Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.     

Late Cenozoic transpressional ductile deformation north of the Nazca–South America–Antarctica triple junction

The southern Andes plate boundary zone records a protracted history of bulk transpressional deformation during the Cenozoic, which has been causally related to either oblique subduction or ridge collision. However, few structural and chronological studies of regional deformation are available to support one hypothesis or the other. We address along- and across-strike variations in the nature and timing of plate boundary deformation to better understand the Cenozoic tectonics of the southern Andes.Two east–west structural transects were mapped at Puyuhuapi and Aysén, immediately north of the Nazca–South America–Antarctica triple junction. At Puyuhuapi (44°S), north–south striking, high-angle contractional and strike-slip ductile shear zones developed from plutons coexist with moderately dipping dextral-oblique shear zones in the wallrocks. In Aysén (45–46°), top to the southwest, oblique thrusting predominates to the west of the Cenozoic magmatic arc, whereas dextral strike-slip shear zones develop within it.New ⁴⁰Ar–³⁹Ar data from mylonites and undeformed rocks from the two transects suggest that dextral strike-slip, oblique-slip and contractional deformation occurred at nearly the same time but within different structural domains along and across the orogen. Similar ages were obtained on both high strain pelitic schists with dextral strike-slip kinematics (4.4±0.3 Ma, laser on muscovite–biotite aggregates, Aysén transect, 45°S) and on mylonitic plutonic rocks with contractional deformation (3.8±0.2 to 4.2±0.2 Ma, fine-grained, recrystallized biotite, Puyuhuapi transect). Oblique-slip, dextral reverse kinematics of uncertain age is documented at the Canal Costa shear zone (45°S) and at the Queulat shear zone at 44°S. Published dates for the undeformed protholiths suggest both shear zones are likely Late Miocene or Pliocene, coeval with contractional and strike-slip shear zones farther north. Coeval strike-slip, oblique-slip and contractional deformation on ductile shear zones of the southern Andes suggest different degrees of along- and across-strike deformation partitioning of bulk transpressional deformation.The long-term dextral transpressional regime appears to be driven by oblique subduction. The short-term deformation is in turn controlled by ridge collision from 6 Ma to present day. This is indicated by most deformation ages and by a southward increase in the contractional component of deformation. Oblique-slip to contractional shear zones at both western and eastern margins of the Miocene belt of the Patagonian batholith define a large-scale pop-up structure by which deeper levels of the crust have been differentially exhumed since the Pliocene at a rate in excess of 1.7 mm/year.     

Scenario Reduction Applied to Geostatistical Simulations

Having a large number of geostatistical simulations of a mineral or petroleum deposit provides a better idea of its upside potential and downside risk; however, large numbers of simulated realizations of a deposit may pose computational difficulties in subsequent decision-making phases. Hence, depending on the specific case, there can be a need to select a representative subset of conditionally simulated deposit realizations. This paper examines and extends an approach developed by the stochastic optimization community based on stochastic mathematical programming with recourse and is discussed here in the context of mineral deposits while it is possibly suitable for other earth science applications. The approach is based on measuring the “distance” between simulations and the introduced distance measure between simulated realizations of a mineral deposit is based on the metal above a given set of cutoff grades while a pre-existing mine design is available. The approach is tested on 100 simulations of the Walker Lake data with promising results.     

Comparative studies on compounds occluded inside asphaltenes hierarchically released by increasing amounts of H2O2/CH3COOH

Being the heaviest fraction of crude oils, asphaltenes are liable to aggregate, and other molecules in the oils can be steadily adsorbed onto, and even occluded inside the macromolecular structures of the asphaltenes. These occluded compounds inside the asphaltenes can survive over geological time in oil reservoirs owing to effective protection by the macromolecular structures of the asphaltenes. The asphaltenes of a crude oil (ZG31) from the central Tarim Basin, NW China, were hierarchically degraded by increasing the amount of H₂O₂/CH₃COOH to release the occluded compounds. Besides the common components, series of even numbered n-alk-1-enes and 3-ethylalkanes were detected among the occluded compounds. Comparison of the biomarker distributions and the compound-specific C isotopic results between the compounds from the maltenes and those from the occluded fraction, the ZG31 reservoir was suggested to have been charged multiple times, with different charges being derived from different strata of source rocks.     

Conflicting structural and geochronological data from the Ibituruna quartz-syenite (SE Brazil): Effect of protracted “hot” orogeny and slow cooling rate?

The Ibituruna quartz-syenite was emplaced as a sill in the Ribeira-Araçuaí Neoproterozoic belt (Southeastern Brazil) during the last stages of the Gondwana supercontinent amalgamation. We have measured the Anisotropy of Magnetic Susceptibility (AMS) in samples from the Ibituruna sill to unravel its magnetic fabric that is regarded as a proxy for its magmatic fabric. A large magnetic anisotropy, dominantly due to magnetite, and a consistent magnetic fabric have been determined over the entire Ibituruna massif. The magmatic foliation and lineation are strikingly parallel to the solid-state mylonitic foliation and lineation measured in the country-rock. Altogether, these observations suggest that the Ibituruna sill was emplaced during the high temperature (~ 750 °C) regional deformation and was deformed before full solidification coherently with its country-rock. Unexpectedly, geochronological data suggest a rather different conclusion. LA-ICP-MS and SHRIMP ages of zircons from the Ibituruna quartz-syenite are in the range 530–535 Ma and LA-ICP-MS ages of zircons and monazites from synkinematic leucocratic veins in the country-rocks suggest a crystallization at ~ 570–580 Ma, i.e., an HT deformation > 35My older than the emplacement of the Ibituruna quartz-syenite. Conclusions from the structural and the geochronological studies are therefore conflicting. A possible explanation arises from ⁴⁰Ar–³⁹Ar thermochronology. We have dated amphiboles from the quartz-syenite, and amphiboles and biotites from the country-rock. Together with the ages of monazites and zircons in the country-rock, ⁴⁰Ar–³⁹Ar mineral ages suggest a very low cooling rate: < 3 °C/My between 570 and ~ 500 Ma and ~ 5 °C/My between 500 and 460 Ma. Assuming a protracted regional deformation consistent over tens of My, under such stable thermal conditions the fabric and microstructure of deformed rocks may remain almost unchanged even if they underwent and recorded strain pulses separated by long periods of time. This may be a characteristic of slow cooling “hot orogens” that rocks deformed at significantly different periods during the orogeny, but under roughly unchanged temperature conditions, may display almost indiscernible microstructure and fabric.     

Caractérisation des chapeaux de fer en milieu latéritique cuirassé

The main discrimination criteria between the gossans and ferruginous laterites are the iron secondary minerals, well known as direct crystallization after weathering of the main sulphide minerals. The characteristics of these iron oxihydroxides and their association in supergene rocks affect all the physical, mineralogical, geochemical, and crystal-chemical aspects: morphology, facies, microfacies, mineralogical constitution, geochemical composition and iron oxide/hydroxide crystal chemistry give thus distinction criteria. In West Africa, where lateritic iron crusts are abundant, the research of the above characteristics could be an alternative method to the classical blind-soil and alluvial-sediment geochemical prospecting. To cite this article: A. Blot, C. R. Geoscience 336 (2004).