Diagnosis of trace metal contamination in sediments: the example of Ensenada and El Sauzal, two harbors in Baja California, Mexico

Total metal concentrations in sediments from within Ensenada and El Sauzal Harbors are generally higher than at the mouths. Grain-size analyses suggested that this enrichment could be due to the presence of fine-grained sediments in the inner part of the harbors rather than to anthropogenic perturbations. The (Me/Al)(sample) ratios for Pb, Co, Ni and Fe were significantly higher for Ensenada Harbor relative to El Sauzal Harbor, whereas the ratios for Cd, Mn, Zn and Cu were statistically equivalent for both harbors. Calculated enrichment factors [EF(Me)=(Me/Al)(sample)/(Me/Al)(shale)] indicated that the metals showing slight enrichment were those associated with anthropogenic contamination (Pb, Zn), or probably related to primary productivity in the water column (Cd, Co). The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake.     

Intercomparisons of earth gravity models by means of lumped coefficients: Terms for eccentricity and longitude

The comparisons of the Earth gravity field models by the order of their harmonic coefficients, performed with the basic lumped coefficients (Planet. Space Sci.29, 653, 1981, Paper I) are here extended to cover all harmonic coefficients (both odd and even degree). The lumped coefficients (the “e-terms” and “longitudinal” terms), corresponding to 18 Earth models, are compared mutually (Figs. 2–15). The large differences, observed for various models and orders, are of particular interest: they are gathered into Table 1. The result of Paper I was a little pessimistic. The same is true here: various inhomogeneities, sometimes very large, in the accuracy of the harmonic coefficients must exist—even for low orders. Most of our comments and objections, however, relate to the older Earth models, which have only a historical value now. Our comparisons are only relative ones; an actual test of the accuracy of the models (their calibration) is possible via data with independent status (Kloko?ník, 1982, 1983).     

Morphosedimentary features and recent depositional architectural model of the Cantabrian continental margin

Multibeam bathymetry, high (sleeve airguns) and very high resolution (parametric system-TOPAS-) seismic records were used to define the morphosedimentary features and investigate the depositional architecture of the Cantabrian continental margin. The outer shelf (down to 180–245 m water depth) displays an intensively eroded seafloor surface that truncates consolidated ancient folded and fractured deposits. Recent deposits are only locally present as lowstand shelf-margin deposits and a transparent drape with bedforms. The continental slope is affected by sedimentary processes that have combined to create the morphosedimentary features seen today. The upper (down to 2000 m water depth) and lower (down to 3700–4600 m water depth) slopes are mostly subject to different types of slope failures, such as slides, mass-transport deposits (a mix of slumping and mass-flows), and turbidity currents. The upper slope is also subject to the action of bottom currents (the Mediterranean Water — MW) that interact with the Le Danois Bank favouring the reworking of the sediment and the sculpting of a contourite system. The continental rise is a bypass region of debris flows and turbidity currents where a complex channel-lobe transition zone (CLTZ) of the Cap Ferret Fan develops.The recent architecture depositional model is complex and results from the remaining structural template and the great variability of interconnected sedimentary systems and processes. This margin can be considered as starved due to the great sediment evacuation over a relatively steep entire depositional profile. Sediment is eroded mostly from the Cantabrian and also the Pyrenees mountains (source) and transported by small stream/river mountains to the sea. It bypasses the continental shelf and when sediment arrives at the slope it is transported through a major submarine drainage system (large submarine valleys and mass-movement processes) down to the continental rise and adjacent Biscay Abyssal Plain (sink). Factors controlling this architecture are tectonism and sediment source/dispersal, which are closely interrelated, whereas sea-level changes and oceanography have played a minor role (on a long-term scale).     

Miocene extensional detachments in the outcropping basement of the northern Alboran Basin (Betics) and their tectonic implications

Whether or not there are extensional detachment faults in the Alboran basement can be tested directly because a part of the Alboran Basin is now emerged. These detachments, related to crustal thinning beneath the Alboran Basin, occurred from the Aquitanian to Tortonian. The resulting extensional geometries can be described in general terms. During the Serravalian a considerable southwest extension of the basin took place, accompanied by south-southeast extension in the northern Gibraltar Arc. Other detachments affected by Serravalian extension can be found. The spreading of the Alboran was nearly coeval with roughly westward migration of the Gibraltar mountain front.     

