Regional studies of dolomites and their included fluids: recognizing multiple chemically distinct fluids during the complex diagenetic history of Lower Carboniferous (Mississippian) rocks of the Irish Zn-Pb ore field

This study provides a regional framework within which studies of ore-related dolomite and dolomite cements may be placed. Fluid inclusion data indicate the presence of three distinct fluids following early dolomitization: 1) a ubiquitous low-temperature, higher salinity fluid found in saddle dolomite; 2) a low-temperature, lower salinity fluid limited to sub-Waulsortian and Waulsortian carbonates; and 3) a higher temperature, lower salinity fluid found in Waulsortian and supra-Waulsortian rocks. Similar fluids have been reported in ore-associated minerals and postmineralization dolomite (Type 1) and in ore-stage carbonates and sphalerite (Types 2 and 3). The halogen geochemistry of included fluids indicates genesis from evaporated seawater. Type 1 fluids are enriched in chloride relative to bromide, reflecting a component of salinity derived via dissolution of halite or from dehydration of seawater. These data suggest that dolomitization and mineralization of Mississippian rocks in the Midlands requires both regionally extensive and localized fluid flow.     

Preliminary Examination of How Human-driven Freshwater Flow Alteration Affects Trophic Ecology of Juvenile Snook (<Emphasis Type="Italic">Centropomus undecimalis</Emphasis>) in Estuarine Creeks

Maintaining proper freshwater and marine inputs is essential for estuarine function. Alteration of freshwater flows into small tributaries that traverse the upland-estuarine margin may be especially problematic, e.g., by impacting the nursery areas for juvenile finfish and shellfish. We used stomach contents and stable isotope analysis (δ¹³C, δ¹⁵N) to examine effects of freshwater flow alterations on the trophic ecology of juvenile common snook (Centropomus undecimalis) in four mangrove creeks with different freshwater flow regimes. Diet diversity in less degraded creeks was greater than in more degraded creeks, and the importance (by % mass) of the top three preys was disproportionately higher in the more degraded creeks. Stable isotope measures of trophic diversity corroborate these trends, suggesting higher intraspecific trophic diversity in less degraded creeks. The difference in diet diversity of juvenile snook may be an indicator of an overall change in ecosystem function and these shifts in food web structure may affect the rate that juveniles of this and other species with similar habitat requirements successfully join the adult population.     

Petrology of lavas from the Puu Oo eruption of Kilauea Volcano: III. The Kupaianaha episode (1986–1992)

 The Puu Oo eruption has been remarkable in the historical record of Kilauea Volcano for its duration (over 13 years), volume (>1 km³) and compositional variation (5.7–10 wt.% MgO). During the summer of 1986, the main vent for lava production moved 3 km down the east rift zone and the eruption style changed from episodic geyser-like fountaining at Puu Oo to virtually continuous, relatively quiescent effusion at the Kupaianaha vent. This paper examines this next chapter in the Puu Oo eruption, episodes 48 and 49, and presents new ICP-MS trace element and Pb-, Sr-, and Nd-isotope data for the entire eruption (1983–1994). Nearly aphyric to weakly olivine-phyric lavas were erupted during episodes 48 and 49. The variation in MgO content of Kupaianaha lavas erupted before 1990 correlates with changes in tilt at the summit of Kilauea, both of which probably were controlled by variations in Kilauea's magma supply rate. These lavas contain euhedral olivines which generally are in equilibrium with whole-rock compositions, although some of the more mafic lavas which erupted during 1990, a period of frequent pauses in the eruption, accumulated 2–4 vol.% olivine. The highest forsterite content of olivines (∼85%) in Kupaianaha lavas indicates that the parental magmas for these lavas had MgO contents of ∼10 wt.%, which equals the highest observed value for lavas during this eruption. The composition of the Puu Oo lavas has progressively changed during the eruption. Since early 1985 (episode 30), when mixing between an evolved rift zone magma and a more mafic summit reservoir-derived magma ended, the normalized (to 10 wt.% MgO) abundances of highly incompatible elements and CaO have systematically decreased with time, whereas ratios of these trace elements and Pb, Sr, and Nd isotopes, and the abundances of Y and Yb, have remained relatively unchanged. These results indicate that the Hawaiian plume source for Puu Oo magmas must be relatively homogeneous on a scale of 10–20 km³ (assuming 5–10% partial melting), and that localized melting within the plume has apparently progressively depleted its incompatible elements and clinopyroxene component as the eruption continued. The rate of variation of highly incompatible elements in Puu Oo lavas is much greater than that observed for Kilauea historical summit lavas (e.g., Ba/Y 0.09 a^–1 vs ∼0.03 a^–1). This rapid change indicates that Puu Oo magmas did not mix thoroughly with magma in the summit reservoir. Thus, except for variable amounts of olivine fractionation, the geochemical variation in these lavas is predominantly controlled by mantle processes. Received: 8 March 1996 / Accepted: 30 April 1996     

