The electrical structure of the Slave craton

The Slave craton in northwestern Canada, a relatively small Archean craton (600×400 km), is ideal as a natural laboratory for investigating the formation and evolution of Mesoarchean and Neoarchean sub-continental lithospheric mantle (SCLM). Excellent outcrop and the discovery of economic diamondiferous kimberlite pipes in the centre of the craton during the early 1990s have led to an unparalleled amount of geoscientific information becoming available.

Over the last 5 years deep-probing electromagnetic surveys were conducted on the Slave, using the natural-source magnetotelluric (MT) technique, as part of a variety of programs to study the craton and determine its regional-scale electrical structure. Two of the four types of surveys involved novel MT data acquisition; one through frozen lakes along ice roads during winter, and the second using ocean-bottom MT instrumentation deployed from float planes.

The primary initial objective of the MT surveys was to determine the geometry of the topography of the lithosphere–asthenosphere boundary (LAB) across the Slave craton. However, the MT responses revealed, completely serendipitously, a remarkable anomaly in electrical conductivity in the SCLM of the central Slave craton. This Central Slave Mantle Conductor (CSMC) anomaly is modelled as a localized region of low resistivity (10–15 Ω m) beginning at depths of 80–120 km and striking NE–SW. Where precisely located, it is spatially coincident with the Eocene-aged kimberlite field in the central part of the craton (the so-called “Corridor of Hope”), and also with a geochemically defined ultra-depleted harzburgitic layer interpreted as oceanic or arc-related lithosphere emplaced during early tectonism. The CSMC lies wholly within the NE–SW striking central zone defined by Grütter et al. [Grütter, H.S., Apter, D.B., Kong, J., 1999. Crust–mantle coupling; evidence from mantle-derived xenocrystic garnets. Contributed paper at: The 7th International Kimberlite Conference Proceeding, J.B. Dawson Volume, 1, 307–313] on the basis of garnet geochemistry (G10 vs. G9) populations.

Deep-probing MT data from the lake bottom instruments infer that the conductor has a total depth-integrated conductivity (conductance) of the order of 2000 Siemens, which, given an internal resistivity of 10–15 Ω m, implies a thickness of 20–30 km. Below the CSMC the electrical resistivity of the lithosphere increases by a factor of 3–5 to values of around 50 Ω m. This change occurs at depths consistent with the graphite–diamond transition, which is taken as consistent with a carbon interpretation for the CSMC.

Preliminary three-dimensional MT modelling supports the NE–SW striking geometry for the conductor, and also suggests a NW dip. This geometry is taken as implying that the tectonic processes that emplaced this geophysical–geochemical body are likely related to the subduction of a craton of unknown provenance from the SE (present-day coordinates) during 2630–2620 Ma. It suggests that the lithospheric stacking model of Helmstaedt and Schulze [Helmstaedt, H.H., Schulze, D.J., 1989. Southern African kimberlites and their mantle sample: implications for Archean tectonics and lithosphere evolution. In Ross, J. (Ed.), Kimberlites and Related Rocks, Vol. 1: Their Composition, Occurrence, Origin, and Emplacement. Geological Society of Australia Special Publication, vol. 14, 358–368] is likely correct for the formation of the Slave's current SCLM.     

Petrological and geochronological constraints on high pressure, high temperature metamorphism in the Snowbird tectonic zone, Canada

