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311.
Noriko T. Kita Qing‐Zhu Yin Glenn J. MacPherson Takayuki Ushikubo Benjamin Jacobsen Kazuhide Nagashima Erika Kurahashi Alexander N. Krot Stein B. Jacobsen 《Meteoritics & planetary science》2013,48(8):1383-1400
High‐precision bulk aluminum‐magnesium isotope measurements of calcium‐aluminum‐rich inclusions (CAIs) from CV carbonaceous chondrites in several laboratories define a bulk 26Al‐26Mg isochron with an inferred initial 26Al/27Al ratio of approximately 5.25 × 10?5, named the canonical ratio. Nonigneous CV CAIs yield well‐defined internal 26Al‐26Mg isochrons consistent with the canonical value. These observations indicate that the canonical 26Al/27Al ratio records initial Al/Mg fractionation by evaporation and condensation in the CV CAI‐forming region. The internal isochrons of igneous CV CAIs show a range of inferred initial 26Al/27Al ratios, (4.2–5.2) × 10?5, indicating that CAI melting continued for at least 0.2 Ma after formation of their precursors. A similar range of initial 26Al/27Al ratios is also obtained from the internal isochrons of many CAIs (igneous and nonigneous) in other groups of carbonaceous chondrites. Some CAIs and refractory grains (corundum and hibonite) from unmetamorphosed or weakly metamorphosed chondrites, including CVs, are significantly depleted in 26Al. At least some of these refractory objects may have formed prior to injection of 26Al into the protosolar molecular cloud and its subsequent homogenization in the protoplanetary disk. Bulk aluminum and magnesium‐isotope measurements of various types of chondrites plot along the bulk CV CAI isochron, suggesting homogeneous distribution of 26Al and magnesium isotopes in the protoplanetary disk after an epoch of CAI formation. The inferred initial 26Al/27Al ratios of chondrules indicate that most chondrules formed 1–3 Ma after CAIs with the canonical 26Al/27Al ratio. 相似文献
312.
Alexander S. Lloyd Terry Plank Philipp Ruprecht Erik H. Hauri William Rose 《Contributions to Mineralogy and Petrology》2013,165(1):129-153
We have investigated the loss of H2O from olivine-hosted melt inclusions (MIs) by designing an experiment using tephra samples that cooled at different rates owing to their different sizes: ash, lapilli, and bomb samples that were deposited on the same day (10/17/74) of the sub-Plinian eruption of Volcán de Fuego in Guatemala. Ion microprobe, laser ablation-ICPMS, and electron probe analyses show that MIs from ash and lapilli record the highest H2O contents, up to 4.4 wt%. On the other hand, MIs from bombs indicate up to 30 % lower H2O contents (loss of ~1 wt% H2O) and 10 % post-entrapment crystallization of olivine. This evidence is consistent with the longer cooling time available for a bomb-sized clast, up to 10 min for a 3–4-cm radius bomb, assuming conductive cooling and the fastest H diffusivities measured in olivine (D~10?9 to 10?10 m2/s). On the other hand, several lines of evidence point to some water loss prior to eruption, during magma ascent and degassing in the conduit. Thus, results point to both slower post-eruptive cooling and slower magma ascent affecting MIs from bombs, leading to H2O loss over the timescale of minutes to hours. The important implication of this study is that a significant portion of the published data on H2O concentrations in olivine-hosted MIs may reflect unrecognized H2O loss via diffusion. This work highlights the importance of reporting clast and MI sizes in order to assess diffusive effects and the potential benefit of using water loss as a chronometer of magma ascent. 相似文献
313.
Alexander Proyer Gerlinde Habler Rainer Abart Richard Wirth Kurt Krenn Georg Hoinkes 《Contributions to Mineralogy and Petrology》2013,166(1):211-234
We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe2+ to Fe3+ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies. 相似文献
314.
Alexander Borisov Harald Behrens Francois Holtz 《Contributions to Mineralogy and Petrology》2013,166(6):1577-1591
The effect of TiO2 and P2O5 on the ferric/ferrous ratio in silicate melts was investigated in model silicate melts at air conditions in the temperature range 1,400–1,550 °C at 1-atm total pressure. The base composition of the anorthite–diopside eutectic composition was modified with 10 wt % Fe2O3 and variable amounts of TiO2 (up to 30 wt %) or P2O5 (up to 20 wt %). Some compositions also contained higher SiO2 concentrations to compare the role of SiO2, TiO2, and P2O5 on the Fe3+/Fe2+ ratio. The ferric/ferrous ratio in experimental glasses was analyzed using a wet chemical technique with colorimetric detection of ferrous iron. It is shown that at constant temperature, an increase in SiO2, TiO2, and P2O5 content results in a decrease in the ferric/ferrous ratio. The effects of TiO2 and SiO2 on the Fe3+/Fe2+ ratio was found to be almost identical. In contrast, adding P2O5 was found to decrease ferric/ferrous ratio much more effectively than adding silica. The results were compared with the predictions from the published empirical equations forecasting Fe3+/Fe2+ ratio. It was demonstrated that the effects of TiO2 are minor but that the effects of P2O5 should be included in models to better describe ferric/ferrous ratio in phosphorus-bearing silicate melts. Based on our observations, the determination of the prevailing fO2 in magmas from the Fe3+/Fe2+ ratio in natural glasses using empirical equations published so far is discussed critically. 相似文献
315.
