Removal of Carbamazepine,Naproxen, and Trimethoprim from Water by Amberlite XAD‐7: A Kinetic Study

The adsorption kinetics of carbamazepine, naproxen, and trimethoprim in aqueous solution by Amberlite? XAD‐7 has been studied. The influence of adsorbent dose (1–3 g/L), stirring rate (80–240 rpm), pH (2–9), temperature (20–60°C), and initial concentration (25–75 ppm) on the adsorption kinetics has been analyzed. The removal efficiency in the first 2 h reaches 85% for carbamazepine, 60% for naproxen, and 70% for trimethoprim. pH appears to be the most important factor conditioning the removal of these latter solutes, whereas carbamazepine adsorption seems to be independent of the pH of the adsorptive solution. Initial concentration and operation temperature moderately influence the adsorption process. Finally, stirring rate scarcely affects the process. The experimental data have been fitted to four kinetic models, namely pseudo‐first and pseudo‐second order, intra‐particle diffusion and Bangham's. The model providing the best fit is the pseudo‐second order one. Again, pH is the factor that affects the adsorption rate in a more remarkable manner although other parameters such as temperature and stirring rate also contribute to accelerate the removal of the solutes. Under the optimal operation conditions, Amberlite? XAD‐7 exhibits a promising ability for the removal of the pharmaceuticals under study.     

Towards integrated geographical information processing

Many geographical applications access data from multiple disparate repositories such as file systems, Geographical Information Systems and database management systems which contain data able to be interrelated. Existing approaches that either built a single repository that contain all the required data or simply interconnect these repositories have not been well received. In this paper, we present the design of the Virtual GIS, a system for distributed spatial data processing in heterogeneous environments. The Virtual GIS is an integrated system that provides all the essential facilities for integrating and retrieving data from multiple component systems.The system isparticularly aimed at extensibility and scalability through distributing the processing load across the component systems and a global frontend. The object-oriented data model is adopted as a common data model to ensure meaningful data sharing. We also employ the fivelevel schema architecture of Sheth and Larson as the framework for system integration. Finally, queries are processed using a five-phase query processing approach.     

Enhanced Atlantic Meridional Overturning Circulation supports the Last Glacial Inception

The Atlantic Meridional Overturning Circulation (AMOC) is a key feature of the climate system. However, its role during climate change is still poorly constrained particularly during an Interglacial to Glacial climate transition and the associated global cooling. We present here the first reconstruction of the evolution of the vertical structure of the rate of the AMOC from the Last Interglaciation to the subsequent glaciation (128,000–60,000 years ago) based on sedimentary (²³¹Pa/²³⁰Th) records. We show a deep AMOC during the interglacial warmth Marine Isotope Stage (MIS) 5.5 and a shallower glacial one during glacial MIS 4. The change between these two patterns occurred mostly during the glacial inception, i.e. the transition from MIS 5.5 to MIS 5.4. Our data show that AMOC was enhanced during this latter transition as a consequence of a large increase of the overturning rate of the Intermediate Waters, above 2500 m. We suggest that this AMOC pattern required a reinforced Gulf Stream-North Atlantic Current system that ultimately supported ice-sheet growth by providing heat and moisture to the Northern high latitudes. From MIS 5.4 to MIS 5.1, the AMOC was broadly continuous below 2000 m and supported periods of ice-sheet growth. As a result, a glacial AMOC is triggered at the beginning of MIS 4 due to the extension of ice-sheet and the subsequent reorganization of deep-water formation. This study highlights the role of intermediate waters as a major player during climate change.     