The upper deck of the East Athabasca mylonite triangle (EAmt), northern Saskatchewan, Canada, contains mafic granulites that have undergone high P–T metamorphism at conditions ranging from 1.3 to 1.9 GPa, 890–960 °C. Coronitic textures in these mafic granulites indicate a near‐isothermal decompression path to 0.9 GPa, 800 °C. The Godfrey granite occurs to the north adjacent to the upper deck high P–T domain. Well‐preserved corona textures in the Godfrey granite constrain igneous crystallization and early metamorphism in the intermediate‐pressure granulite field (Opx + Pl) at 1.0 GPa, 775 °C followed by metamorphism in the high pressure granulite field (Grt + Cpx + Pl) at 1.2 GPa, 860 °C. U–Pb geochronology of zircon in upper deck mafic granulite yields evidence for events at both c. 2.5 Ga and c. 1.9 Ga. The oldest zircon dates are interpreted to constrain a minimum age for crystallization or early metamorphism of the protolith. A population of 1.9 Ga zircon in one mafic granulite is interpreted to constrain the timing of high P–T metamorphism. Titanite from the mafic granulites yields dates ranging from 1900 to 1894 Ma, and is interpreted to have grown along the decompression path, but still above its closure temperature, indicating cooling following the high P–T metamorphism from c. 960–650 °C in 4–10 Myr. Zircon dates from the Godfrey granite indicate a minimum crystallization age of 2.61 Ga, without any evidence for 1.9 Ga overgrowths. The data indicate that an early granulite facies event occurred at c. 2.55–2.52 Ga in the lower crust (c. 1.0 GPa), but at 1.9 Ga the upper deck underwent high P–T metamorphism, then decompressed to 0.9–1.0 GPa. Juxtaposition of the upper deck and Godfrey granite would have occurred after or been related to this decompression. In this model, the high P–T rocks are exhumed quickly following the high pressure metamorphism. This type of metamorphism is typically associated with collisional orogenesis, which has important implications for the Snowbird tectonic zone as a fundamental boundary in the Canadian Shield.     

A statistical approach to evaluating distance metrics and analog assignments for pollen records

The modern analog technique typically uses a distance metric to determine the dissimilarity between fossil and modern biological assemblages. Despite this quantitative approach, interpretation of distance metrics is usually qualitative and rules for selection of analogs tend to be ad hoc. We present a statistical tool, the receiver operating characteristic (ROC) curve, which provides a framework for identifying analogs from distance metrics. If modern assemblages are placed into groups (e.g., biomes), this method can (1) evaluate the ability of different distance metrics to distinguish among groups, (2) objectively identify thresholds of the distance metric for determining analogs, and (3) compute a likelihood ratio and a Bayesian probability that a modern group is an analog for an unknown (fossil) assemblage. Applied to a set of 1689 modern pollen assemblages from eastern North America classified into eight biomes, ROC analysis confirmed that the squared-chord distance (SCD) outperforms most other distance metrics. The optimal threshold increased when more dissimilar biomes were compared. The probability of an analog vs no-analog result (a likelihood ratio) increased sharply when SCD decreased below the optimal threshold, indicating a nonlinear relationship between SCD and the probability of analog. Probabilities of analog computed for a postglacial pollen record at Tannersville Bog (Pennsylvania, USA) identified transitions between biomes and periods of no analog.     

Chromite-plagioclase assemblages as a new shock indicator; implications for the shock and thermal histories of ordinary chondrites

