Investigation of cutting methods for small samples of Hayabusa and future sample return missions

We report the investigation of cutting methods for Hayabusa samples. The purpose of our study is to explore the possibility of applying multiple analyses to a single particle effectively. We investigated the cutting performance of a blade dicing saw, laser, focused ion beam (FIB), and physical breaking by microindenter. Cutting performance was examined by estimating the aspect ratio of the cut slit, i.e., depth over width of the slit. We also investigated the possible contamination and sample damage by cutting. The result of the investigation shows that we can cut the samples from <50 μm to 500 μm using those methods with aspect ratios from 10 to 20, although they would introduce some contamination or damage to the samples. Our investigations also provide an important basis for the analysis of samples obtained by future sample return missions.     

Sulfate reduction and sulfur fixation in sediment of a historically meromictic lake,Lake Suigetsu,Japan

Vertical distributions of sulfate, hydrogen sulfide, and iron (II) concentrations in interstitial waters and of sulfur content in sediment have been studied in a sediment core (73 cm long) from a meromictic lake, Lake Suigetsu, which changed from fresh-water to brackish conditions in 1664 A.D. The diatom assemblage of the sediment has also been analyzed. A boundary between high (>1.5%) and low (<0.2%) sulfur contents is found at a depth of 52 cm in the core. In the high sulfur layer (above 52 cm), the maximum sulfur content is 6.8% at 35 to 37 cm. The diatom assemblage, however, indicates that the boundary between fresh-water and brackish sediments lies at 40 cm. The hydrogen sulfide and iron (II) profiles in the interstitial waters indicate a sink for these chemical species near a depth of 40 cm. The discrepancy between the chemically-defined boundary at 52 cm and the paleontologically-defined boundary at 40 cm seems to be due to the downward migration of hydrogen sulfide and deposition of iron sulfide after the lake became brackish.     

Production of the Blood Pressure Lowing Peptides from Brown Alga （ Undaria pinnatifida ）

Brown alga （ Undaria pinnatifida） was treated with alginate lyase and hydrolyzed using 17 kinds of proteases and the inhibitory activity of the hydrolysates for the angiotensin-I-converting enzyme （ACE） was measured. Four hydrolysates with potent ACE-inhibitory activity were administered singly and orally to spontaneously hypertensive rats （SHRs）. The systolic blood pressure of SHRs decreases significantly after single oral administration of the brown alga hydrolysates by pro- tease S ＇ Amano＇ （from Bacillus stearothermophilus） at the concentration of 10 （mg protein） （kg body weight）^ - 1. In the 17 weeks of feeding experiment, 7-week-old SHRs were fed standard diet supplemented with the brown alga hydrolysates for 10 weeks. In SHRs fed 1.0 and 0.1% brown alga hydrolysates, elevating of systolic bloodpressure was significantly suppressed for 7 weeks. To elucidate the active components, the brown alga hydrolysates were fractionated by 1-butanol extraction and HPLC on a reverse-phase column. Seven kinds of ACE-inhibitory peptides were isolated and identified by amino acid composition analysis, sequence analysis, and LC-MS with the results Val-Tyr, Ile-Tyr, Ala-Trp, Phe-Tyr, Val-Trp, Ile-Trp, and Leu-Trp. Each peptide was determined to have an antihypertensive effect after a single oral administration in SHRs. The brown alga hydrolysates were also confirmed to decrease the blood pressure in humans.     

Sensitivity of the central Asian climate to uplift of the Tibetan Plateau in the coupled climate model (MRI-CGCM1)

Abstract   The relationship between the altitude of the Tibetan Plateau and climate change in central Asia was investigated through a numeric experiment using the Meteorological Research Institute (MRI) coupled atmosphere–ocean general circulation model I (MRI-CGCM1). The results suggest that summer precipitation in central Asia decreased significantly as the Tibetan Plateau rose in height. Spring precipitation, however, increased during initial growth stages when the plateau height was up to 40% of its present-day height, and then decreased with further plateau growth. During the Tibetan Plateau uplift, the difference between precipitation and evaporation was minimal during spring. When the plateau attained a height exceeding 60% of its present height, relatively low precipitation but high evaporation in spring led to a lower amount of ground moisture. In the case of the high plateau, sensible heat flux during summer and fall largely exceeded latent heat flux. Change was particularly significant for cases when the plateau reached 40–60% of its present-day height. The duration of the predominant sensible heat flux became longer with the uplift of the Tibetan Plateau. The period in which latent heat exceeded sensible heat seems to have been restricted to winter and early spring. The numeric experiments suggest that a significant drying of central Asia corresponded to the period in which the Tibetan Plateau exceeded approximately half its present-day height.     

