐1 and WPR‐1), Re extraction efficiencies obtained by the CT digestion with and without HF desilicification were similar. This may indicate that Re in these rocks may dominantly reside in some phases (e.g., magnetite and sulfides) that could be completely dissolved in aqua regia solutions without the aid of HF desilicification. Our results also show that the HF desilicification increased Os extraction efficiency (by 13–99%) in some RMs (e.g., BHVO‐2, WGB‐1 and AGV‐2). This observation suggests that a portion of Os‐rich trace phases may occur as inclusions in the silicate phases that act as isolators at ~ 200 mesh sizes. This study demonstrates that the HF desilicification step prior to CT digestion is important for complete extraction of Re and Os in geological samples. 相似文献
182.
Abstract— To constrain the metamorphic history of the H‐chondrite parent body, we dated phosphates and chondrules from four H6 chondritic meteorites using U‐Pb systematics. Reconnaissance analyses revealed that only Estacado had a sufficiently high 206Pb/204Pb ratio suitable for our purposes. The Pb‐Pb isochron date for Estacado phosphates is measured to be 4492 ± 15 Ma. The internal residue‐second leachate isochron for Estacado chondrules yielded the chondrule date of 4546 ± 18 Ma. An alternative age estimate for Estacado chondrules of 4527.6 ± 6.3 Ma is obtained from an isochron including two chondrules, two magnetically separated fractions, and four bulk chondrite analyses. This isochron date might represent the age of termination of Pb diffusion from the chondrules to the matrix. From these dates and previously established closure temperatures for Pb diffusion in phosphates and chondrules, we estimate an average cooling rate for Estacado between 5.5 ± 3.2 Myr/°C and 8.3 ± 5.0 Myr/°C. Using previously published results for Ste. Marguerite (H4) and Richardton (H5), our data reveal that the cooling rates of H chondrites decrease markedly with increasing metamorphic grade, in agreement with the predictions of the “onion‐shell” asteroid model. Several issues, however, need to be addressed before confirming this model for the H‐chondrite parent body: the discrepancies between peak metamorphic temperatures established by various mineral thermometers need to be resolved, diffusion and other mechanisms of element migration in polycrystalline solids must be better understood, and dating techniques should be further improved. 相似文献
183.
Photo‐identification has been established as a helpful tool in cetacean research. However, no study to date has attempted to apply this method to short‐beaked common dolphins (Delphinus delphis L.). We present here the results of two studies that were conducted concurrently in Mercury Bay and the Hauraki Gulf on the north‐east coast of New Zealand's North Island. Methods for distinguishing between individual dolphins are discussed. Sighting records of recognisable individuals indicate that some common dolphins move between Mercury Bay and the Hauraki Gulf (100 km distance), as well as between Mercury Bay and Whakatane (200 km distance). Common dolphin abundance and site fidelity appeared to be greater in the Hauraki Gulf than in Mercury Bay. A selection of photographs of distinct individuals is presented to allow future studies to compare their sighting records to ours, which may help establish the extent of home ranges, site fidelity, and possibly even longevity for common dolphins. 相似文献
184.
Alexandra D. Syphard Susan I. Stewart Jason Mckeefry Roger B. Hammer Jeremy S. Fried Sherry Holcomb 《International journal of geographical information science》2013,27(7):859-876
The US Census provides the primary source of spatially explicit social data, but changing block boundaries complicate analyses of housing growth over time. We compared procedures for reconciling housing density data between 1990 and 2000 census block boundaries in order to assess the sensitivity of analytical methods to estimates of housing growth in Oregon. Estimates of housing growth varied substantially and were sensitive to the method of interpolation. With no processing and areal‐weighted interpolation, more than 35% of the landscape changed; 75–80% of this change was due to decline in housing density. This decline was implausible, however, because housing structures generally persist over time. Based on aggregated boundaries, 11% of the landscape changed, but only 4% experienced a decline in housing density. Nevertheless, the housing density change map was almost twice as coarse spatially as the 2000 housing density data. We also applied a dasymetric approach to redistribute 1990 housing data into 2000 census boundaries under the assumption that the distribution of housing in 2000 reflected the same distribution as in 1990. The dasymetric approach resulted in conservative change estimates at a fine resolution. All methods involved some type of trade‐off (e.g. analytical difficulty, data resolution, magnitude or bias in direction of change). However, our dasymetric procedure is a novel approach for assessing housing growth over changing census boundaries that may be particularly useful because it accounts for the uniquely persistent nature of housing over time. 相似文献
185.