Chromite in ordinary chondrites (OC) can be used as a shock indicator. A survey of 76 equilibrated H, L and LL chondrites shows that unshocked chromite grains occur in equant, subhedral and rounded morphologies surrounded by silicate or intergrown with metallic Fe-Ni and/or troilite. Some unmelted chromite grains are fractured or crushed during whole-rock brecciation. Others are transected by opaque veins; the veins form when impacts cause localized heating of metal-troilite intergrowths above the Fe-FeS eutectic (988°C), mobilization of metal-troilite melts, and penetration of the melt into fractures in chromite grains. Chromite-plagioclase assemblages occur in nearly every shock-stage S3-S6 OC; the assemblages range in size from 20-300 μm and consist of 0.2-20-μm-size euhedral, subhedral, anhedral and rounded chromite grains surrounded by plagioclase or glass of plagioclase composition. Plagioclase has a low impedance to shock compression. Heat from shock-melted plagioclase caused adjacent chromite grains to melt; chromite grains crystallized from this melt. Those chromite grains in the assemblages that are completely surrounded by plagioclase are generally richer in Al₂O₃ than unmelted, matrix chromite grains in the same meteorite. Chromite veinlets (typically 0.5-2 μm thick and 10-300 μm long) occur typically in the vicinity of chromite-plagioclase assemblages. The veinlets formed from chromite-plagioclase melts that were injected into fractures in neighboring silicate grains; chromite crystallized in the fractures and the residual plagioclase-rich melt continued to flow, eventually pooling to form plagioclase-rich melt pockets. Chromite-rich “chondrules” (consisting mainly of olivine, plagioclase-normative mesostasis, and 5-15 vol.% chromite) occur in many shocked OC and OC regolith breccias but they are absent from primitive type-3 OC. They may have formed by impact melting chromite, plagioclase and adjacent mafic silicates during higher-energy shock events. The melt was jetted from the impact site and formed droplets due to surface tension. Crystallization of these droplets may have commenced in flight, prior to landing on the parent-body surface.Chromite-plagioclase assemblages and chromite veinlets occur in 25 out of 25 shock-stage S1 OC of petrologic type 5 and 6 that I examined. Although these rocks contain unstrained olivine with sharp optical extinction, most possess other shock indicators such as extensive silicate darkening, numerous occurrences of metallic Cu, polycrystalline troilite, and opaque veins. It seems likely that these rocks were shocked to levels at least as high as shock-stage S3 and then annealed by heat generated during the shock event. During annealing, the olivine crystal lattices healed but other shock indicators survived. Published Ar-Ar age data for some S1 OC indicate that many shock and annealing events occurred very early in the history of the parent asteroids. The common occurrence of shocked and annealed OC is consistent with collisions being a major mechanism responsible for metamorphosing OC.     

Vanadium in peridotites as a proxy for paleo-fO2 during partial melting : prospects, limitations, and implications

The compatibility of vanadium (V) during mantle melting is a function of oxygen fugacity (fO₂): at high fO₂’s, V becomes more incompatible. The prospects and limitations of using the V content of peridotites as a proxy for paleo-fO₂ at the time of melt extraction were investigated here by assessing the uncertainties in V measurements and the sensitivity of V as a function of degree of melt extracted and fO₂. V-MgO and V-Al₂O₃ systematics were found to be sensitive to fO₂ variations, but consideration of the uncertainties in measurements and model parameters indicates that V is sensitive only to relative fO₂ differences greater than ∼2 log units. Post-Archean oceanic mantle peridotites, as represented by abyssal peridotites and obducted massif peridotites, have V-MgO and -Al₂O₃ systematics that can be modeled by 1.5 GPa melting between FMQ − 3 and FMQ − 1. This is consistent with fO₂’s of the mantle source for mid-ocean ridge basalts (MORBs) as determined by the Fe³⁺ activity of peridotitic minerals and basaltic glasses. Some arc-related peridotites have slightly lower V for a given degree of melting than oceanic mantle peridotites, and can be modeled by 1.5 GPa melting at fO₂’s as high as FMQ. However, the majority of arc-related peridotites have V-MgO systematics overlapping that of oceanic mantle peridotites, suggesting that although some arc mantle may melt under slightly oxidizing conditions, most arc mantle does not. The fact that thermobarometrically determined fO₂’s in arc peridotites and lavas can be significantly higher than that inferred from V systematics, suggests that V retains a record of the fO₂ during partial melting, whereas the activity of Fe³⁺ in arc peridotitic minerals and lavas reflect subsequent metasomatic overprints and magmatic differentiation/emplacement processes, respectively.Peridotites associated with middle to late Archean cratonic mantle are characterized by highly variable V-MgO systematics. Tanzanian cratonic peridotites have V systematics indistinguishable from post-Archean oceanic mantle and can be modeled by 3 GPa partial melting at ∼FMQ − 3. In contrast, many South African and Siberian cratonic peridotites have much lower V contents for a given degree of melting, suggesting at first glance that partial melting occurred at high fO₂’s. More likely, however, their unusually low V contents for a given degree of melting may be artifacts of excess orthopyroxene, a feature that pervades many South African and Siberian peridotites but not the Tanzanian peridotites. This is indicated by the fact that the V contents of South African and Siberian peridotites are correlated with increases in SiO₂ content, generating data arrays that cannot be modeled by partial melting but can instead be generated by the addition of orthopyroxene through processes unrelated to primary melt depletion. Correction for orthopyroxene addition suggests that the South African and Siberian peridotites have V-MgO systematics similar to those of Tanzanian peridotites. Thus, if the Tanzanian peridotites represent the original partial melting residues, and if the South African and Siberian peridotites have been modified by orthopyroxene addition, then there is no indication that Archean cratonic mantle formed under fO₂’s significantly greater than that of modern oceanic mantle. Instead, the fO₂’s inferred from the V systematics in these three cratonic peridotite suites are within range of modern oceanic mantle. This also suggests that the transition from a highly reducing mantle in equilibrium with a metallic core to the present oxidized state must have occurred by late Archean times.     

