Mineral species control of aluminum solubility in sulfate-rich acidic waters

The identification of the mineral species controlling the solubility of Al in acidic waters rich in sulfate has presented researchers with several challenges. One of the particular challenges is that the mineral species may be amorphous by X-ray diffraction. The difficulty in discerning between adsorbed or structural sulfate is a further complication. Numerous studies have employed theoretical calculations to determine the Al mineral species forming in acid sulfate soil environments. The vast majority of these studies indicate the formation of a mineral species matching the stoichiometry of jurbanite, Al(OH)SO₄·5H₂O. Much debate, however, exists as to the reality of jurbanite forming in natural environments, particularly in view of its apparent rare occurrence. In this work the use of Al, S and O K-edge XANES spectroscopy, in combination with elemental composition analyses of groundwater precipitates and a theoretical analysis of soluble Al concentrations ranging from pH 3.5 to 7, were employed to determine the mineral species controlling the solubility of Al draining from acid sulfate soils into Blacks Drain in north-eastern New South Wales, Australia. The results indicate that a mixture of amorphous Al hydroxide (Al(OH)₃) and basaluminite (Al₄(SO₄)(OH)₁₀·5H₂O) was forming. The use of XANES spectroscopy is particularly useful as it provides insight into the nature of the bond between sulfate and Al, and confirms the presence of basaluminite. This counters the possibility that an Al hydroxide species, with appreciable amounts of adsorbed sulfate, is forming within these groundwaters.Below approximately pH 4.5, prior to precipitation of this amorphous Al(OH)₃/basaluminite mixture, our studies indicate that the Al³⁺ activity of these acidic sulfate-rich waters is limited by the availability of dissolved Al from exchangeable and amorphous/poorly crystalline mineral species within adjacent soils. Further evidence suggests the Al³⁺ activity below pH 4.5 is then further controlled by dilution with either rainwater or pH 6-8 buffered estuarine water, and not a notional Al(OH)SO₄ mineral species.     

Dissociation kinetics of Fe(III)- and Al(III)-natural organic matter complexes at pH 6.0 and 8.0 and 25 °C

The rate at which iron- and aluminium-natural organic matter (NOM) complexes dissociate plays a critical role in the transport of these elements given the readiness with which they hydrolyse and precipitate. Despite this, there have only been a few reliable studies on the dissociation kinetics of these complexes suggesting half-times of some hours for the dissociation of Fe(III) and Al(III) from a strongly binding component of NOM. First-order dissociation rate constants are re-evaluated here at pH 6.0 and 8.0 and 25 °C using both cation exchange resin and competing ligand methods for Fe(III) and a cation exchange resin method only for Al(III) complexes. Both methods provide similar results at a particular pH with a two-ligand model accounting satisfactorily for the dissociation kinetics results obtained. For Fe(III), half-times on the order of 6-7 h were obtained for dissociation of the strong component and 4-5 min for dissociation of the weak component. For aluminium, the half-times were on the order of 1.5 h and 1-2 min for the strong and weak components, respectively. Overall, Fe(III) complexes with NOM are more stable than analogous complexes with Al(III), implying Fe(III) may be transported further from its source upon dilution and dispersion.     

The distribution of particulate matter in the Atlantic Ocean

We have determined the dry weight of suspended particulate matter in seawater in a section through the western Atlantic Ocean from 75°N to 52°S. The concentrations, operationally defined as that weight retained on 0.6-μm and 0.4-μm pore size Nuclepore filters, contained in 1 kg of seawater, range from 5 to 300 μg/kg and show readily explainable regional features. High concentrations are found in surface waters and in association with radpidly moving bottom waters in the Denmark Straits overflow and in Antarctic bottom waters to 15°S. Low concentrations, <12 μg/kg, characterize the mid-water regions of the sub-tropical gyres. High concentrations are seen in sinking Labrador Sea water and in a plume extending at least a kilometer off the bottom at 35°N–40°N where the cruise track intersects the North Atlantic gyre. It is doubtful whether this important phenomenon could be observed by any means other than through particulate observations, either optical or gravimetric, and this provides a unique insight into the scale of vertical turbulent processes.     

Electromagnetic sounding of geothermal zones

Electromagnetic (EM) data provide a substantial contribution to the geophysical mapping and monitoring of geothermal reservoirs. This paper presents an up-to-date picture of the achievements of EM methods for geothermal exploration as they have emerged over the last few years. It has been proved that EM sounding of geothermal zones and distant monitoring macro-parameters of the reservoirs, fluid-filled faults and other elements of the geothermal system are possible provided that modern 3-D inversion is used along with techniques that reduce the effects of industrial and geological noise. In addition, geological and petrophysical data also need to be included in the analysis.     

