Mixing states of cloud interstitial particles between water-soluble and insoluble materials at Mt. Tateyama,Japan: Effects of meteorological conditions

Mixing states of cloud interstitial particles between water-soluble and insoluble materials apparently differ under various cloud-forming conditions. To study the mixing states of cloud interstitial particles, we made observations at Mt. Tateyama, Japan (2300 m a.s.l.) during June 2007 using fog (> 10 μm)-cut inlets. Number concentrations of dried particles (0.3–0.5 μm diameter) selected for less-grown (LG) particles (particles smaller than 0.56 μm diameter at 88% relative humidity) were used to quantify tendencies of the growth characteristics of cloud interstitial particles. Size-segregated soot mass concentrations (< 0.4 and < 1.1 μm) were also measured for cloud interstitial particles. Three samples of cloud interstitial LG particles at 88% RH were investigated for water-soluble and insoluble components using dialysis (extraction) of water-soluble materials with transmission electron microscopy (TEM). For one TEM sample with high fractions of the LG particles and high soot mass concentrations under high precipitation (2–6 mm/h), most particles (0.1–0.5 μm) were found to be water insoluble. More than half of the water-insoluble particles were considered to be soot particles showing chain aggregations of electron-opaque spherules. Regarding the other two TEM samples with low fractions of the LG particles under less intense precipitation (ca. 1 mm/h), most particles were partly water soluble. The scavenging process in the precipitating cloud can change the population of particles left behind, preferentially leaving insoluble particles according to cloud formation conditions.     

Compression behaviors of distorted rutile-type hydrous phases, MOOH (M?=?Ga, In, Cr) and CrOOD

X-ray diffraction measurements of distorted rutile-type oxyhydroxides β-GaOOH, InOOH, β-CrOOH, and β-CrOOD were taken at a maximum pressure of up to 35 GPa under quasi-hydrostatic conditions, at ambient temperature. Anomalies in the evolution of the relative lattice constants and the axial ratios of β-GaOOH, InOOH, and β-CrOOD suggest anisotropic stiffening along the a- and/or b-axes where the hydrogen bond is formed. The changes were observed at 15 GPa in β-GaOOH and InOOH and at 4 GPa in β-CrOOD. The pressures were higher in oxyhydroxides that have longer O…O distances of the hydrogen bond at ambient pressure. In contrast, such stiffening behavior was not observed in CrOOH, which has a significant short O…O distance and strong hydrogen bond. The stiffening behaviors observed in the present study can be attributed to the symmetrization of the hydrogen bonds in oxyhydroxides, as was previously found in δ-AlOOH(D).     

A model not requiring continuous lithosphere for anomalous high-frequency arrivals from deep-focus South American earthquakes

Various workers have constructed models to explain a class of anomalous arrivals at Peruvian and Chilean stations from deep-focus South American earthquakes. These arrivals are shear waves with a later arrival time, a higher frequency content, a longer duration and a lower apparent velocity than direct S. Our models assume that there is a sufficiently sharp discontinuity at the upper interface of the descending lithospheric slab between depths of 80 and 250 km to provide efficient reflection (≈0.1) for S-waves incident from below. The observed travel times require a single S-to-S reflection at this interface if the J-B velocity-depth model is modified to allow for 7% higher velocities down to a depth of 300 km (excluding the crust). The locus of required reflection points correlates well with the upper boundary of the observed seismicity (strike and dip angles within 5°) and Q for the proposed path is consistent with the frequency content of the anomalous arrivals. Thus the existence of these arrivals requires a dipping interface down to about 250 km, but, contrary to the wave-guide model of Isacks and Barazangi, cannot be used to infer a continuous lithospheric slab down to the deep-focus earthquakes (h #62; 500 km).     

