Geochemical characteristics of zircons in the Ashizuri A‐type granitoids: An additional granite topology tool for detrital zircon studies

Zircon is resistant to alteration over a wide range of geological environments, and isotopic ratios within the mineral provide constraints on ages and their parental magmas. Trace element compositions in zircon are also expected to reflect those of their parent magmas, and have a potential as essential indicators for their host rocks. Because most detrital zircons that accumulate at river mouths are derived primarily from granitoids, the classification of zircon within granitoids is potentially meaningful. This study employs the conventional classification scheme of granites (I‐, S‐, M‐, and A‐types). To clarify geochemical characteristics of zircons in A‐type granites, trace element compositions of zircons extracted from the A‐type Ashizuri granitoids were examined. Zircons from the Ashizuri granitoids commonly show enrichments of heavy rare earth elements and positive Ce anomalies, indicating that these zircons were igneous in origin. In addition, zircons in these A‐type granites are characterized by enrichments of Nb, Y, Ta, Th, and U and strong negative Eu anomalies, which exhibit good positive correlations with those in their whole rocks. This fact indicates that these signatures in zircons reflect well those in their parental bodies and are useful in identifying zircons derived from A‐type granite. Based on compilations of available data, zircons from A‐type granites can be clearly discriminated from other‐types of granites within Nb/Sr–Eu anomaly, U/Sr–Eu anomaly, Nb/Sr–U/Sr, and Nb/Sr–Ta/Sr cross‐plots. All indices used in these diagrams were selected based on the geochemical features of both zircon and whole rock of A‐type granites. Application of these discrimination diagrams to detrital zircons will likely provide further insights. For example, some Hadean detrital zircons plot in similar fields to A‐type granites, implying the existence of A‐type magmatism in the Earth's earliest history.     

Preface to the special issue on electromagnetic phenomena related to seismic and volcanic activities from EMSEV in 2016

<正>EMSEV,Electromagnetic Studies of Earthquake and Volcanoes,set up in 2002,is a joint academic organization by multi-associations in IUGG(International Union of Geodesy and Geophysics),including IAGA(International Association of Geomagnetism and Aeronomy),IASPEI(International Association of Seismology and Physics of the Earth’s Interior),IAVCEI(International Association of Volcanology and Chemistry of the Earth’s Interior).On     

Evaluation of tidal error in altimetry data in the Asian marginal seas

The magnitude and geographical distribution of the error in the Archiving, Validation and Interpretation of Satellite Oceanographic data (AVISO) altimetry data associated with tidal correction around Asian marginal seas has been revealed. The errors were evaluated by harmonic analysis of the AVISO corrected sea surface heights data (CorSSH). Errors of more than 15 cm of tidal correction were recognized in the western and northern parts of the Yellow Sea, Celebes Sea, Kuril Islands, and the northwestern part of the Okhotsk Sea. It was found that the CorSSH and sea level anomaly (SLA) data downloaded from the AVISO are not available for direct use in those marginal seas. To reduce the tidal correction error, the harmonic constants calculated from the latest tide model and regional tide model were applied as the tidal correction of the Altimetry data. The tidal errors in the Yellow Sea and the northwestern part of the Okhotsk Sea were reduced by approximately 20 cm and 10 cm, respectively. Root mean square differences between the harmonic constants derived from tide models and those derived from altimetry data were calculated. The root mean square differences were large in the Yellow and the Okhotsk Seas. Root sum squares for four principal tidal constituents in the Yellow and East China Seas and Okhotsk Sea were 7.72 cm and 8.36 cm, respectively.     

Igneous History of the Aubrite Parent Asteroid: Evidence from the Norton County Enstatite Achondrite

Abstract— We studied numerous specimens of the Norton County enstatite achondrite (aubrite) by optical microscopy, electron microprobe, and neutron-activation analysis. Our main conclusions are the following: 1. Norton County is a fragmental impact breccia, consisting of a clastic matrix made mostly of crushed enstatite, into which are embedded a variety of mineral and lithic clasts of both igneous and impact melt origin. 2. The Norton County precursor materials were igneous rocks, mostly plutonic orthopyroxenites, not grains formed by condensation from the solar nebula. 3. The Mg-silicate-rich aubrite parent body experienced extensive melting and igneous differentiation, causing formation of diverse lithologies, some of which have not been described previously. These lithologies include dunites (represented by forsterite crystals), plutonic orthopyroxenites (represented by most enstatite crystals in the matrix), plutonic pyroxenites (the pyroxenitic clasts), and plagioclase-silica rocks (like the feldspathic clasts). Presence of impact melt breccias (the microporphyritic clasts and the diopside-plagioclase-silica clast) of still different compositions further attest to the lithologic diversity of the aubrite parent body.     

