Solubility of Fe2(OH)3Cl (pure-iron end-member of hibbingite) in NaCl and Na2SO4 brines

Pure-iron end-member hibbingite, Fe₂(OH)₃Cl(s), may be important to geological repositories in salt formations, as it may be a dominant corrosion product of steel waste canisters in an anoxic environment in Na–Cl- and Na–Mg–Cl-dominated brines. In this study, the solubility of Fe₂(OH)₃Cl(s), the pure-iron end-member of hibbingite (Fe^II, Mg)₂(OH)₃Cl(s), and Fe(OH)₂(s) in 0.04 m to 6 m NaCl brines has been determined. For the reactionFe₂(OH)₃Cl(s) + 3H⁺ ? 3 H₂O + 2 Fe²⁺ + Cl^?,the solubility constant of Fe₂(OH)₃Cl(s) at infinite dilution and 25 °C has been found to be log₁₀ K = 17.12 ± 0.15 (95% confidence interval using F statistics for 36 data points and 3 parameters). For the reactionFe(OH)₂(s) + 2H⁺ ? 2 H₂O + Fe²⁺,the solubility constant of Fe(OH)₂ at infinite dilution and 25 °C has been found to be log₁₀ K = 12.95 ± 0.13 (95 % confidence interval using F statistics for 36 data points and 3 parameters). For the combined set of solubility data for Fe₂(OH)₃Cl(s) and Fe(OH)₂(s), the Na⁺–Fe²⁺ pair Pitzer interaction parameter θ_{Na⁺/Fe²⁺} has been found to be 0.08 ± 0.03 (95% confidence interval using F statistics for 36 data points and 3 parameters). In nearly saturated NaCl brine we observed evidence for the conversion of Fe(OH)₂(s) to Fe₂(OH)₃Cl(s). Additionally, when Fe₂(OH)₃Cl(s) was added to sodium sulfate brines, the formation of green rust(II) sulfate was observed, along with the generation of hydrogen gas. The results presented here provide insight into understanding and modeling the geochemistry and performance assessment of nuclear waste repositories in salt formations.     

Far-zone gravity field contributions corrected for the effect of topography by means of molodensky’s truncation coefficients

A spectral representation of the topographic corrections to gravity field quantities is formulated in terms of spherical height functions. When computing the far-zone contributions to the topographic corrections, various types of the truncation coefficients are applied to a spectral representation of Newton’s integral. In this study we utilise Molodensky’s truncation coefficients in deriving the expressions for the far-zone contributions to topographic corrections. The expressions for computing the far-zone gravity field contributions corrected for the effect of topography are then obtained by combining the expressions for the far-zone contributions to the gravity field quantities and to the respective topographic corrections, both expressed in terms of Molodensky’s truncation coefficients. The numerical examples of the far-zone contributions to the topographic corrections and to the topography-corrected gravity field quantities are given over the study area situated in the Canadian Rocky Mountains with adjacent planes. Coefficients of the global elevation and geopotential models are used as the input data.     

Mineralogy and geochemistry of shallow sediments of Sonargaon, Bangladesh and implications for arsenic dynamics: Focusing on the role of organic matter

Mineralogy and geochemistry of modern shallow sediments (up to 5 m thick) within the zone of water table fluctuations were studied to determine the likely sources and processes responsible for releasing As into groundwater. Samples were collected from different geological settings with varying groundwater As concentrations during dry (December 2005) and wet (September 2006) seasons at Sonargaon, Bangladesh. Stratigraphic sequences of the studied sediments showed three distinct lithofacies, viz. clayey-silt, silty-clay, and silty-very fine sand, corresponding to fine-grained overbank associations. Total As concentrations of shallow sediments ranged from <1 to 16 mg/kg without a significant difference in the range of As concentrations between the seasons. Sequential chemical extraction analysis of As revealed that >80% of the As was fixed in insoluble and organic phases, while the amount of As in reducible and acid-soluble phases was very low (<20%) and varied inversely with total As content. Total As concentration varied with mica content (muscovite and biotite) and its related elements (Al, Mg and Fe), but not with total organic C, suggesting that biotite is the major host phase of As. Arsenic appears to be liberated from biotite and/or other As-bearing minerals via chemical weathering (i.e., hydration-decomposition), either from the near-surface sediments which are subject to seasonal cycling of the redox conditions, or from within the aquifer sediments. Once released, progressive diagenesis to form As-bearing organic matter may be responsible for controlling As distribution in the sediments and coexisting groundwater of the study area.     