250 years of sardine and anchovy scale deposition record in Mejillones Bay, northern Chile

Marine oxygen-deficient environments with high sedimentation rates and high primary productivity can provide relevant information regarding variations of ocean–climatic conditions in the past. In the Humboldt current ecosystem, which now hosts huge populations of pelagic fishes (mainly anchovy and sardine), fish scale abundance in the sedimentary record may be useful indicators of environmental change. Here we assess such a proxy record in a 42 cm-long sedimentary core collected from 80 m in Mejillones Bay (23°S, northern Chile). We also analyse fish remains in surface sediment sampled along a bathymetric transect (from 10 to 110 m water depth) in the same bay. In the core-top record, the fluctuations of sardine and anchovy scale deposition rates (SDR) agreed with those of industrial catches for these two species in northern Chile, tending to validate the SDR as a proxy of local fish biomass when bottom anoxic conditions prevail. However, apparent SDR for records prior to 1820 have probably been influenced by dissolution processes linked to the oxygenation of the bottom environment of Mejillones Bay, as suggested by other proxy records. After 1820, the fluctuations in the relative abundance of sardine and anchovy scales point to alternating warm and cold conditions during about 30 years and then a progressively cooler period. Since ca. 1870, marked fluctuations of SDR of both species are observed, probably as a consequence of the onset of a different oceanographic regime characterized by intensified upwelling, stronger subsurface oxygen deficiency, higher primary productivity, and enhanced “ENSO-like” interdecadal variability. While anchovy SDR fluctuated in periods of 25–40 years, only two peak periods of sardine SDR occurred (late 19th century and late 20th century), suggesting that sardine abundance depends on other ocean–climatic factors.     

Geochemistry of volcanic glass from Oligocene detrital sediments at DSDP Site 296, Kyushu Palau Ridge: Interpreting the magmatic evolution of the early northern Izu–Bonin–Mariana Island Arc

Understanding the petrologic and geochemical evolution of island arcs is important for interpreting the timing and impacts of subduction and processes leading to the formation of a continental crust. The Izu–Bonin–Mariana (IBM) Arc, western Pacific, is an outstanding location to study arc evolution. The IBM first arc (45–25 Ma) followed a period of forearc basalt and boninite formation associated with subduction initiation (52–45 Ma). In this study, we present new major and trace element data for the IBM first arc from detrital glass shards and clasts from DSDP Site 296, located on the northernmost Kyushu Palau Ridge (KPR). We synthesize these data with published literature for contemporaneous airfall ash and tephra from the Izu–Bonin forearc, dredge and piston core samples from the KPR, and plutonic rocks from the rifted eastern KPR escarpment, locations which lie within or correlate with KPR Segment 1 of Ishizuka, Taylor, Yuasa, and Ohara (2011). Our objective is to test ways in which petrologic and chemical data for diverse igneous materials can be used to construct a complete picture of this section of the Oligocene first arc and to draw conclusions about its evolution. Important findings reveal that widely varying primary magmas formed and differentiated at various depths at this location during this period. Changes in key trace element ratios such as La/Sm, Nb/Yb, and Ba/Th show that mantle sources varied in fertility and in the inputs of subducted sediment and fluids over time and space. Plutonic rocks appear to be related to early K‐poor dacitic liquids represented by glasses sampled both in the forearc and volcanic fronts. An interesting observation is that the variation in magma compositions in this relatively small segment encompasses that inferred for the IBM Arc as a whole, suggesting that sampling is a key factor in inferring temporal, across‐arc, and along‐strike geochemical trends.     

Impact of erosion-transported overburden dump materials on water quality in Lake Cospuden evolved from a former open cast lignite mine south of Leipzig, Germany

 Acidification is the most common water quality problem in lakes created from previous open cast lignite mines. Aeration of aquifers and dump materials from mining activities causes pyrite oxidation. Pyrite oxidation products are stored in pore water, minerals and at the exchange complexes of the aquifers and dump sediments. Rainfall runoff transports sediments on the dump slope into the lakes. Elutriation of these sediments whithin the lakes releases either acid-producing or acid-neutralizing agents. At a test site south of Leipzig, the annual erosion rates were quantified by water erosion models (RUSLE, EROSION 2D, PEPP) and field measurements. They ranged from 300 up to 900 tons per hectare. Hydrogen ion equivalent release or binding at the sediment elutriation was computed from laboratory analysis of the pore-water quality, ion exchange complex and mineral composition of the sediment. Two of the three investigated sediments contained 3 mmol (eq) acidity per 100 g dry sediment and revealed saturation with respect to jarosite, jurbanite and gypsum. In the third sediment, 6 mmol (eq) alkalinity per 100 g dry sediment was obtained. The annual net acidity influx was calculated to be about 0.5 million mol (eq) for the lake of the test site. Received: 2 November 1998 · Accepted: 26 January 1999     