High-pressure phase behavior of MnTiO<Subscript>3</Subscript>: decomposition of perovskite into MnO and MnTi<Subscript>2</Subscript>O<Subscript>5</Subscript>

The phase relations and compression behavior of MnTiO₃ perovskite were examined using a laser-heated diamond-anvil cell, X-ray diffraction, and analytical transmission electron microscopy. The results show that MnTiO₃ perovskite becomes unstable and decomposes into MnO and orthorhombic MnTi₂O₅ phases at above 38 GPa and high temperature. This is the first example of ABO₃ perovskite decomposing into AO + AB₂O₅ phases at high pressure. The compression behavior of volume, axes, and the tilting angle of TiO₆ octahedron of MnTiO₃ perovskite are consistent with those of other A²⁺B⁴⁺O₃ perovskites, although no such decomposition was observed in other perovskites. FeTiO₃ is also known to decompose into two phases, instead of transforming into the CaIrO₃-type post-perovskite phase and we argue that one of the reasons for the peculiar behavior of titanate is the weak covalency of the Ti–O chemical bonds.     

CHEMICAL COMPOSITION,PETROGRAPHY AND MINERALOGY OF THE SHIBAYAMA CHONDRITE FOUND IN SHIBAYAMA-MACHI,SANBU-GUN,CHIBA-KEN,JAPAN

In April 1969, the chondrite was accidentally found in the side wall of the vegetable storage excavated at Shibayama-machi, Sanbu-gun, Chiba-ken, Japan, by Mr. A. Ishii and his grandson, Mr. S. Ito. The chondrite named Shibayama has been weathered thoroughly for a long period of burial underground. The bulk chemical composition, especially total Fe (21.41%) and ratios of Fe_total/SiO₂(0.557), SiO₂/MgO (1.59) and molar composition of olivine (Fa₂₃) and pyroxene (Fs₂₂) as well as mineral composition, indicate that Shibayama is a typical olivine-hypersthene chondrite. If the oxidized Fe is assumed only from metallic Fe, the original metallic Fe (7.75%) and Fe_metal/Fe_total(0.361) also support the above conclusion. From the well-recrystallized texture, indistinct and obliterated chondrule-matrix boundary, homogeneous composition of olivine and pyroxene, absence of igneous glass, and interstitial and well-developed plagioclase, this chondrite could be classified in petrologic type 6. Mosaic texture, kink bands, undulatory extinction of silicate grains and maskelynitization of plagioclase indicate that Shibayama suffered from a heavy shock effect, as is seen in other L-6 group chondrites.     

Impact of flood events on macrobenthic community structure on an intertidal flat developing in the Ohta River Estuary

We investigated the effects of river floods on the macrobenthic community of the intertidal flat in the Ohta River Estuary, Japan, from 2005 to 2010. Sediment erosion by flood events ranged from about 2–3 cm to 12 cm, and the salinity dropped to 0‰ even during low-intensity flood events. Cluster analysis of the macrobenthic population showed that the community structure was controlled by the physical disturbance, decreased salinity, or both. The opportunistic polychaete Capitella sp. was the most dominant species in all clusters, and populations of the long-lived polychaete Ceratonereis erythraeensis increased in years with stable flow and almost disappeared in years with intense flooding. The bivalve Musculista senhousia was also an important opportunistic species that formed mats in summer of the stable years and influenced the structure of the macrobenthic community. Our results demonstrate the substantial effects of flood events on the macrobenthic community structure.     

Damage Evaluation of Agro-meteorological Hazards in the Maize-Growing Region of Songliao Plain,China: Case Study of Lishu County of Jilin Province

Agro-meteorological hazards such as drought, waterlogging and cool summer occur with very high frequency and affect maize production and social-economic development in the maize-growing region of Songliao Plain, China. Moreover, both the frequency of these hazards and loss from them are considered to be increasing with global warming. The purpose of this paper is to quantitatively analyze the relationships between the fluctuation of maize yield and drought, waterlogging and cool summer, and to evaluate the consequences of these hazards in the maize-growing area of Songliao Plain, taking Lishu county as a case study area based on GIS (Geographic Information System). Crop yield-climate analysis and regression analysis were employed to analyze and quantify relationships between the fluctuation of maize yield and drought, waterlogging and cool summer, and to evaluate the consequences of these hazards. The parameters and model of damage evaluation were presented using weighted comprehensive analysis, and the degree of damage of drought, waterlogging and cool summer to maize production was comprehensively evaluated and regionalized. It is shown that from 1949 to 1990, the negative value years of the fluctuation of maize yield due to meteorological hazards accounted for 55% of seasons, of which 14% was caused by drought, 30% by waterlogging, 4% by cool summer and drought, 9% by cool summer and waterlogging, 13% by drought and waterlogging, 30% by drought, waterlogging and cool summer. Studies on the instability and spatial variation of the fluctuations in maize yield in Lishu county showed that the middle plains are stable areas to climatic influence, while southeastern hills and low mountains, the low lands of the plains along the East Liao River and the western plain are unstable areas in terms of areas in maize yield. The synthetic index of the degree of damage to maize of drought, waterlogging and cool summer showed a strong positive correlation with the ratio of the amount damaged to the normal yield of maize. This suggests that this index can be used to evaluate such damage. The degree of damage of drought, waterlogging and cool summer to maize in Lishu county shows the regional characteristics, which increase gradually from the center to the west and east, this being almost identical with the spatial distribution of the fluctuation of maize yield due to these hazards. This study can be expected to provide the basis for developing strategies to mitigate agro-meteorological hazards and reducing the losses from them, and adjust the medium and long-term distribution of agricultural activities so as to adapt to environmental changes.     