Stratigraphic framework of gas accumulations in the Ría de Pontevedra (NW Spain)

Knowledge of marine geological environments in which shallow gas is accumulating is becoming increasingly important in global studies of climate change because a measurable proportion of the total methane source comes from continental margins. Previous studies have revealed that coastal environments represent important geological environments where microbial methane is being generated, is accumulating, and is being released. In the Ría de Pontevedra, at least 4.5 km² of seafloor in the innermost part of the ría is underlain by sediments containing natural gas. Seismic interpretation contributes new findings for the definition of periods and geological environments in which the gas could have been generated, and is accumulating and released in the Ría de Pontevedra. Groundtruthing the seismic data (facies, environments) makes it possible to identify favourable geological environments for gas generation in the sedimentary infill of the Ría de Pontevedra. Sequence stratigraphy based on high-resolution seismic profiles and post-Last Glacial Maximum sea-level records makes it possible to establish the stratigraphic architecture of the ría and to define the periods in which gas could have been generated. The results of this study show that the sedimentary infill is composed of a fifth-order sequence developed since the Last Glacial Maximum. Within this sequence, gas appears to have accumulated in the Holocene deposits associated with the latest transgressive and highstand system tracts. Seismic analysis shows that gas could have been generated in different geological environments in the Ría de Pontevedra. If coastal environments at times of lower sea level were similar to those of the present, organic-rich mud deposits (deposited mainly in lakes, estuaries and floodplains) could have survived transgression and remained buried as potential gas sources in the inner part of the ría.     

Dynamics of arrays of floating point-absorber wave energy converters with inter-body and bottom slack-mooring connections

If point absorbers are employed in the extensive exploitation of the offshore wave energy resource, they should be deployed in arrays, the distance between the elements in the array being possibly tens of meters. In such cases, it may be more convenient that the array is spread moored to the sea bottom through only some of its elements, located in the periphery, while the other array elements are prevented from drifting and colliding with each other by connections to adjacent elements. An array of identical floating point absorbers located at the grid points of an equilateral triangular grid is considered in the paper. A spread set of slack-mooring lines connect the peripheric floaters to the bottom. A weight is located at the centre of each triangle whose function is to pull the three floaters towards each other and keep the inter-body mooring lines under tension. The power take-off system (PTO) is a linear damper activated by the buoy heaving motion. The whole system–buoys, moorings and power take-off systems–is assumed linear, so that a frequency domain analysis may be employed. Hydrodynamic interference between the oscillating buoys in array is accounted for. Equations are presented for a set of three identical point absorbers. This is then extended to more complex equilateral triangular grid arrays. Results from numerical simulations, with regular and irregular waves, are presented for the motions and power absorption of hemispherical converters in arrays of three and seven elements and for different mooring parameters and wave incidence angles. Comparisons are given with the unmoored and independently-moored buoy situations.     

Assessment of soil factors controlling ephemeral gully erosion on agricultural fields

The soil factor is crucial in controlling and properly modeling the initiation and development of ephemeral gullies (EGs). Usually, EG initiation has been related to various soil properties (i.e. sealing, critical shear stress, moisture, texture, etc.); meanwhile, the total growth of each EG (erosion rate) has been linked with proper soil erodibility. But, despite the studies to determine the influence of soil erodibility on (ephemeral) gully erosion, a universal approach is still lacking. This is due to the complex relationship and interactions between soil properties and the erosive process. A feasible soil characterization of EG erosion prediction on a large scale should be based on simple, quick and inexpensive tests to perform. The objective of this study was to identify and assess the soil properties – easily and quickly to determine – which best reflect soil erodibility on EG erosion. Forty‐nine different physical–chemical soil properties that may participate in establishing soil erodibility were determined on agricultural soils affected by the formation of EGs in Spain and Italy. Experiments were conducted in the laboratory and in the field (in the vicinity of the erosion paths). Because of its importance in controlling EG erosion, five variables related to antecedent moisture prior to the event that generated the gullies and two properties related to landscape topography were obtained for each situation. The most relevant variables were detected using multivariate analysis. The results defined 13 key variables: water content before the initiation of EGs, organic matter content, cation exchange capacity, relative sealing index, two granulometric and organic matter indices, seal permeability, aggregates stability (three index), crust penetration resistance, shear strength and an erodibility index obtained from the Jet Test erosion apparatus. The latter is proposed as a useful technique to evaluate and predict soil loss caused by EG erosion. Copyright © 2018 John Wiley & Sons, Ltd.     

