Comparison between inductively coupled plasma and X-ray fluorescence performance for Pb analysis in environmental soil samples

Comparison of two conventional analytical techniques such as X-ray fluorescence (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) for measuring Pb concentrations in soil samples was achieved using field and laboratory work. Seventy-three samples were collected from urban areas surrounding the large lead smelter at South Australia, as an indicator of the environment impact of smelter activity. Soil Pb concentrations were determined using hand-held XRF analyser under laboratory conditions. ICP-MS analysis on digested soils (using a microwave-assisted nitric acid digestion-extraction) was applied to validate p-XRF data. The analysis showed that Pb concentrations determined by XRF correlated with high linearity with Pb concentrations determined by ICP-MS measurements (R ² = 0.89). Statistical test (t test) was applied to the data of both methods applied without any significant difference between the two techniques. These results indicated that ICP-MS corroborated XRF for Pb soil measurements and suggests that XRF was a reliable and quick alternative to traditional analytical methods in studies of environmental health risk assessment, allowing for much larger sampling regimes in relatively shorter times and could be applied in the field.     

A Review on Chemical Stabilization of Peat

Geotechnical and Geological Engineering - Peat is a problematic or weak soil derived from fossilized organic material. The characteristics of peat like low shear strength (3–16 kPa),...     

Spatial dimension of impact,relief, and rescue of the 2014 flood in Kashmir Valley

Flood relief and rescue form an important basis of disaster management, and the assessment of flood damage is a critical component of flood risk management. In its recent history, Kashmir Valley witnessed the floods in 2014, 2015, 2017, 2019, 2020, and 2021, but the worst flood in the living memory of the people was witnessed in the year 2014, which created widespread loss in economic and societal aspects. The present study discusses the spatial dimension of impact, relief, and rescue of the flood of 2014 in the Kashmir Valley. It analyses the distribution of relief and politics of relief and rescue and highlights the role of the communitarianism and the heroics of the community members in dealing with floods. The study provides the data of relief distribution under different government schemes and reveals that the relief was not distributed equally in various districts of the valley. The study relies on primary and secondary sources of data. Ethnographic approach was used for acquiring primary data because it provides the complex narratives of disasters and the political and social rupture experienced during the disasters. The data have been analysed with the help of Geographic Information System.

     

Rn solution by the circulating fluids in a “hot dry rock” geothermal reservoir

The mechanism of²²²Rn release into fracture fluids by direct alpha-recoil, lattice and grain boundary/micro-crack diffusion is discussed. Experimental measurements of²²²Rn release into surrounding air and water phases have been made for crystalline rock specimens with well defined surface areas. The²²²Rn flux from an infinite plane surface and hence the effective diffusion length of²²²Rn in the rock matrix has been estimated.The²²²Rn flux from plane crystalline rock surfaces has been used in conjunction with a simple hydrological model of the reservoir to calculate the²²²Rn content of the return fluids of a geothermal doublet circulation system. For given production rate and piezometric difference between the injection and production wells, the²²²Rn content of the return fluid is dependent upon the distribution of flow path lengths and fracture apertures in the reservoir. Matching of the calculated and experimental²²²Rn contents of the return fluids has been used to select appropriate parameters for the reservoir model and hence to estimate the extent of the heat-transfer surface. The model estimates the fracture width of the flow paths, total swept surface area and fracture volume within the reservoir.     

Secular Variation of Geomagnetic Field at Karachi Observatory

Geomagnetism and Aeronomy - In this work, the secular variation of noon/midnight geomagnetic observed field has been investigated at Karachi observatory using the data of total geomagnetic field...     

Use of breakdown coefficients in turbulent jets to determine the universal exponent μ

Second-order moments of the breakdown coefficients q _r,l of the squared velocity derivative in plane and circular jets indicate a value of the exponent which is larger than that obtained by other methods using the same data or that previously reported by other workers using the same method on atmospheric data. The difference may be due to a failure of the present data to satisfy the first condition of scale similarity, possibly because of the relatively small Reynolds numbers of the laboratory flows. The dependence of the variance of ln q _r,l on the length scale l appears to be independent of Reynolds number.     

Simulation of vortex-induced vibrations of a cylinder using ANSYS CFX

In this paper, vortex-induced vibrations of a cylinder are simulated by use of ANSYS CFX simulation code. The cylinder is treated as a rigid body and transverse displacements are obtained by use of a one degree of freedom spring damper system. 2-D as well as 3-D analysis is performed using air as the fluid. Reynolds number is varied from 40 to 16000 approx., covering the laminar and turbulent regimes of flow. The experimental results of （Khalak and Williamson, 1997） and other researchers are used for validation purposes. The results obtained are comparable.