Diets of Steller sea lions off the coast of Hokkaido,Japan: An inter‐decadal and geographic comparison

Inter‐decadal and geographic variations in the diets of Steller sea lion, Eumetopias jubatus, were examined based on the contents of 408 stomachs collected from coastal areas around Hokkaido Island during the periods 1994–1998 and 2005–2012. The most important prey species in the 1990s were gadid fishes (walleye pollock [Gadus chalcogrammus], Pacific cod [Gadus microcephalus] and saffron cod [Eleginus gracilis]). The frequency of occurrence and gravimetric contribution of gadids decreased in the 2000s latter period at three study sites (Rausu, Shakotan and Rebun) and were replaced by Okhotsk Atka mackerel (Pleurogrammus azonus) and smooth lumpsucker (Aptocyclus ventricosus). However, analysis based on gravimetric composition indicated that the dietary diversity of prey showed only a slight inter‐decadal difference, reflecting the wide diversity of prey ingested during both study periods. These results indicate that Steller sea lions along the Hokkaido coast are opportunistic feeders that utilize a wide variety of prey, and appear to feed mainly upon prey that is easily obtained.     

Optimal operation model of a single reservoir with drought duration explicitly concerned

In this paper, a new model for a single reservoir operation optimization is proposed. The proposed model can design the optimal operation policy of a reservoir with explicit consideration of drought duration. The authors model this problem by formulating a single-stage loss function as a function of both the reservoir release and drought duration. Thereby the expected loss per period which is calculated based on the above extended single-stage loss function is minimized in infinite time horizon on the basis of Markov decision process (MDP) theory. The reliability indices are estimated as expected loss per period for specified extended loss functions. Finally, the features of the proposed model are illustrated through numerical analysis.     

Optical properties of the red tide in Isahaya Bay,southwestern Japan: Influence of chlorophyll a concentration

Remote sensing reflectance [R _rs(λ)] and absorption coefficients of red tides were measured in Isahaya Bay, southwestern Japan, to investigate differences in the optical properties of red tide and non-red tide waters. We defined colored areas of the sea surface, visualized from shipboard, as “red tides”. Peaks of the R _rs(λ) spectra of non-red tide waters were at 565 nm, while those of red tides shifted to longer wavelengths (589 nm). The spectral shape of R _rs(λ) was close to that of the reciprocal of the total absorption coefficient [1/a(λ)], implying that the R _rs(λ) peak is determined by absorption. Absorption coefficients of phytoplankton [a _ph(λ)], non-pigment particles and colored dissolved organic matter increased with increasing chlorophyll a concentration (Chl a), and those coefficients were correlated with Chl a for both red tide and non-red tide waters. Using these relationships between absorption coefficients and Chl a, variation in the spectrum of 1/a(λ) as a function of Chl a was calculated. The peak of 1/a(λ) shifted to longer wavelengths with increasing Chl a. Furthermore, the relative contribution of a _ph(λ) to the total absorption in red tide water was significantly higher than in non-red tide water in the wavelength range 550–600 nm, including the peak. Our results show that the variation of a _ph(λ) with Chl a dominates the behavior of the R _rs(λ) peak, and utilization of R _rs(λ) peaks at 589 and 565 nm may be useful to discriminate between red tide and non-red tide waters by remote sensing.