Constantin Cosma Alexandra Cucoş Botond Papp Robert Begy Tiberiu Dicu Mircea Moldovan Lucia Adina Truţă Dan Constantin Niţă Bety-Denissa Burghele Liviu Suciu Carlos Sainz 《Acta Geophysica》2013,61(4):859-875
B?i?a-?tei mine is an open pit mine in NW Romania (West Carpathian Mountains). It was the largest surface uranium deposit in the world. Two means of uranium transport and dissemination were used over time. The first was the natural way, represented by transportation of geological sediments by Cri?ul-B?i?a River that crosses the B?i?a surface deposit. These sediments were used as building materials (stone, gravel, sand). The second way was related to the people living in this valley, who used also the uranium waste as building material. The preliminary indoor radon concentrations measured in the buildings ranged from 40 to 4000 Bq m?3 with a mean value of 241 Bq m?3. A focused radon survey facilitated the selection of 20 houses with the highest indoor radon that were therefore proposed for remediation. To find the radon sources of these houses, systematic investigations on radon were performed. The remedial measures for these 20 houses were tested on a chosen pilot house. 相似文献
186.
Anita Peter Hendrik Lamert Matthias Beyer G?tz Hornbruch Ben Heinrich Alexandra Schulz Helmut Geistlinger Ben Schreiber Peter Dietrich Ulrike Werban Carsten Vogt Hans-Hermann Richnow Jochen Gro?mann Andreas Dahmke 《Environmental Earth Sciences》2012,67(2):335-349
A small scale and temporally limited CO2 injection test was performed in a shallow aquifer to investigate the geochemical impact of CO2 upon such aquifers and to apply and verify different monitoring methods. Detailed site investigation coupled with multiphase simulations were necessary to design the injection experiment and to set up the monitoring network, before CO2 was injected over a ten-day period at three injection wells, at a depth of 18?m below surface level into a quaternary sand aquifer located close to the town of Wittstock in Northeast Germany. Monitoring methods comprised groundwater sampling and standard analyses, as well as trace element analyses and isotope analyses; geoelectrical borehole monitoring; passive samplers to analyse temporally integrated for cations and multi-parameter probes that can measure continuously for dissolved CO2, pH and electrical conductivity. Due to CO2 injection, total inorganic carbon concentrations increased and pH decreased down to a level of 5.1. Associated reactions comprised the release of major cations and trace elements. Geoelectrical monitoring, as well as isotope analyses and multi-parameter probes proved to be suitable methods for monitoring injected CO2 and/or the alteration of groundwater. 相似文献
187.
A simulation program, which works seamlessly with GIS and simulates flows in coastal aquifers, is presented in the present paper. The model is based on the Galerkin finite element discretization scheme and it simulates both steady and transient freshwater and saltwater flow, assuming that the two fluids are separated by a sharp interface. The model has been verified in simple cases where analytical solutions exist. The simulation program works as a tool of the GIS program, which is the main database that stores and manages all the necessary data. The combined use of the simulation and the GIS program forms an integrated management tool offering a simpler way of simulating and studying saline intrusion in coastal aquifers. Application of the model to the Yermasogia aquifer illustrates the coupled use of modeling and GIS techniques for the examination of regional coastal aquifer systems.
Resumen Se ha desarrollado un modelo casi tridimensional de elementos finitos para simular el flujo de agua dulce y salada, tanto en régimen estacionario como en transitorio, en sistemas acuíferos costeros, bajo la hipótesis de separación por medio de una interfaz abrupta. Las ecuaciones del modelo han sido discretizadas mediante un esquema de Galerkin de discretización en elementos finitos. El modelo ha sido verificado en casos sencillos para los que existe solución analítica. Todos los datos necesarios se introducen y gestionan con un Sistema de Información Geográfica [SIG] por ordenador. El programa de simulación forma parte del programa de SIG, constituyendo una herramienta integrada de gestión para estudiar la intrusión salina en acuíferos costeros. La aplicación del modelo al acuífero de Yermasogia ilustra el uso acoplado de las técnicas de modelación y de SIG con el fin de examinar sistemas acuíferos costeros a escala regional.