Mid- and far-infrared extinction coefficients of hydrous silicate minerals

Extinction coefficients were measured for three kind of hydrous silicate minerals, montmorillonite, chlorite and serpentine, from 7 to 140 m. The infrared extinction coefficients of these minerals show (1) a few broad bands in the mid-infrared region and (2) a less steep wavelength-dependence in the far-infrared region, in contrast to those of high-temperature magnesium silicates. In the far-infrared region, montmorillonite shows a ^–0.8±0.1 dependence (, the wavelength) without any band structure, chlorite has a double maxima structure around 80 m, and serpentine shows a rather steep dependence with a small peak at 77 m.The changes of mid-infrared spectra by heating were measured. Change in chlorite spectrum is the most significant. Many fine features appear by heating and then they disappear. Above 900°C one broad feature remains around 10 m. Fine features of the montmorillonite spectrum disappear by heating. For serpentine, many new peaks appear and the spectrum resembles the spectrum of olivin. In near-infrared a band around 2.72 m disappears by heating.Extinction coefficients at very low temperatures were measured in the far-infrared region. For montmorillonite and serpentine, the spectrum is the same as that at room temperature. The double peaks of chlorite around 80 m become higher.     

Evaluation of ADEOS-II GLI ocean color atmospheric correction using SIMBADA handheld radiometer data

The performance of the “version 2” Global Imager (GLI) standard atmospheric correction algorithm, which includes empirical absorptive aerosol correction and sun glint correction, was evaluated using data collected with handheld above-water SIMBADA radiometers during 23 cruises of opportunity (research vessels, merchant ships), mostly in the North Atlantic and European seas. A number of 100 match-up data sets of GLI-derived and SIMBADA-measured normalized water-leaving radiance (nL _W ) and aerosol optical thickness (AOT) were sorted out, using objective selection criteria, and analyzed. The Root-Mean-Square (RMS) difference between GLI and SIMBADA nL _W was about 0.32 μW/cm²/nm/sr for the 412 nm band, showing improvement by 30% in RMS difference with respect to the conventional “version 1” GLI atmospheric correction algorithm, and the mean difference (or bias) was reduced significantly. For AOT, the RMS difference was 0.1 between GLI estimates and SIMBADA measurements and the bias was small (a few 0.01), but the ?ngstr?m exponent was systematically underestimated, by 0.4 on average, suggesting a potential GLI calibration offset in the near infrared. The nL _W differences were not correlated to AOT, although performance was best in very clear conditions (AOT less than 0.05 in the 865 nm band). Despite the relatively large scatter between estimated and measured nL _W , the derived chlorophyll-a concentration estimates, applying the same ratio algorithm (GLI OC4V4) to GLI and SIMBADA, were consistent and highly correlated in the range of 0.05–2 μg/l. The large variability in chlorophyll-a concentration estimate for clear clean water areas (e.g. with the concentration range lower than about 0.05 μg/l) turns out to be due to the nature of the “band ratio” based in-water algorithm.     

Temporal changes in electrical resistivity at Sakurajima volcano from continuous magnetotelluric observations

Continuous magnetotelluric (MT) measurements were conducted from May 2008 to July 2009 at Sakurajima, one of the most active volcanoes in Japan. Two observation sites were established at locations 3.3 km east and 3 km west–northwest of the summit crater. At both observation sites, the high-quality component of the impedance tensor (Zyx) showed variations in apparent resistivity of approximately ± 20% and phase change of ± 2°, which continued for 20–180 days in the frequency range between 320 and 4 Hz. The start of the period of changes in apparent resistivity approximately coincided with the start of uplift in the direction of the summit crater, as observed by a tiltmeter, which is one of the most reliable pieces of equipment with which to detect magma intrusion beneath a volcano. A 2D inversion of MT impedance suggests that the resistivity change occurred at a depth around sea level. One of the possible implications of the present finding is that the degassed volatiles migrated not only vertically through the conduit but also laterally through a fracture network, mixing with shallow groundwater beneath sea level and thereby causing the observed resistivity change.     

Discriminating residual and colluvial soils using topographic analysis in a small,forested catchment in Japan

Soil moisture plays an important role in hydrology. Understanding factors (such as topography, vegetation, and meteorological conditions) that influence spatio‐temporal variability in soil moisture, and how this influence is manifested, is important for understanding hydrological processes. A number of distributed (quasi‐)physical hydrological models have been developed to investigate this subject. Previous studies have shown that the spatial differences in the distribution of soil types (residual and colluvial soils) dominantly reflect spatio‐temporal fluctuations in soil moisture and runoff. We present a methodology for assessing the spatial distribution of residual and colluvial soils, which differ with respect to their physical characteristics, in a 0·88 km² forested catchment with complex topography and a complex land‐use history. Our method is based on penetration resistance profile data; in this data set, each data point represents soil physical characteristics within an area of about 25 m². If the spatial distribution of soils under similar meteorological, geological, historical land use, and other conditions could be characterized on the basis of similarity in topographic features, then the spatial distribution of soil could be predicted based on relationships between various topographic indices (e.g. topographic index and local slope). We tested whether our model correctly assessed the reference data. The model's results were 90·5% correct for residual soils and 87·3% correct for colluvial soils. Further studies will quantify the relationships between topographic features of land covered by residual and colluvial soils and changes in spatio‐temporal variations in the catchment (e.g. vegetation and land use) as a function of geology or meteorology. Copyright © 2007 John Wiley & Sons, Ltd.