Relationships among intrinsic properties of ordinary chondrites: Oxidation state, bulk chemistry, oxygen-isotopic composition, petrologic type, and chondrule size

The properties of ordinary chondrites (OC) reflect both nebular and asteroidal processes. OC are modeled here as having acquired nebular water, probably contained within phyllosilicates, during agglomeration. This component had high Δ¹⁷O and acted like an oxidizing agent during thermal metamorphism. The nebular origin of this component is consistent with negative correlations in H, L, and LL chondrites between oxidation state (represented by olivine Fa) and bulk concentration ratios of elements involved in the metal-silicate fractionation (e.g., Ni/Si, Ir/Si, Ir/Mn, Ir/Cr, Ir/Mg, Ni/Mg, As/Mg, Ga/Mg). LL chondrites acquired the greatest abundance of phyllosilicates with high Δ¹⁷O among OC (and thus became the most oxidized group and the one with the heaviest O isotopes); H chondrites acquired the lowest abundance, becoming the most reduced OC group with the lightest O isotopes.Chondrule precursors may have grown larger and more ferroan with time in each OC agglomeration zone. Nebular turbulence may have controlled the sizes of chondrule precursors. H-chondrite chondrules (which are the smallest among OC) formed from the smallest precursors. In each OC region, low-FeO chondrules formed before high-FeO chondrules during repeated episodes of chondrule formation.During thermal metamorphism, phyllosilicates were dehydrated; the liberated water oxidized metallic Fe-Ni. This caused correlated changes with petrologic type including decreases in the modal abundance of metal, increases in olivine Fa and low-Ca pyroxene Fs, increases in the olivine/pyroxene ratio, and increases in the kamacite Co and Ni contents. As water (with its heavy O isotopes) was lost during metamorphism, inverse correlations between bulk δ¹⁸O and bulk δ¹⁷O with petrologic type were produced.The H5 chondrites that were ejected from their parent body ∼7.5 Ma ago during a major impact event probably had been within a few kilometers of each other since they accreted ∼4.5 Ga ago. There are significant differences in the olivine compositional distributions among these rocks; these reflect stochastic nebular sampling of the oxidant (i.e., phyllosilicates with high Δ¹⁷O) on a 0.1-1 km scale during agglomeration.     

Elastoplastic model with loading memory surfaces (LMS) for monotonic and cyclic behaviour of geomaterials

A new elastoplastic model called loading memory surface based on the critical state concept and the multi‐surface framework is proposed for geomaterials. The model uses a hypoelastic formulation and two plastic mechanisms. The formulations of the model are made in three‐dimensional stress–strain space and work under both monotonic and cyclic loadings. A newly introduced formalism makes it possible to obtain the cyclic response directly from the monotonic loading one. This formalism gives a three‐dimensional generalization of the well‐known Masing rule. The model has been validated against test results of Hostun sand under several conditions: monotonic and cyclic, drained and undrained, tests in compression and in extension, and at different confining pressures and different densities. Copyright © 2014 John Wiley & Sons, Ltd.     

A middle–late Ediacaran volcano‐sedimentary record from the eastern Arabian‐Nubian shield

The Ediacaran Jibalah Group comprises volcano‐sedimentary successions that filled small fault‐bound basins along the NW–SE‐trending Najd fault system in the eastern Arabian‐Nubian Shield. Like several other Jibalah basins, the Antaq basin contains exquisitely preserved sedimentary structures and felsic tuffs, and hence is an excellent candidate for calibrating late Ediacaran Earth history. Shallow‐marine strata from the upper Jibalah Group (Muraykhah Formation) contain a diversity of load structures and intimately related textured organic (microbial) surfaces, along with a fragment of a structure closely resembling an Ediacaran frond fossil and a possible specimen of Aspidella. Interspersed carbonate beds through the Muraykhah Formation record a positive δ¹³C shift from ?6 to 0‰. U‐Pb zircon geochronology indicates a maximum depositional age of ~570 Ma for the upper Jibalah Group, consistent with previous age estimates. Although this age overlaps with that of the upper Huqf Supergroup in nearby Oman, these sequences were deposited in contrasting tectonic settings on opposite sides of the final suture of the East African Orogen.     