Dynamics of arsenic adsorption in the targeted arsenic-safe aquifers in Matlab, south-eastern Bangladesh: Insight from experimental studies

Targeting shallow low-As aquifers based on sediment colour may be a viable solution for supplying As-safe drinking water to rural communities in some regions of Bangladesh and West Bengal in India. The sustainability of this solution with regard to the long-term risk of As-safe oxidized aquifers becoming enriched with As needs to be assessed. This study focuses on the adsorption behaviour of shallow oxidized sediments from Matlab Region, Bangladesh, and their capacity to attenuate As if cross-contamination of the oxidized aquifers occurs. Water quality analyses of samples collected from 20 tube-wells in the region indicate that while there may be some seasonal variability, the groundwater chemistry in the reduced and oxidized aquifers was relatively stable from 2004 to 2009. Although sediment extractions indicate a relatively low amount of As in the oxidized sediments, below 2.5 mg kg⁻¹, batch isotherm experiments show that the sediments have a high capacity to adsorb As. Simulations using a surface complexation model that considers adsorption to amorphous Fe(III) oxide minerals only, under-predict the experimental isotherms. This suggests that a large proportion of the adsorption sites in the oxidized sediments may be associated with crystalline Fe(III) oxides, Mn(IV) and Al(III) oxides, and clay minerals. Replicate breakthrough column experiments conducted with lactose added to the influent solution demonstrate that the high adsorption capacity of the oxidized sediments may be reduced if water drawn down into the oxidized aquifers contains high levels of electron donors such as reactive dissolved organic C.     

Comparative study between filtering and inversion of VLF-EM profile data

This paper discusses the practical use of filtering and inversion in VLF-EM data processing and interpretation. The advantages and disadvantages of both mentioned techniques were outlined to avoid the misleading interpretation of such data in some case studies. Much concern is taken to show the interval distance effect upon the correct depth identification of the anomalous body by either inversion or filtering. The methodology of the study is going through proposing an initial model, generating the synthetic VLF-EM data of the model by means of forward modeling, filtering (Karous–Hjelt filter) and inversion (Inv2DVLF software) of the synthetic data and comparing between the results of both methods and the initial model. The study reached to (1) Karous–Hjelt filter provides misleading depths for his limited depth of resolution and cannot provide estimates of deep targets if the profile is too small, whereas inversion provides exact results, particularly in case of shallow anomalous target; (2) crossover between in-phase and out-of-phase data could resulted from a small shallow conductive target or a large deep one; (3) selection of a reasonable environmental resistivity has an important impact on the inversion process; and (4) the numerical reflection resulted during VLF-EM data inversion could lead to an erroneous interpretation.     

Characterization of bioflocculants produced by bacteria isolated from crude petroleum oil

The aim of this study was to look for high efficient bioflocculant-producing microorganisms. Among 36 bacterial colonies isolated from a crude petroleum oil sample, three of them as Bacillus subtilis and Pseudomonas spp. exhibited flocculation activity exceeding 90 % after 3 days of cultivation. They were identified by 16 S rDNA sequence analysis as Bacillus subtilis and Pseudomonas sp. Spectroscopic analysis of the polymers by nuclear magnetic resonance and fourier-transform infrared revealed that the polymers were glycoproteins. These polymers were soluble in water and insoluble in any organic solvents tested. The effects of bioflocculant dosage, temperature and pH on the flocculation activity were evaluated. The maximum bioflocculation activities were observed at an optimum bioflocculant dosage of 3.5 mg/L (strains Bacillus subtilis and Pseudomonas) and 5.0 mg/L (strain CPO14), respectively. In addition, these biopolymers were able to flocculate kaolin suspension (5 g/L) over a wide range of pH (pH 3–9) and temperature (5–50 °C) tested in the presence of CaCl₂. The highest flocculation activities of strains CPO8, CPO13 and CPO14 were 96.03 %, 92.17 % and 97.59 %, respectively in the early stationary phase (at 24 h), while the cell production reached its maximum in the stationary phase (at 72 h). Their efficient flocculation capabilities suggest potential applications in industries.     