Intercomparison and analyses of the climatology of the West African Monsoon in the West African Monsoon Modeling and Evaluation project (WAMME) first model intercomparison experiment

This paper briefly presents the West African Monsoon (WAM) Modeling and Evaluation Project (WAMME) and evaluates WAMME general circulation models’ (GCM) performances in simulating variability of WAM precipitation, surface temperature, and major circulation features at seasonal and intraseasonal scales in the first WAMME experiment. The analyses indicate that models with specified sea surface temperature generally have reasonable simulations of the pattern of spatial distribution of WAM seasonal mean precipitation and surface temperature as well as the averaged zonal wind in latitude-height cross-section and low level circulation. But there are large differences among models in simulating spatial correlation, intensity, and variance of precipitation compared with observations. Furthermore, the majority of models fail to produce proper intensities of the African Easterly Jet (AEJ) and the tropical easterly jet. AMMA Land Surface Model Intercomparison Project (ALMIP) data are used to analyze the association between simulated surface processes and the WAM and to investigate the WAM mechanism. It has been identified that the spatial distributions of surface sensible heat flux, surface temperature, and moisture convergence are closely associated with the simulated spatial distribution of precipitation; while surface latent heat flux is closely associated with the AEJ and contributes to divergence in AEJ simulation. Common empirical orthogonal functions (CEOF) analysis is applied to characterize the WAM precipitation evolution and has identified a major WAM precipitation mode and two temperature modes (Sahara mode and Sahel mode). Results indicate that the WAMME models produce reasonable temporal evolutions of major CEOF modes but have deficiencies/uncertainties in producing variances explained by major modes. Furthermore, the CEOF analysis shows that WAM precipitation evolution is closely related to the enhanced Sahara mode and the weakened Sahel mode, supporting the evidence revealed in the analysis using ALMIP data. An analysis of variability of CEOF modes suggests that the Sahara mode leads the WAM evolution, and divergence in simulating this mode contributes to discrepancies in the precipitation simulation.     

Suppression of Matrix Effects in ICP-MS by High Power Operation of ICP: Application to Precise Determination of Rb, Sr, Y, Cs, Ba, REE, Pb, Th and U at ng g-1 Levels in Milligram Silicate Samples

We found that the suppression of signals for ⁸⁸Sr, ¹⁴⁰Ce and ²³⁸U in rock solution caused by rock matrix in ICP-MS (matrix effects) was reduced at high power operation (1.7 kW) of the ICP. To make the signal suppression by the matrix negligible, minimum dilution factors (DF) of the rock solution for Sr, Ce and U were 600, 400 and 113 at 1.1, 1.4 and 1.7 kW, respectively. Based on these findings, a rapid and precise determination method for Rb, Sr, Y, Cs, Ba, REE, Pb, Th and U using FI (flow injection)-ICP-MS was developed. The amount of the sample solution required for FI-ICP-MS was 0.2 ml, so that 1.8 mg sample was sufficient for analysis with a detection limit of several ng g^-1. Using this method, we determined the trace element concentrations in the USGS rock reference materials, DTS-1, PCC-1, BCR-1 and AGV-1, and the GSJ rock reference materials, JP-1, JB-1, -2, -3, JA-1, -2 and -3. The reproducibilities (RSD %) in replicate analyses (n=5) of BCR-1, AGV-1, JB-1, -2, -3, JA-1, -2, and -3 were < 6 %, and typically 2.5%. The difference between the average concentrations of this study for BCR-1 and those of the reference values were < 2%. Therefore, it was concluded that the method can give reliable data for trace elements in silicate rocks.     

