Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature

The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm³ molecule⁻¹ s⁻¹). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO₃, O₃ and Cl have been calculated.     

On the Derivation of Input Parameters for Urban Canopy Models from Urban Morphological Datasets

Two techniques are analysed to derive mean street width and mean building width from morphological data of real cities: one based on a two-dimensional simplified morphology, and the other based on a three-dimensional regular simplified morphology. For each simplified morphology (two-dimensional and three-dimensional), the sky-view factors (street-to-sky) are computed and compared with the sky-view factors derived from the real morphology for selected districts of three European and two North American cities. The two-dimensional simplified morphology reproduces the real sky-view factors better than the three-dimensional morphology. Since many urban canopy parameterizations represent the city using simplified morphologies, this can be useful information for the derivation of input parameters for urban canopy parameterizations from real morphological data.     

Recovering the real-space correlation function from photometric redshift surveys

Measurements of clustering in large-scale imaging surveys that make use of photometric redshifts depend on the uncertainties in the redshift determination. We have used light-cone simulations to show how the deprojection method successfully recovers the real-space correlation function when applied to mock photometric redshift surveys. We study how the errors in the redshift determination affect the quality of the recovered two-point correlation function. Considering the expected errors associated with the planned photometric redshift surveys, we conclude that this method provides information on the clustering of matter useful for the estimation of cosmological parameters that depend on the large-scale distribution of galaxies.     

Gravitation astrometric measurement experiment

The Gravitation Astrometric Measurement Experiment (GAME) is a mission concept based on astronomical techniques (astrometry and coronagraphy) for Fundamental Physics measurements, namely the ?? and ?? parameters of the Parametrized Post-Newtonian formulation of gravitation theories extending the General Relativity. The science case also addresses cosmology, extra-solar planets, Solar System objects and fundamental stellar parameters. The mission concept is described, including the measurement approach and the instrument design.     

Intercomparison of the LASCO-C2, SECCHI-COR1, SECCHI-COR2, and Mk4 Coronagraphs

In order to assess the reliability and consistency of white-light coronagraph measurements, we report on quantitative comparisons between polarized brightness [pB] and total brightness [B] images taken by the following white-light coronagraphs: LASCO-C2 on SOHO, SECCHI-COR1 and -COR2 on STEREO, and the ground-based MLSO-Mk4. The data for this comparison were taken on 16?April 2007, when both STEREO spacecraft were within 3.1^° of Earth??s heliographic longitude, affording essentially the same view of the Sun for all of the instruments. Due to the difficulties of estimating stray-light backgrounds in COR1 and COR2, only Mk4 and C2 produce reliable coronal-hole values (but not at overlapping heights), and these cannot be validated without rocket flights or ground-based eclipse measurements. Generally, the agreement between all of the instruments?? pB values is within the uncertainties in bright streamer structures, implying that measurements of bright CMEs also should be trustworthy. Dominant sources of uncertainty and stray light are discussed, as is the design of future coronagraphs from the perspective of the experiences with these instruments.     

Determination of Meteoroid Orbits and Spatial Fluxes by Using High-Resolution All-Sky CCD Cameras

By using high-resolution, low-scan-rate, all-sky CCD cameras, the SPanish Meteor Network (SPMN) is currently monitoring meteor and fireball activity on a year round basis. Here are presented just a sampling of the accurate trajectory, radiant and orbital data obtained for meteors imaged simultaneously from two SPMN stations during the continuous 2006–2007 coverage of meteor and fireball monitoring. Typical astrometric uncertainty is 1–2 arc min, while velocity determination errors are of the order of 0.1–0.5 km/s, which is dependent on the distance of each event to the station and its particular viewing geometry. The cameras have demonstrated excellent performance for detecting meteor outbursts. The recent development of automatic detection software is also providing real-time information on the global meteor activity. Finally, some examples of the all-sky CCD cameras applications for detecting unexpected meteor activity are given.     

A depth average SPH model including μ(I) rheology and crushing for rock avalanches

Classical depth-integrated smoothed particle hydrodynamics (SPH) models for avalanches are extended in the present work to include a μ(I)− rheological model enriched with a fragmentation law. With this improvement, the basal friction becomes grain distribution dependent. Rock avalanches, where grain distribution tends to change with time while propagating, are the appropriate type of landslide to apply the new numerical proposal. The μ(I)− rheological models considered in the present work are those of Hatano and Gray, combined with two different fragmentation laws, a hyperbolic and a fractal-based law. As an application, Frank avalanche, which took place in Canada in 1903, is analyzed under the scope of the present approach, focusing in the influence of the rheological and fragmentation laws in the evolution of the avalanche.     

Late Pleistocene climate of the northern Iberian Peninsula: New insights from palaeoglaciers at Fuentes Carrionas (Cantabrian Mountains)

New ¹⁰Be dates for glacial landforms in the Fuentes Carrionas area (Cantabrian Mountains, nothern Spain) are presented. Mapped and dated landforms in Fuentes Carrionas made possible a palaeoglacier reconstruction for four glacial stages. Results were compared to other nearby palaeoenvironmental proxies, so a final approximation on the mean annual temperature and annual precipitation that caused the four glacial advance stages is proposed. Glaciers reached their maximum extension at 36 ka, in a cold and dry environment. A second advance stage took place between 18.5 and 19.5 ka, during the Last Glacial Maximum (LGM), when glaciers advanced in a wet environment, with positive rainfall anomalies. A third glacial advance was dated during the Oldest Dryas, in which climate shifted to extremely cold and dry conditions. Finally, a last stage has been identified and proposed to the Younger Dryas, in which precipitation anomalies are negligible. Our results confirm some of the previously made palaeoglacial and palaeoenvironmental inferences for the Iberian Peninsula, as well as provide valuable and accurate anomalies, which are useful for climate modelling.     

Using low-density discrete Airborne Laser Scanning data to assess the potential carbon dioxide emission in case of a fire event in a Mediterranean pine forest

The aim of study is to map the carbon dioxide (CO₂) emission of the aboveground tree biomass (AGB) in case of a fire event. The suitability of low point density, discrete, multiple-return, Airborne Laser Scanning (ALS) data and the influence of several characteristics of these data and the study area on the results obtained have been evaluated. A sample of 45 circular plots representative of Pinus halepensis Miller stands were used to fit and validate the model of AGB. The ALS point clouds were processed to obtain the independent variables and a multivariate linear regression analysis between field data and ALS-derived variables allowed estimation of AGB. Then, the influence of several characteristics on the residuals of the model was analyzed. Finally, conversion factors were applied to obtain the CO₂ values. The AGB model presented a R² value of 0.84 with a relative root-mean-square error of 27.35%. This model included ALS variables related to vegetation height variability and to canopy density. Terrain slope, aspect, canopy cover, scan angle and the number of laser returns did not influence AGB estimations at plot level.     

Social networks and healthy cities: spreading good practices based on a spanish case study

The city of Vitoria‐Gasteiz in Spain is considered a “healthy city” and has implemented sustainable actions to increase the mobility of its healthcare professionals. The objectives of this study are firstly to account for the use of bicycles at work as a strategy for a healthy city and secondly to propose a conceptual framework for analyzing this network and its capacity to spread their practices The paradigm proposed is that of social networks, within which sharing between contacts is explained by means of two models: the “threshold model” and “opinion leaders”.