Mário André Trindade Dantas Rodrigo Parisi Dutra Alexander Cherkinsky Daniel Costa Fortier Luciana Hiromi Yoshino Kamino Mario Alberto Cozzuol Adauto de Souza Ribeiro Fabiana Silva Vieira 《Quaternary Research》2013,79(1):61-65
During the Pleistocene a fauna composed of large (biomass > 44 kg) and giant mammals (biomass > 1000 kg) that are usually associated with open environments lived in the Brazilian Intertropical Region. We present here new information concerning the paleoecology and chronology of some species of this megafauna. Carbon isotope analyses were performed for a better understanding of the paleoecology of the species Eremotherium laurillardi (Lund, 1842), Notiomastodon platensis (Ameghino, 1888) and Toxodon platensis (Owen, 1849). The δ13C data allow attributing a generalist diet to these species, which varied according to the kind of habitat in which they lived. In more open habitats all species were grazers; in mixed habitats E. laurillardi and T. platensis were mixed feeders, and N. platensis was grazer; and in more closed habitats all species were mixed feeders. 相似文献
316.
317.
Alexander Z. Bochev Karel Kudela Iren A. Dimitrova Petko Nenovski Ashwini K. Sinha Marián Slivka 《Studia Geophysica et Geodaetica》2009,53(4):537-556
Examples of long period Pc5 magnetic field pulsations near field-aligned current (FAC) regions in the high-latitude magnetosphere,
observed by INTERBALL-Auroral satellite during January 11, April 11 and June 28, 1997 are shown. Identification of corresponding
magnetosphere regions and subregions is provided by electrons and protons in the energy-range of 0.01–100 keV measured simultaneously
onboard the spacecraft. The examined Pc5 pulsations reveal a compressional character. A fairly good correlation is demonstrated
between these ULF Pc5 waves and the consecutive injection of magnetosheath low energy protons. The ULF Pc5 wave occurrence
is observed in both upward and downward FACs. 相似文献
318.
Miriam Dühnforth Alexander L. Densmore Susan Ivy‐Ochs Philip A. Allen 《地球表面变化过程与地形》2008,33(10):1602-1613
The degree of glacial modification in small catchments along the eastern Sierra Nevada, California, controls the timing and pattern of sediment flux to the adjacent fans. There is a close relationship between the depth of fan‐head incision and the pattern and degree of Late Pleistocene catchment erosion by valley glaciers; catchments with significant glacial activity are associated with deeply incised fan heads, whereas fans emerging from glacially unmodified catchments are unincised. We suggest that the depth of fan‐head incision is controlled by the potential for sediment storage during relatively dry ice‐free periods, which in turn is related to the downstream length of the glacially modified valley and creation of accommodation through valley floor slope lowering and glacial valley overdeepening and widening. Significant storage in glacially modified basins during ice‐free periods leads to sediment supply‐limited conditions at the fan head and causes deep incision. In contrast, a lack of sediment trapping allows quasi‐continuous sediment supply to the fan and prevents incision of the fan head. Sediment evacuation rates should thus show large variations in glacially modified basins, with major peaks during glacial and lows during interglacial or ice‐free periods, respectively. In contrast, sediment removal from glacially unmodified catchments in this type of setting should be free of this effect, and will be dominated instead by short‐term variations, modulated for example by changes in vegetation cover or storm frequency. This distinction may help improve our understanding of long‐term sediment yields as a measure of erosional efficiency. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
319.
Indira Molina Hiroyuki Kumagai Alexander García-Aristizábal Masaru Nakano Patricia Mothes 《Journal of Volcanology and Geothermal Research》2008
Renewed seismic activity of Cotopaxi, Ecuador, began in January 2001 with the increased number of long-period (LP) events, followed by a swarm of volcano-tectonic (VT) earthquakes in November 2001. In late June 2002, the activity of very-long-period (VLP) (2 s) events accompanying LP (0.5–1 s) signals began beneath the volcano. The VLP waveform was characterized by an impulsive signature, which was accompanied by the LP signal showing non-harmonic oscillations. We observed temporal changes of both the VLP and LP signals from the beginning until September 2003: The VLP signal gradually disappeared and the LP signal characterized by decaying harmonic oscillations became dominant. Assuming possible source geometries, we applied a waveform inversion method to the observed waveforms of the largest VLP event. Our inversion and particle motion analyses point to volumetric changes of a sub-vertical crack as the VLP source, which is located at a depth of 2–3 km beneath the northeastern flank. The spectral analysis of the decaying harmonic oscillations of LP events shows frequencies between 2.0 and 3.5 Hz, with quality factors significantly above 100. The increased VT activity and deformation data suggest an intrusion of magma beneath the volcano. A release of gases with small magma particles may have repetitively occurred due to the pressurization, which was caused by sustained bubble growth at the magma ceiling. The released particle-laden gases opened a crack above the magma system and triggered the resonance of the crack. We interpret the VLP and LP events as the gas-release process and the resonance of the crack, respectively. 相似文献
320.
Alexander I. Malinovsky Vladimir V. Golozoubov Vladimir P. Simanenko Ludmila F. Simanenko 《Island Arc》2008,17(3):285-304
Abstract The Kema terrane is a suite of Barremian(?)–Aptian to Albian volcano-sedimentary rocks of Sikhote–Alin that are interpreted as deposits of the back-arc basin of the Moneron–Samarga island-arc system. Compositional features of the different-type deposits indicate a near-slope depositional environment influenced by volcanic processes. Studies of slump fold orientation testify to the accumulation of material from southeast to northwest by gravitational sliding. Compositional characteristics of terrigenous rocks suggest the major provenance for detrital material was an ensialic volcanic island arc. Petrochemical characteristics of basaltic rocks indicate that the formations studied were confined to the back part of the arc. 相似文献