A parallel algorithm for coverage optimization on multi-core architectures

Location siting is an important part of service provision, with much potential to impact operational efficiency, safety, security, system reliability, etc. A class of location models seeks to optimize coverage of demand for service that is continuously distributed across space. Decision-making and planning contexts include police/fire resource allocation for a community, siting cellular towers to support cell phone signal transmission, locating emergency warning sirens to alert the public of severe weather and other related dangers, and many others as well. When facilities can be sited anywhere in continuous space to provide coverage to an entire region, this is a very computationally challenging problem to solve because potential demand for service is everywhere and there are an infinite number of potential facility sites to consider. This article develops a new parallel solution approach for this location coverage optimization problem through an iterative bounding scheme on multi-core architectures. The developed approach is applied to site emergency warning sirens in Dublin, Ohio, and fire stations in Elk Grove, California. Results demonstrate the effectiveness and efficiency of the proposed approach, enabling real-time analysis and planning. This work illustrates that the integration of cyberinfrastructure can significantly improve computational efficiency in solving challenging spatial optimization problems, fitting the themes of this special issue: cyberinfrastructure, GIS, and spatial optimization.     

Impact of irrigated agriculture on groundwater-recharge salinity: a major sustainability concern in semi-arid regions

Intensive irrigated agriculture substantially modifies the hydrological cycle and often has major environmental impacts. The article focuses upon a specific concern—the tendency for progressive long-term increases in the salinity of groundwater recharge derived from irrigated permeable soils and replenishment of unconfined aquifers in more arid regions. This process has received only scant attention in the water-resource literature and has not been considered by agricultural science. This work makes an original contribution by analysing, from scientific principles, how the salinisation of groundwater recharge arises and identifies the factors affecting its severity. If not proactively managed, the process eventually will impact irrigation waterwell salinity, the productivity of agriculture itself, and can even lead to land abandonment. The types of management measure required for mitigation are discussed through three detailed case histories of areas with high-value groundwater-irrigated agriculture (in Spain, Argentina and Pakistan), which provide a long-term perspective on the evolution of the problem over various decades.     

Depositional setting,provenance, and tectonic-volcanic setting of Eocene–Recent deep-sea sediments of the oceanic Izu–Bonin forearc,northwest Pacific (IODP Expedition 352)

New biostratigraphical, geochemical, and magnetic evidence is synthesized with IODP Expedition 352 shipboard results to understand the sedimentary and tectono-magmatic development of the Izu–Bonin outer forearc region. The oceanic basement of the Izu–Bonin forearc was created by supra-subduction zone seafloor spreading during early Eocene (c. 50–51 Ma). Seafloor spreading created an irregular seafloor topography on which talus locally accumulated. Oxide-rich sediments accumulated above the igneous basement by mixing of hydrothermal and pelagic sediment. Basaltic volcanism was followed by a hiatus of up to 15 million years as a result of topographic isolation or sediment bypassing. Variably tuffaceous deep-sea sediments were deposited during Oligocene to early Miocene and from mid-Miocene to Pleistocene. The sediments ponded into extensional fault-controlled basins, whereas condensed sediments accumulated on a local basement high. Oligocene nannofossil ooze accumulated together with felsic tuff that was mainly derived from the nearby Izu–Bonin arc. Accumulation of radiolarian-bearing mud, silty clay, and hydrogenous metal oxides beneath the carbonate compensation depth (CCD) characterized the early Miocene, followed by middle Miocene–Pleistocene increased carbonate preservation, deepened CCD and tephra input from both the oceanic Izu–Bonin arc and the continental margin Honshu arc. The Izu–Bonin forearc basement formed in a near-equatorial setting, with late Mesozoic arc remnants to the west. Subduction-initiation magmatism is likely to have taken place near a pre-existing continent–oceanic crust boundary. The Izu–Bonin arc migrated northward and clockwise to collide with Honshu by early Miocene, strongly influencing regional sedimentation.