Five hundred million years of punctuated addition of juvenile crust during extension in the Goochland Terrane,central Appalachian Piedmont Province

ABSTRACT

The Goochland Terrane is an enigmatic crustal block in the Appalachian Piedmont Province of central Virginia, USA. Sparse exposures of terminal Mesoproterozoic and late Neoproterozoic igneous rocks in the central Goochland Terrane offer the opportunity to investigate both the continental affinity of the terrane during the Proterozoic Eon and the timing and mechanisms of crustal growth. We apply multiple geochemical tools to these rocks: tectonic discrimination using whole-rock major and trace element abundances; whole-rock Sm-Nd isotopes; O, U-Pb, and Lu-Hf isotope analyses of spots in zircon; and measurement of O isotopes in multi-grain quartz separates. Eruption of the Sabot Amphibolite protolith is difficult to date, but we tentatively assign an age of 552 ± 11 Ma. Goochland Terrane continental crust first separated from the mantle prior to ca. 1050–1010 Ma intrusion of the Montpelier Anorthosite and the State Farm Gneiss protolith. The granitic magma that became the State Farm Gneiss protolith could have been derived entirely from partial melting of this initial Goochland Terrane crust. In contrast, the magmas that became the Montpelier Anorthosite, Neoproterozoic granitoid, and the Sabot Amphibolite were mixtures of mantle melt and preexisting Goochland Terrane crust. This production of juvenile continental crust occurred during continental extension and, eventually, rifting. The timing and compositions of terminal Mesoproterozoic magmatism in the Goochland Terrane closely match those in the nearby Blue Ridge Province. Although the compositions of the Neoproterozoic magmas in the two regions are similar, intrusion and possibly eruption occurred about 10 M.y. later in the Goochland Terrane.     

Multicomponent solute transport with sorption and soluble complexation

A numerical algorithm for predicting the migration of multiple subsurface pollutants has been developed accounting for dispersion, convection, soluble complexation and solid phase accumulations (sorption). The basis of the model is a finite element solution of the mass transport equation. The essence of the algorithm is the treatment of the sorption terms as implicit functions of the total soluble concentrations facilitating a general and modularized treatment of solution phase and solid phase chemistry. Examples are presented illustrating the effects of soluble complexation and competitive sorption on the transport of multicomponent solutions.     

Spatial distribution of surface conditions and runoff generation in small arid watersheds, Zin Valley Badlands, Israel

High rill density may be regarded as indicative of frequent and integrated runoff along a drainage network. However, field observations of soil development and rill geometry in small, first-order catchments (0.1 to 1 ha) of the Zin Valley Badlands, northern Negev, Israel, suggest a pattern of partial area contribution and frequent flow discontinuities along hillslopes and channels. Changing soil properties, associated with an increase of slope angle and slope length, appear to be responsible for high infiltration on the slopes, leading to nonuniform runoff generation within small drainage basins. Runoff observation, sprinkling tests, and soil analysis along ridges and sideslopes were carried out to test this hypothesis. The results confirmed that infiltration capacity on the sideslopes is significantly higher than on the ridges. Under current rainfall conditions, only extreme rainfall intensities are sufficient to generate runoff along entire slopes. The discontinuous nature of most runoff events causes erosion on ridges and deposition on slopes, which enhances soil development on the valley sideslopes, creating a positive feedback on infiltration rate and depth. This demonstrates that the links between within-storm rainfall conditions and spatial distribution of soil characteristics have to be incorporated into our understanding of landscape development in badlands.     

Constructed wetland technology and mosquito populations in Arizona

Constructed wetlands and other aquatic habitat creation or restoration efforts offer both potential benefits and problems for arid areas. An unintentional consequence of these efforts has been the potential for an increase in local adult mosquito populations. Shallow water-emergent plant zones may provide ideal conditions for mosquito larval growth, and areas of high humidity, dense vegetation, and abundant birds and other wildlife may provide ideal conditions for adult mosquitoes. Three constructed wetlands in southern Arizona were studied over a period of years before and after they were constructed and operational. Mosquito populations were sampled using a variety of methods, primarily trapping of adults with CO₂-baited traps. Populations apparently increased, sometimes by several orders of magnitude, after wetlands became operational. Several methods of mosquito abatement were initiated and their results are discussed. However, no definitive conclusions can be drawn because no untreated areas were available for comparison and many factors that may have affected mosquito populations also changed. Based on the experience gained at these three sites, mosquito control is an especially important design and management component for constructed wetlands in arid environments with low background populations of mosquitoes.     

New strategies to detect life on Mars

If we are to find unequivocal evidence for life on Mars, we will need new ways to search for it. Jeff L Bada and the MOD team describe the innovative strategy developed for the ExoMars mission.