Usage of chromite wastes as aggregate in foam concrete production

The rapidly developing mining sector in recent years has also brought environmental problems together. At the beginning of these problems are mine process wastes produced in high quantities from mines every year. The waste material at 90% and the concentrate chromite at 10% are obtained in the chromite ore enrichment plants. This significant amount of waste creates pollution in nature visually and physically. The aim of the study is to determine the advantages of using foamed concrete as a building material, to reduce the production cost of foamed concrete, to produce alternative solutions for rehabilitation, and to eliminate environmental pollution. The chromite enrichment wastes obtained from Fethiye, Köyce?iz, Denizli and Burdur regions were used as aggregates in the production of foamed concrete. In this study, compressive strength experiments were carried out according to TS EN 1354, thermal conductivity experiments were carried out according to TS EN 12664. As a result, it has been observed that chromite waste (dunite) can be used in the production of foamed concrete under certain conditions.     

Upper crustal electrical resistivity structures in the vicinity of the Çatalca Fault, Istanbul, Turkey by magnetotelluric data

A magnetotelluric survey was performed at the Çatalca Region, west of Istanbul, Turkey with the aim of investigating geoelectrical properties of the upper crust near the Çatalca Fault and its vicinity. Broadband magnetotelluric data were collected at nine sites along a single southwest-northeast profile to image the electrical resistivity structure from surface to the 5 km depth. The dimensionality of the data was examined through tensor decompositions and highly two-dimensional behavior of the data is shown. Following the tensor decompositions, two-dimensional inversions were carried out where E-polarization, B-polarization and tipper data were utilized to construct electrical resistivity models. The results of the inversions suggest: a) the Çatalca Fault extends from surface to 5 km depth as a conductive zone dipping to southwest; b) the thickness of the sedimentary cover is increasing from SW to NE to 700 m with low resistivity values between 1–100 Ωm; c) the crystalline basement below the sedimentary unit is very resistive and varies between 2000–100000 Ωm; d) a SW-dipping resistivity boundary in the northeastern part of our profile may represent the West Black Sea Fault.     

Settling of Kaolinite in Different Aqueous Environment

Settling characteristics of soils carry great importance for geotechnical engineers since sediments properties are formed during the settling of soil particles in an aqueous environment. In this study, settling characteristics of kaolinite are investigated. Different ionic strengths of NaCl, CaCl₂ and AlCl₃ were considered as a function of pH in aqueous environment of varying solid concentrations. Factors affecting the settling characteristics and fabric of kaolinitic sediments have been identified. The results of the study reveal that kaolinite settles in either flocculated or dispersed forms depending on pH and ion concentration. Flocculated settling occurs in acidic pH due to formation of flocs in edge-to-face structure with increasing positive charges at the particle edges. Dispersed settling occurs in alkaline pHs when ionic strength is low. When ionic strength is increased in alkaline pHs, kaolinite particles settle in flocculated form. Furthermore, the results show that pH has a significant role on the final sediment thickness or void ratio of kaolinite. Densely packed structures in alkaline and loosely packed structures in acidic aqueous environments are formed depending on pH level. Results also show that as the solid concentration increases, the settling rate decreases due to buoyancy effect. Finally, the zeta potential of kaolinite is correlated with the final sediment thickness or void ratio of kaolinite as a function of pH. This correlation proves that there is a good agreement between zeta potential and the final sediment thickness or void ratio, especially when the soil is settled in a dispersed form.     

Deciphering factors controlling trace element distribution in the soils of Karaduvar industrial-agricultural area (Mersin,SE Turkey)

In this study, 30 topsoil samples were collected from Karaduvar area (Mersin, SE Turkey) where at present various industrial and agricultural activities are occurring. Using a five-step ultrasound-assisted sequential extraction (UASE) procedure, trace elements in soil samples were partitioned into the following: (1) soluble-exchangeable; (2) bound to carbonates; (3) bound to Fe- and Mn-oxides; (4) bound to organic matter and sulfide compounds, and (5) residual fraction. Concentrations of 11 trace elements in the extracts were determined using ICP-MS. Total concentrations ranged between (in mg kg⁻¹) 3.35 and 7.26 for As; 1.18 and 3.96 for Cd; 10.76 and 20.26 for Co; 37.99 and 63.48 for Cr; 18.55 and 243.1 for Cu; 338.7 and 565.6 for Mn; 4.42 and 6.44 for Mo; 148 and 279.3 for Ni; 10.12 and 73.71 for Pb; 17.93 and 36.55 for V, and 25.46 and 331.7 for Zn. Factor analysis was applied to dataset in order to discriminate between natural and anthropogenic pollution sources and factors controlling the spatial distribution of trace elements in the area. Results suggest that distributions of Co, Cr, Mn, and Ni are mainly controlled by lithological factors, whereas, distributions of Cu, Pb, and Zn can be attributed to agricultural activities such as pesticide/herbicide use and fertilizer application, as well as irrigation with petroleum hydrocarbon-contaminated groundwater. Highest concentrations of Cd and Mo are generally observed around the diesel-fired thermal power plant and ATAŞ refinery. Highest concentrations of As and V are generally observed at the NW sector of the area; however, no definitive source can be designated for both of these elements.