Quality and origin of mountain food products: the new European label as a strategy for sustainable development

Mountain farming provides high-quality food products due to the peculiar characteristics of the raw materials combined with traditional processing conditions. However, these products and their intrinsic characteristics are not clearly recognized by consumers on the market. Nowadays, Protected Designation of Origin(PDO), Protected Geographical Indication(PGI) and Traditional Specialities Guaranteed(TSG) certifications include products originating in mountain areas, even if a large part of mountain foodstuff is not protected by these certifications and foods not made in mountain areas are often labeled as ―mountain food products‖. For this reason, the European Union has set a specific Regulation in 2012 to recognize and protect mountain food and to make the consumers safer about the origin information. The objective of this paper is twofold: firstly, it presents the recent aspects related to European legislation of mountain food product; secondly, it aims at reviewing the main features of nutritional quality and technology of dairy and meat products, as the most widespread mountain food products, and the main protocols used to evaluate the authenticity of these food products. The promotion of mountain food product through a specific label and the use of tracing methods, which are able to verify the authenticity of the origin of these products, may play a pivotal role in increasing the consumer‘s loyalty towards these products and could be a way to boost a sustainable development of these economically marginal rural areas. However, the analytical protocols developed so far(stable isotopes, macro and microelements, radionuclides, spectroscopic, molecular techniques, volatile substances profile, terpenes) are in many cases still at the experimental level due to the extreme variability of the mountain origin of the products to be tested.     

Schwertmannite stability in acidified coastal environments

A combination of analytical and field measurements has been used to probe the speciation and cycling of iron in coastal lowland acid sulfate soils. Iron K-edge EXAFS spectroscopy demonstrated that schwertmannite dominated (43-77%) secondary iron mineralization throughout the oxidized and acidified soil profile, while pyrite and illite were the major iron-bearing minerals in the reduced potential acid sulfate soil layers. Analyses of contemporary precipitates from shallow acid sulfate soil groundwaters indicated that 2-line ferrihydrite, in addition to schwertmannite, is presently controlling secondary Fe(III) mineralization. Although aqueous pH values and concentrations of Fe(II) were seasonally high, no evidence was obtained for the Fe(II)-catalyzed crystallization of either mineral to goethite. The results of this study indicate that: (a) schwertmannite is likely to persist in coastal lowland acid sulfate soils on a much longer time-scale than predicted by laboratory experiments; (b) this mineral is less reactive in these types of soils due to surface-site coverage by components such as silicate and possibly, to a lesser extent, natural organic matter and phosphate and; (c) active water table management to promote oxic/anoxic cycles around the Fe(II)-Fe(III) redox couple, or reflooding of these soils, will be ineffective in promoting the Fe(II)-catalyzed transformation of either schwertmannite or 2-line ferrihydrite to crystalline iron oxyhydroxides.     

Volcanic structure of the southern sector of Mt. Etna after the 2001 and 2002 eruptions defined by magnetotelluric measurements

Two magnetotelluric (MT) surveys were carried out on the Mt. Etna volcano after two of the most intense eruptions of the last 30 years which took place in summer 2001 and winter 2002–2003. Surveying was pursued for two main reasons. First, we sought to contribute to the definition of the first-order structure and physico-chemical state (temperature, fluids, melts) of a volcano that has been extensively explored and monitored by means of various geophysical methods, but where only few electrical and electromagnetic surveys have been performed. Secondly, we acquired MT data in the same sites in the two different surveys with the aim of monitoring the possible changes of the first-order structure, since conditions are expected to vary on an active volcano such as Etna, and are supposed to be linked to the eruptive events. Soundings have been acquired in an E-W 10 km-long profile across the southern flank of Mt. Etna, at a distance of almost 6 km south from the Central Crater. The first survey was carried out three months after the 2001 eruption. Inverse models define a pronounced (4 km thickness) low resistivity section at a depth of about 1 km b.s.l. to the west. To the east, a low resistivity section is still present, but appears deeper, thinner and more resistive, and a shallow low resistivity anomaly also exists. The shallow anomaly to the east is tentatively correlated with altered and clayey volcanic units and/or temporary groundwater storage. The deep anomalies are interpreted as being due to melt storage at shallow depths which was not exhausted during the eruption. This would be confirmed by the abundance of lava erupted within one year from the end of the survey. The few good sites retrieved in the second survey, carried out a few weeks after the eruption of 2002–2003, confirm the picture defined in the first survey, and provide a better definition of the bottom of the deep anomaly located in the sedimentary basement.     

Wave-adjusted boundary condition for longshore current in finite-volume circulation models

Numerical modeling of coastal circulation encompassing the nearshore requires forcing by tide, surface gravity waves, and possibly other factors. In the nearshore, the wave-induced longshore current and setup are dominant hydrodynamic processes, and lateral boundary conditions representing tide and oceanic forcing typically do not include surface-wave contributions. Without proper boundary conditions, significant gradients in current and water level can occur that contaminate the solution in the internal domain. A standard strategy is to place the boundaries far from the site of interest, but this strategy greatly increases computational demands, and it may not be appropriate for long-term simulations. This paper describes a wave-adjusted boundary condition that accounts for wave-induced water level and current acting in combination with tidal forcing. The wave-adjusted boundary condition is demonstrated for an idealized case of a parallel-contour beach and for an engineering application at Ocean City, MD.     

Building a European geothermal information network using a distributed e-Infrastructure

Geothermal data are published using different IT services, formats and content representations, and can refer to both regional and global scale information. Geothermal stakeholders search for information with different aims. E-Infrastructures are collaborative platforms that address this diversity of aims and data representations. In this paper, we present a prototype for a European Geothermal Information Platform that uses INSPIRE recommendations and an e-Infrastructure (D4Science) to collect, aggregate and share data sets from different European data contributors, thus enabling stakeholders to retrieve and process a large amount of data. Our system merges segmented and national realities into one common framework. We demonstrate our approach by describing a platform that collects data from Italian, French, Hungarian, Swiss and Icelandic geothermal data providers.