Flash flood risk estimation along the St. Katherine road,southern Sinai,Egypt using GIS based morphometry and satellite imagery

Flash floods are considered to be one of the worst weather-related natural disasters. They are dangerous because they are sudden and are highly unpredictable following brief spells of heavy rain. Several qualitative methods exist in the literature for the estimations of the risk level of flash flood hazard within a watershed. This paper presents the utilization of remote sensing data such as enhanced Thematic Mapper Plus (ETM+), Shuttle Radar Topography Mission (SRTM), coupled with geological, geomorphological, and field data in a GIS environment for the estimation of the flash flood risk along the Feiran–Katherine road, southern Sinai, Egypt. This road is a vital corridor for the tourists visiting here for religious purposes (St. Katherine monastery) and is subjected to frequent flash floods, causing heavy damage to man-made features. In this paper, morphometric analyses have been used to estimate the flash flood risk levels of sub-watersheds within the Wadi Feiran basin. First, drainage characteristics are captured by a set of parameters relevant to the flash flood risk. Further, comparison between the effectiveness of the sub-basins has been performed in order to understand the active ones. A detailed geomorphological map for the most hazardous sub-basins is presented. In addition, a map identifying sensitive sections is constructed for the Feiran–Katherine road. Finally, the most influenced factors for both flash flood hazard and critical sensitive zones have been discussed. The results of this study can initiate appropriate measures to mitigate the probable hazards in the area.     

Geotechnical modeling of fractures and cavities that are associated with geotechnical engineering problems in Kuala Lumpur limestone,Malaysia

This study presents a modified geotechnical model of subsurface cavities and fractures that are associated with foundation and pilling problems. The topographical model was used to automatically extract minimum surface curvature, slope, and pits. The image processing shows that more than fourteen regional faults, trending NE, SW, and WNW affect the Kuala Lumpur limestone bedrock and the surface topography from South to North. These fractures often show higher probability of piling and constructions problems. The faults are tensional, low lying, and wrench of length 10–20 km. Opencast ex-mining pond floors (bathymetry) are good indicators of subsurface fractures and cavities that affect the limestone bedrock. The LANDSAT image (band one) shows that the fractures of opencast ex-mining pond floors have the same trend as the regional faults. These techniques can help geotechnical engineers to predict subsurface fractures and cavities, especially in areas adjacent to ex-mining ponds. In brief, most of the subsurface cavities and ex-mining ponds, for example the Phong Fatt pond, are located on and along fault zones.     

Airborne γ-ray spectrometric characteristics of lithological units and environmental issues in the Bahariya Oases area in the northern part of western desert, Egypt

Two significant airborne gamma ray spectrometic (AGRS) statistical parameters, i.e., the arithmetic mean and the standard deviation, were computed for all lithologic units and formations of the Bahariya Oases area, Northern Western Desert, Egypt. The results ascertain that the maximum AGRS values are associated with sabkha sediments, Bahariya Formation, basalt flows and sand dunes. The intermediate values are correlated with El-Heiz, El-Hefhuf, Qazzun and Naqb formations. The minimum values are connected with Khoman Chalk and El-Hamra formations. The AGRS records were found to vary from one type of rock to another and to some extent between units of the same rock type too. On the aerial total-count (TC) radiometric maps, the records change from 6.2 to 69.36 μR/h. On the potassium map, the values range from 0.05% to 4.35%. On the equivalent uranium (eU) and equivalent thorium (eTh) maps, the records oscillate from 0.12 to 7.4 ppm and from 0.28 to 8.4 ppm, respectively. Concerning the Bahariya Oases area, the calculated arithmetic mean natural dose rate values originating from the terrestrial gamma radiation were found to range from 0.14 to 0.26 mSv/year and where the maximum value attains 0.62 mSv/year. These values remain on the safe side and within the maximum permissible safe radiation dose without harm to individuals, with continuous external irradiation of the whole body.     

Hydrochemical evolution and variation of groundwater and its environmental impact at Sohag, Egypt

Groundwater resources of Sohag, Egypt are currently threatened by contamination from agricultural and urbanization activities. Groundwater in Sohag area has a special significance where it is the second source for fresh water used for agricultural, domestic, and industrial purposes. Due to growing population, agriculture expansion, and urbanization, groundwater quality assessment needs more attention to cope with the increasing water demand in this arid zones and limited water resources. The aim of this paper is to address the integrated role of geochemical processes, agriculture and urbanization in evolution of groundwater composition, and their impact on groundwater quality to help in management and protection of groundwater resources of study area using geochemical modeling techniques and geographical information systems. Spatial variation of groundwater hydrochemical properties, rock–water interaction, ion exchange, and assessment of groundwater quality were investigated. Results indicated that groundwater properties are varied spatially and its evolution in the study area is generally controlled by the prevailed geochemical processes represented by leaching, dissolution, and precipitation of salts and minerals, ion exchange, in addition to human activities represented by agriculture and urbanization as well as climatic and poor drainage conditions. Management alternatives should be followed in the study area to avoid degradation of groundwater quality and provide sustainable development.