Influence of metal oxides in the colorimetric determination of acid volatile sulfide in sediments

The sediment of Lagoa dos Patos‐MS, Brazil, was investigated to verify the influence of metal sulfides and oxyhydroxides of Mn and Fe on the heavy metal availability. The spectrophotometric method of methylene blue was used, with 8 interlinked tubes containing the samples with SnCl₂, where N₂ was introduced to release the H₂S extracted with 6.0 mol L^–1 HCl, and trapped in 0.05 M NaOH solution. The influence of SO₄^2–, Mn(IV) and Fe(III) oxyhydroxides was investigated with samples constituted by a mixture of MnO₂; Na₂SO₄; FeCl₃, and sediments. The presence of SnCl₂ was very important to avoid the interferences of iron and manganese oxyhydroxides. The method of standard addition was applied and the efficiency was (100.8 ± 9.4)%. The ratio among the quantities of metals potentially available and the acid volatile sulfide (AVS) indicate that the system presents small metals availability to the benthic community, by the existence of sulfide capable to immobilize the metal as insoluble sulfide.     

Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results

The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ¹¹B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution.     

New insights on late Quaternary palaeogeographic setting in the Northern Adriatic Sea (Italy)

Sedimentological, geochemical and micropalaeontological data from sediment cores in the northwestern Adriatic Sea were obtained to reconstruct the stratigraphic framework and palaeogeographic setting during the last post‐glacial sea‐level rise (14000–6000 yr BP). Four lithostratigraphic units were identified: (a) distal plain deposits (>14000 yr BP), submerged during the first phases of marine ingression; (b) coastal lagoon system; (c) barrier‐lagoon system, which is dated back to between 10019 ± 61 and 10228 ± 174 cal. yr BP from ¹⁴C dating on peat and shell remains; (d) marine prodelta deposits (<5500 yr BP). Geochemical data allow the identification of three distinct sediment sources: River Po, River Adige and Eastern Alpine rivers characterised by decreasing Ni/Mg ratios (50–70, 8–15 and 5–10, respectively) and Ba/Al ratios of 45–55, 55–65 and 35–45, respectively. The three sources display different relative abundances in time. During the Lateglacial, the Po is the main sediment source for the southern cores, whereas the Eastern Alps and the River Adige are the main sediment sources for the northern cores. This suggests a northern position of the Po River bed compared to previous studies. Coastal drowning led to a homogenization of the provenance signal within the sediments. Only after the marine transgression does a River Po signal appear in the northern cores. At the same time, in the southern cores the signal of Eastern Alpine rivers becomes stronger. Transgressive barrier‐lagoon and recent sediments do not display a predominant signal for provenance indicators. Copyright © 2008 John Wiley & Sons, Ltd.     

Vertically stacked Gilbert-type deltas of Ventimiglia (NW Italy): The Pliocene record of an overfilled Messinian incised valley

Overfilled incised valleys develop when the rate of sediment supply outpaces the rate of accommodation. An overfilled incised valley presents simple or compound valley-fill architecture, depending on the depth of the valley incision, compared with the height reached by the following sea-level rise.The Ventimiglia incised valley, exposed on the Ligurian coast, north-western Mediterranean margin, presents a spectacular example of compound incised-valley fill, developed in perennial “overfill” conditions. The valley was subaerially incised during the Messinian Salinity Crisis and rapidly flooded by the sea at the beginning of Pliocene, then filled by eleven coarse-grained Gilbert-type deltas during Early–Middle Pliocene time.The basal Messinian unconformity is locally paved with subaerial scree breccias and bioclastic shallow-marine sandstones, and blanketed by bathyal marls. These deposits record the lowstand, transgressive and early-highstand systems tracts of the first valley-fill sequence. The subsequent progradation of Gilbert-type deltas occurred in four stages, or depositional sequences, separated by transgressive marine-marl intervals. Within each depositional sequence, the deltaic bodies display offlapping architecture, recording falling shoreline trajectory, downward shifts in facies, and overall forced regression. The water depth and accommodation in the inundated coastal valley was gradually decreasing with time. The reduced accommodation allowed the youngest deltas to prograde out to the shelf edge, triggering mass collapses and subsequent filling into the newly created slump scars. Some of the deltas probably acted as “canyon-perched deltas” and supplied sediment to the deep-water slope and floor of the Ligurian Basin.The vertical stacking of Gilbert-type deltas is usually attributed, in tectonically active basins, to fault-related subsidence pulses. In Ventimiglia, the accommodation was created by high-frequency eustatic sea-level rises that, probably accompanied by climate controlled reductions in sediment supply, temporarily outpaced uplift, leading to the development of multiple cycles of infill.     

Carbon in Meteoroids: Wild 2 Dust Analyses, IDPs and Cometary Dust Analogues

Assuming that similar organic components as in comet 81P/Wild 2 are present in incoming meteoroids, we try to anticipate the observable signatures they would produce for meteor detection techniques. In this analysis we consider the elemental and organic components in cometary aggregate interplanetary dust particles and laboratory analyses of inter- and circumstellar carbon dust analogues. On the basis of our analysis we submit that (semi) quantitative measurements of H, N and C produced during meteor ablation will open an entire new aspect to using meteoroids as tracers of these volatile element abundances in active comets and their contributions to the mesospheric metal layers.