Microscopy and rock magnetism of fine grain-size titanomagnetite from the Jacupiranga Alkaline Complex,Brazil: unearthing Ti-magnesioferrite nanoparticles

Very fine samples from the mineralized zones of the Jacupiranga complex at the Cajati mine were selected for crystallographic identification of Ti-magnesioferrite (TMf) nanostructures embedded in titanomagnetite (TM) using high-resolution transmission electron microscopy (TEM). A magnetic concentrate obtained of pyroxenite samples (sites 4 to 7) was reduced and divided into fractions of distinct range sizes: 26±2 μm, 19±1 μm, 13±1 μm, 9±1 μm, 6±1 μm and 6-0.1 μm. The mineralized samples of carbonatite and pyroxenite were characterized by X-ray diffraction, transmitted and reflected light microscope, and scanning electron microscope with multielemental analysis. The finest magnetic concentrate sample (MC₆) was analyzed under high-resolution transmitted electron microscopy (TEM) and high angle annular dark field and Raman spectroscopy. Magnetic properties were measured for the distinct granulometric fractions, showing drastic changes when grain sizes go beyond the frontier from micro to nanometer sizes. Frequency-dependent magnetic susceptibility percentage (÷_fd%) report higher values (10.2%) for the finer fractions (6±1 μm and 6-0.1 μm) attributed to dominant fractions of superparamagnetic particles. Nanometer and < 6 μm grain size TMf in TM particles require a magnetic field up to 249 mT to reach saturation during the isothermal remanent magnetization experiment. Coercivity and remanent magnetization of these samples increase when the particle size decreases, probably due to parallel coupling effects. Magnetic susceptibility versus temperature experiments were conducted two times on the same (< 35 nm) sample, showing that the repetition during the second heating is probably due to the formation of new TMf nanoparticles and growth of those already present during the first heating process.     

Probabilistic calibration of a distributed hydrological model for flood forecasting

Abstract

The complexity of distributed hydrological models has led to improvements in calibration methodologies in recent years. There are various manual, automatic and hybrid methods of calibration. Most use a single objective function to calculate estimation errors. The use of multi-objective calibration improves results, since different aspects of the hydrograph may be considered simultaneously. However, the uncertainty of estimates from a hydrological model can only be taken into account by using a probabilistic approach. This paper presents a calibration method of probabilistic nature, based on the determination of probability functions that best characterize different parameters of the model. The method was applied to the Real-time Interactive Basin Simulator (RIBS) distributed hydrological model using the Manzanares River basin in Spain as a case study. The proposed method allows us to consider the uncertainty in the model estimates by obtaining the probability distributions of flows in the flood hydrograph.

Citation Mediero, L., Garrote, L. & Martín-Carrasco, F. J. (2011) Probabilistic calibration of a distributed hydrological model for flood forecasting. Hydrol. Sci. J. 56(7), 1129–1149.     

Validation of methods to estimate design discharge flow rates for dam spillways with large regulating capacity

Abstract

The estimation and review of discharge flow rates in hydraulic works is a fundamental problem in water management. In the case of dams with large regulating capacity, in order to estimate return periods of discharge flow rates from the spillways, it becomes necessary to consider both peak flow and volume of the incoming floods. In this paper, the results of the validation for several methods of assessing design floods for spillways of dams with a large flood control capacity are presented; the validation is performed by comparing the maximum outflows (or the maximum levels reached in the reservoir) obtained from the routing of the design floods with those obtained from the routing of the historical annual maximum floods. The basin of Malpaso Dam, Mexico, is used as the case study.

Editor D. Koutsoyiannis

Citation Domínguez, M.R. and Arganis, J.M.L., 2012. Validation of methods to estimate design discharge flow rates for dam spillways with large regulating capacity. Hydrological Sciences Journal, 57 (3), 460–478.