Résumé Pour étudier un système aquifère côtier, nous avons développé un modèle aux éléments finis en quasi 3-D qui simule les écoulements deau douce et deau salée en régime aussi bien permanent que transitoire. Les équations qui les régissent sont discrétisées par un schéma de discrétisation de Garlekin aux éléments finis. Le modèle a été vérifié dans des cas simples où il existe des solutions analytiques. Toutes les données nécessaires sont introduites et gérées grâce à un logiciel de gestion de SIG. Le programme de simulation est utilisé comme un outil du logiciel de SIG, constituant ainsi un outil de gestion intégrée dont le but est de simuler et détudier lintrusion saline dans les aquifères côtiers. Lapplication du modèle à laquifère de Yermasogia illustre lutilisation couplée de la modélisation et des techniques de SIG pour létude des systèmes aquifères côtiers régionaux.相似文献
188.
Influence of localised igneous activity on cleat dawsonite formation in Late Permian coal measures, Upper Hunter Valley, Australia 总被引:6,自引:0,他引:6
Alexandra N. Golab Paul F. Carr Daniel R. Palamara 《International Journal of Coal Geology》2006,66(4):296-304
Stable (δ13C and δ18O) and radiogenic 87Sr/86Sr isotopic data have been used to investigate the origin of cleat dawsonite (NaAlCO3(OH)2) in the Late Permian Wittingham Coal Measures of the Upper Hunter region in the Sydney Basin, New South Wales. The δ13CPDB values have a narrow range (− 1.7‰ to + 2.4‰), with an average of + 0.3‰, suggesting a magmatic source for the carbon. In contrast, δ18OSMOW values have a wide range (+ 13.6‰ to + 19.8‰), and decrease systematically with decreasing distance from a major intrusion. This systematic variation reflects establishment of localised hydrothermal cells. Water–rock interaction between fluids associated with these hydrothermal cells, and Rb-poor volcaniclastic detritus in the coal measures, produced mantle-like 87Sr/86Sr (0.705032 to 0.706464) in the dawsonite. 相似文献
189.
Biodiversität und Ökologie aquatischer Oomycetes‐Arten im Auesee und in der Fulda in Kassel (Hessen)
Biodiversity and Ecology of Species of Aquatic Oomycetes in the Aue Lake and the River Fulda in Kassel (Hessen) In this study, we record diversity and ecology of aquatic Oomycetes in the Aue Lake and the river Fulda in Kassel (Hesse, Germany). We monthly collected water samples of both water bodies from July 2003 to June 2004. The baiting method was used to gain an insight into the occurrence of aquatic Oomycetes. A total of 14 species of aquatic Oomycetes belonging to the orders Saprolegniales, Leptomitales and Olpidiopsidales could be isolated of both water bodies. Numerous saprophytic isolates of Rhizophydium Schenk (Chytridiomycetes), Rhizophydium carpophilum (Zopf) Fischer, parasitic on Oomycetes, and additionally one species of Plasmodiophoromycetes, Woronina polycystis Cornu could be isolated. Many isolates of Saprolegniales attributable to the genera Achlya Nees, Dictyuchus Leitgeb, Saprolegnia Nees and Pythium Pringsheim (Pythiales), which could only be identified on generic level, could be isolated as well. The species were examined and discussed with respect to their occurrence in the stagnant water Aue Lake and/or in the running water of the river Fulda. Half of the isolated species only occurred in one of the water bodies. In this study the occurrence of Achlya proliferoides Coker could be documented for Germany for the first time. The trophic status of the Aue Lake and of the classification of water quality of the river Fulda were determined by limnological‐chemical parameters obtained by simultaneous investigations of both water bodies. 相似文献
190.
New approaches to environmental monitoring: the use of ICT to explore volunteered geographic information 总被引:3,自引:0,他引:3
Citizen participation in environmental monitoring is not a new idea. However, recent developments in information and communication technologies (ICT), such as the social web and the miniaturization of sensors, have created new opportunities to promote citizen participation in environmental monitoring. The analysis of existing citizen initiatives that use ICT tools, identified the need for a framework conceptualizing ways to increase the contribution of volunteered geographic data in environmental monitoring. Environmental Collaborative Monitoring Networks (ECMN) are proposed in this paper as a framework that combines the concepts of traditional environmental monitoring networks with the ideals of the open source movement. Such framework can guide the creation of fixed and mobile monitoring networks and is organized based on three building blocks: (1) Motivated Citizens; (2) Sensing Devices; and (3) Back-End Information Infrastructure. To illustrate the issues involved in the implementation of the building blocks of ECMN, the Senses@Watch project is presented, which explored the use of sensory data as a source of monitoring data. 相似文献