Paleoclimate reconstruction based on the timing of speleothem growth and oxygen and carbon isotope composition in a cave located in the rain shadow in Israel

High-resolution ²³⁰Th/²³⁴U ages and δ¹⁸O and δ¹³C compositions of speleothems in Ma’ale Efrayim Cave located to the east of the central mountain ridge of Israel enable us to examine the nature of the rain shadow aridity during glacial and interglacial intervals. Speleothem growth occurred during marine glacial isotopic periods, with no growth during the two last marine isotope interglacial intervals and during the peak of the Last Glacial Maximum. This contrasts with speleothem growth in caves located on the western flank of the central mountain ridge, in the Eastern Mediterranean semiarid climatic zone, which continued throughout the last 240,000 yr. Thus, during glacial periods water reached both sides of the central mountain ridge. A comparison of the present-day rain and cave water isotopic compositions and amounts at the Ma’ale Efrayim Cave site with those on the western flank shows that evaporation and higher temperatures on the eastern flank are major influences on isotopic composition and the lack of rainfall. The δ¹⁸O and δ¹³C profiles of the speleothems deposited between 67,000 and 25,000 yr B.P. match the general trends of the isotopic profiles of Soreq Cave speleothems, suggesting a similar source (eastern Mediterranean Sea) and similar climatic conditions. Thus, during glacial periods the desert boundary effectively migrated further south or east from its present-day location on the eastern flank, whereas interglacial periods appear to have been similar to the present, with the desert boundary at the same position. The decrease in overall temperature and a consequent reduction in the evaporation to precipitation ratios on the eastern flank are viewed as the major factors controlling the decay of the rain shadow effect during glacial periods.     

Recent advances in accessibility research: Representation,methodology and applications

 In this article we examine recent advances in accessibility research and their implications for future studies. We base our discussion on three intersecting dimensions that are useful for evaluating the contribution of recent studies: representation, methodology and applications. Various examples are selected to show that research concerned with representation and methodological problem solving is often applied to issues of broad concern in policy and planning. It is, however, not clear that the simultaneous treatment of representation, methodological and application issues has ever been fully worked out. The questions raised in this article may serve as a foundation for addressing issues pertinent to accurate representation, improved model building, and more rigorous applications in accessibility research. Received: 9 December 2002 / Accepted: 10 February 2003     

Yucatán karst features and the size of Chicxulub crater

The buried Chicxulub impact structure is marked by a dramatic ring of sinkholes (called cenotes if containing water), and adjacent less prominent partial rings, which have been shown to coincide with maxima in horizontal gravity gradients and a topographic depression. These observations, along with the discreteness and spacing of the features, suggest a formation mechanism involving faulting in the outer slump zone of the crater, which would thus have a diameter of approximately 180 km.
An opposing view, based primarily on the interpretation of gravity data, is that (he crater is much larger than the cenote ring implies. Given the association of the known cenote ring with faults, we here examine northern Yucatan for similar rings in gravity, surface features and elevation, which we might expect to be associated with outer concentric faults in the case of a larger, possibly multiring, structure.
No such outer rings have been found, although definite patterns are seen in the distribution of karst features outside the crater rim. We explain these patterns as resulting mainly from deformation related to the block fault zone that parallels tbe shelf edge of eastern Yucatan.