Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Sludge weathering and mobility of contaminants in soil affected by the Aznalcollar tailing dam spill (SW Spain)

As a result of the collapse of the Aznalcollar mine tailings dam, a large extension of the Guadiamar valley in SW Spain was covered with a layer of pyrite sludge. Although most of the sludge was removed, a small amount remains in the soil, constituting a potential source of water pollution. A column experiment was carried out in order to determine the rate of sludge oxidation in the soil, and the existence of metal retention processes. The column was filled with a mixture of sludge and a sandy soil common in the region. At different time intervals, the column was leached with water and the resulting solution analysed.

The pH of the water dropped to values around 2 after 260 days and then remained constant due to the buffering role of silicate dissolution. The concentration of Zn, Cd and Co in the leachates matched the expected values from flow-through experiments at atmospheric oxygen pressure. This indicates that oxygen diffusion in the pores was complete. Moreover, no efficient processes existed for retaining Zn, Cd and Co, which formed soluble salts and were entirely incorporated into the infiltrating water. During the first 2 months of the experiment, when pH was higher than 4.5, the concentrations of Fe and Al were very low. Saturation indices showed that the solution was in equilibrium with amorphous Fe(OH)₃ and Al(OH)₃. Subsequently, at lower pH values, jarosite [(Na,K)Fe₃(SO₄)₂(OH)₆] formed. This solid phase was identified by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Jarosite was also responsible for the depletion of As, Pb, Sb and probably Tl in the water resulting from infiltration.     

The El Salvador earthquakes of January and February 2001: context, characteristics and implications for seismic risk

The small Central American republic of El Salvador has experienced, on average, one destructive earthquake per decade during the last hundred years. The latest events occurred on 13 January and 13 February 2001, with magnitudes M_w 7.7 and 6.6, respectively. The two events, which were of different tectonic origin, follow the patterns of the seismicity of the region although neither event has a known precedent in the earthquake catalogue in terms of size and location. The earthquakes caused damage to thousands of traditionally built houses and triggered hundreds of landslides, which were the main causes of fatalities. The earthquakes have clearly demonstrated trends of increasing seismic risk in El Salvador due to rapid population expansion in areas of high shaking and landslide hazard, exacerbated by deforestation and uncontrolled urbanisation. The institutional mechanisms required for the control of land use and building practice are very weak and present a major obstacle to risk mitigation.     

Alpujarride attribution of the supposed ‘Almagride Complex’ (Betic Internal Zone,Almerı́a Province,Spain)Appartenance Alpujarride du prétendu « Complexe almagride » (Zones internes bétiques,province d'Almeria,Espagne)

The differentiation of units in the Sierra de Almagro has been a source of controversy. There were defined the Almagride and Ballabona–Cucharón complexes, the former considered by several authors as part of a Subbetic metamorphosed and outcropping in a tectonic window. In this study, the units of Ballabona, Almagro and Cucharón are integrated into a single one, that of Tres Pacos, because they correspond to different parts of the same stratigraphic series. This unit is tectonically over the Nevado–Filabride Complex. The existence of the Almagride and Ballabona–Cucharón complexes is discarded and their units form part of the Alpujarride Complex. To cite this article: C. Sanz de Galdeano, F.J. Garc??a Tortosa, C. R. Geoscience 334 (2002) 355–362.     

Old inherited origin for the present near-bimodal topography of Africa

Africa’s landscape is dominated by a manifold of second-order epeirogenic structures superimposed on a first-order bimodal topography. Bivariate regression analysis of Africa’s surface topography shows that this is a complexly folded surface with regionally elevated areas in southern and eastern Africa, and a topographically low northern and western Africa. The apparent spatial relationships between these features are analysed using anomaly correlation between surface topography and free-air gravity anomalies. Occurrences of positively correlated features between gravity and topography in Africa are found to be limited to second-order epeirogenic features. Geophysical modelling and geologic evidence indicate that Africa’s bimodal topography is genetically distinct from these second-order features, and linked to sources as deep as the sublithospheric mantle. The age, measured and modelled elevation of the bimodal topography require that topographic uplift of south-central Africa be episodic. We infer from our findings together with relative sea-level changes, that the near-bimodality of Africa’s topography is an ancient feature inherited at least from upper Paleozoic times. Our reconstructed paleotopography suggests that Africa was largely a low-lying continent dominated by its cratons, and that basement distribution disregards the present-day uplift patterns of Africa.     

Modelling the short-term response of the Greenland ice-sheet to global warming

 A two-dimensional vertically integrated ice flow model has been developed to test the importance of various processes and concepts used for the prediction of the contribution of the Greenland ice-sheet to sea-level rise over the next 350 y (short-term response). The mass balance is modelled by the degree-day method and the energy-balance method. The lithosphere is considered to respond isostatically to a point load and the time evolution of the bedrock follows from a viscous asthenosphere. According to the IPCC-IS92a scenario (with constant aerosols after 1990) the Greenland ice-sheet is likely to cause a global sea level rise of 10.4 cm by 2100 AD. It is shown, however, that the result is sensitive to precise model formulations and that simplifications as used in the sea-level projection in the IPCC-96 report yield less accurate results. Our model results indicate that, on a time scale of a hundred years, including the dynamic response of the ice-sheet yields more mass loss than the fixed response in which changes in geometry are not incorporated. It appears to be important to consider sliding, as well as the fact that climate sensitivity increases for larger perturbations. Variations in predicted sea-level change on a time scale of hundred years depend mostly on the initial state of the ice-sheet. On a time scale of a few hundred years, however, the variability in the predicted melt is dominated by the variability in the climate scenarios. Received: 21 August 1996/Accepted: 12 May 1997     

Prediction in hydrogeology: two case histories

An inherent aspect of hydrogeology is the dynamic character of groundwater flow within the more passive lithospheric medium. Prediction therefore requires insight into the spatial pattern of aquifer properties as well as the dynamic character of groundwater flow systems. Both aspects together determine hydrogeological system behaviour in space and time. The spatial characteristics of an aquifer are mainly based on geological and geomorphological structure, whereas the dynamics of the system result predominantly from climate and topography; knowledge of paleoconditions are a prerequisite for sound understanding of present systems. The integration of exploration and forecast is illustrated by two case studies. The first study focuses on an assessment of groundwater resource and their sustainable development in semi-arid Botswana. The second study concerns the impact of land and water management in the Netherlands coastal area on the groundwater regime and its future development, including the redistribution of salt and fresh groundwater on a long time scale.