Effects of scattering and dust grain size on the temperature structure of protoplanetary discs: a three-layer approach

The temperature in the optically thick interior of protoplanetary discs is essential for the interpretation of millimetre observations of the discs, for the vertical structure of the discs, for models of the disc evolution and the planet formation, and for the chemistry in the discs. Since large icy grains have a large albedo even in the infrared, the effect of scattering of the diffuse radiation in the discs on the interior temperature should be examined. We have performed a series of numerical radiation transfer simulations, including isotropic scattering by grains with various typical sizes for the diffuse radiation as well as for the incident stellar radiation. We also have developed an analytic model including isotropic scattering to understand the physics concealed in the numerical results. With the analytic model, we have shown that the standard two-layer approach is valid only for grey opacity (i.e. grain size ≳10 μm) even without scattering. A three-layer interpretation is required for grain size ≲10 μm. When the grain size is 0.1–10 μm, the numerical simulations show that the isotropic scattering reduces the temperature of the disc interior. This reduction is nicely explained by the analytic three-layer model as a result of the energy loss by scatterings of the incident stellar radiation and of the warm diffuse radiation in the disc atmosphere. For grain size ≳10 μm (i.e. grey scattering), the numerical simulations show that the isotropic scattering does not affect the interior temperature. This is nicely explained by the analytic two-layer model; the energy loss by scattering in the disc atmosphere is exactly offset by the 'green-house effect' due to the scattering of the cold diffuse radiation in the interior.     

Application of spectral decomposition algorithm for mapping water quality in a turbid lake (Lake Kasumigaura,Japan) from Landsat TM data

The remote sensing of Case 2 water has been far less successful than that of Case 1 water, due mainly to the complex interactions among optically active substances (e.g., phytoplankton, suspended sediments, colored dissolved organic matter, and water) in the former. To address this problem, we developed a spectral decomposition algorithm (SDA), based on a spectral linear mixture modeling approach. Through a tank experiment, we found that the SDA-based models were superior to conventional empirical models (e.g. using single band, band ratio, or arithmetic calculation of band) for accurate estimates of water quality parameters. In this paper, we develop a method for applying the SDA to Landsat-5 TM data on Lake Kasumigaura, a eutrophic lake in Japan characterized by high concentrations of suspended sediment, for mapping chlorophyll-a (Chl-a) and non-phytoplankton suspended sediment (NPSS) distributions. The results show that the SDA-based estimation model can be obtained by a tank experiment. Moreover, by combining this estimation model with satellite-SRSs (standard reflectance spectra: i.e., spectral end-members) derived from bio-optical modeling, we can directly apply the model to a satellite image. The same SDA-based estimation model for Chl-a concentration was applied to two Landsat-5 TM images, one acquired in April 1994 and the other in February 2006. The average Chl-a estimation error between the two was 9.9%, a result that indicates the potential robustness of the SDA-based estimation model. The average estimation error of NPSS concentration from the 2006 Landsat-5 TM image was 15.9%. The key point for successfully applying the SDA-based estimation model to satellite data is the method used to obtain a suitable satellite-SRS for each end-member.     

Future Projections of Precipitation Characteristics in East Asia Simulated by the MRI CGCM2

Projected changes in precipitation characteristics around the mid-21st century and end-of-the-century are analyzed using the daily precipitation output of the 3-member ensemble Meteorological Research Institute global ocean-atmosphere coupled general circulation model (MRI-CGCM2) simulations under the Special Report on Emissions Scenarios (SRES) A2 and B2 scenarios. It is found that both the frequency and intensity increase in about 40% of the globe, while both the frequency and intensity decrease in about 20% of the globe. These numbers differ only a few percent from decade to decade of the 21st century and between the A2 and B2 scenarios. Over the rest of the globe (about one third), the precipitation frequency decreases but its intensity increases, suggesting a shift of precipitation distribution toward more intense events by global warming. South China is such a region where the summertime wet-day frequency decreases but the precipitation intensity increases. This is related to increased atmospheric moisture content due to global warming and an intensified and more westwardly extended North Pacific subtropical anticyclone, which may be related with an E1 Nin^-o-like mean sea surface temperature change. On the other hand, a decrease in summer precipitation is noted in North China, thus augmenting a south-to-north precipitation contrast more in the future.