Colouration Phenomena of Mediterranean Blennies (Pisces,Blenniidae)

Abstract. The blennies of the Mediterranean Sea were observed in nature by snorkeling and SCUBA diving. Particular attention was paid to their changeable basic patterns and colouring alternations as effected by ecological and ethological factors. Additionally, the tendency for colour change was tested in differently coloured tanks. These experiments failed to demonstrate the striking adaptations seen in the natural environment, except for a remarkable reaction to black and white. The summary of all known reports is supported by colour illustrations; the problems of the colouring alternations are discussed.     

Dry conditions over Argentina and the related monthly circulation patterns

Summary This paper presents an analysis of the frequency and spatial distribution of droughts in Argentina during the 20th century. Special attention is given to the mean monthly atmospheric circulation associated with dry conditions in the Pampas during the second half of the century. A reduction in the number of dry cases is found throughout the century, especially during the warm season (October to March). Droughts occurred more often in only one or two regions simultaneously and only a few covered a large territory. Many of the dry months in the Pampas occurred under, or were preceded by, neutral ENSO conditions. During the warm season the ENSO cold phase preceded some of the dry months. Circulation patterns at 1000 hPa and 500 hPa and their temporal evolution are determined using Principal Component Analysis. A coupled 1000-500 hPa level analysis is performed to study the vertical coherence associated with dry conditions. Different patterns related to the warm season are clearly identified using this methodology. The principal feature are positive anomalies over the continent (principally at low levels), high circulation index and an enhancement of the westerlies. Patterns related to the cold season reflect high pressure at the surface, but some differences pre- and post- 1970 have been observed. In this season, some dry cases were found to have high correlations with opposites modes of PC scores. In these cases, a water deficit acted as the principal causes of the dry conditions.     

Book Review: Geostatistics Rio 2000, Quantitative Geology and Geostatistics: By M. Armstrong,C. Bettini,N. Champigny,A. Galli,and A. Remacre (eds.) Kluwer Academic Publishers,Dordrecht, 2002, 235 p., $94 (U.S.), ISBN 1-4020-0470-2 (hard back)

Mathematical Geosciences -     

Analysis of electrojet-distorted magnetotelluric sounding curves

South America presents several unique geomagnetic features, one of which is the Equatorial Electrojet (EEJ), a current system which extends itself east to west in Northeastern Brazil for almost 3500 km. Considering the fact that the influence of this phenomenon at low magnetic latitudes can be detected at great distances from its central axis, it is important to simulate its effect in magnetotelluric (MT) exploration. To accomplish this and by the use of an integral equation scheme, we have modeled the MT response of confined three-dimensional (3D) bodies (dykes in an homogeneous half-space) and deep 3D structures (horst and graben located at Marajo Basin in Northern Brazil). As the inductive source, we replace the classical plane wave source by a common line of current, besides gaussian and undulatory electrojets. The results of the modelling indicate that the studied effect is prominent in both one-dimensional (1D) and 3D media for periods (T) greater than 10 s. It decreases with distance, but it is detectable as far as 3000 km from the center of the EEJ. It is also observed that for T greater than 10 s, the computed soundings can be strongly distorted, mainly by EEJ effects in the host medium which, in turn, cause changes in the final branch of the 3D soundings. For structures in the Marajo Basin, our results reveal that the 3D galvanic effect prevails in the interval 0.1<T<10 s, while source influence occurs mainly for T>10 s. On the other hand, automatic inversion of these 3D data shows that, in equatorial regions having complex geology, some errors arise in conventional 1D interpretation of the MT soundings. This is due to the superposition of the host medium response, the galvanic effect of 3D structures, and the EEJ influence.