生物炭对磷石膏中磷的固化作用

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。     

处理水环境中微量铬的菌种筛选研究

从云南各地采集微生物菌种进行筛选、驯化,找到一株对水环境中的微量铬具有良好吸附去除能力的菌种,并研究了碳源、氮源、培养液pH值和培养温度等因素对其去除铬的影响.试验结果表明,去除水环境中微量铬的适宜菌种的培养条件为以可溶性淀粉为碳源、（NH4）2SO4为氮源、培养温度25℃、培养液pH 8,培养液中碳：氮=10：1,利用该条件培养的菌种对水环境中微量铬具有较好的去除能力.     

Learning to trade ethically: Knowledgeable capitalism, retailers and contested commodity chains

This paper explores what happens when corporations engage explicitly in practices of organisational learning not only to become better capitalists by generating ever more innovative ways of maintaining profitability, improving competitiveness and maximising shareholder value, but also to become more responsible corporate citizens in their business practices. In particular, I evaluate the ways in which UK food and clothing retailers are learning to develop their ethical trading programmes in response to political calls for more responsible trading. Thrift’s [Thrift, N., 2005. Knowing Capitalism. Sage, London] notion of ‘knowledgeable, or soft, capitalism’ is adopted to understand the creative and experimental ways in which retailers and their mentors (ethical consultancies, social auditors and multi-stakeholder organisations) are learning to trade ethically. Two specific examples of formal learning spaces experienced by UK food and clothing retailers are examined: (i) training courses on social auditing and (ii) corporate awareness-raising courses on ethical trade. These courses are shown to encompass various participative and affective practices of learning. And while particular limits to the success of these courses are argued to exist, ethical learning practices discussed in this paper are nonetheless suggested to play a role in the making of new, albeit moderate, forms of responsible capitalism.     

Cretaceous and Tertiary terrane accretion in the Cordillera Occidental of the Andes of Ecuador

New field, geochronological, geochemical and biostratigraphical data indicate that the central and northern parts of the Cordillera Occidental of the Andes of Ecuador comprise two terranes. The older (Pallatanga) terrane consists of an early to late (?) Cretaceous oceanic plateau suite, late Cretaceous marine turbidites derived from an unknown basaltic to andesitic volcanic source, and a tectonic mélange of probable late Cretaceous age. The younger (Macuchi) terrane consists of a volcanosedimentary island arc sequence, derived from a basaltic to andesitic source. A previously unidentified, regionally important dextral shear zone named the Chimbo-Toachi shear zone separates the two terranes. Regional evidence suggests that the Pallatanga terrane was accreted to the continental margin (the already accreted Cordillera Real) in Campanian times, producing a tectonic mélange in the suture zone. The Macuchi terrane was accreted to the Pallatanga terrane along the Chimbo-Toachi shear zone during the late Eocene, probably in a dextral shear regime. The correlation of Cretaceous rocks and accretionary events in the Cordillera Occidental of Ecuador and Colombia remains problematical, but the late Eocene event is recognised along the northern Andean margin.     

北江大堤植草护坡效应研究

北江大堤在航运的浪涛侵蚀以及洪水和雨水的冲蚀下，部分河段边坡已变得支离破碎，对广州和珠江三角洲地区的防洪安全构成了严重威胁。香根草和百喜草都能耐较长时间的水淹，并都有较强的抗逆性。结合土石方工程，并辅以三维网覆盖，将香根草和百喜种在北江两岸的边坡上。结果，这一护坡措施不仅有较地防止了洪流冲蚀和雨水侵蚀，较好地起到了固土护坡作用，而且绿化美化了河岸边坡，成功解决了河湖水库的河岸带难以植被覆盖的难题。     

黑龙江东安金矿床成因探讨

东安金矿床是黑龙江省新近发现的大型浅成热液金矿床。受断裂和隐爆角砾岩带控制，赋存于中生代陆相火山-侵入岩及晚印支期碱长花岗岩强硅化带中。成矿与火山-侵入岩作用有密切成生关系。通过对矿区内矿化围岩和基底岩石的金丰度和稀土元素特征的研究，以及对石英中包裹体测温、盐度、液相成分、氢-氧同位素特征的研究，认为该矿床的成矿物质主要来源于基底变质岩；成矿温度为144℃～348℃；成矿深度约0．2km～1．0km；成矿时代为中燕山晚期，为一浅成热液低硫型金矿床。     

What is the source of baseflow in agriculturally fragmented catchments? Complex groundwater/surface‐water interactions in three tributary catchments of the Wabash River,Indiana, USA

Some conceptual models suggest that baseflow in agriculturally fragmented watersheds may contain little, if any, groundwater. This has critical implications for stream quality and ecosystem functioning. Here, we (a) identify the sources and flowpaths contributing to baseflow using ²²²Rn and ⁸⁷Sr/⁸⁶Sr and (b) quantify mean apparent ages of groundwater and baseflow using multiple isotopic tracers (CFC, SF₆, ³⁶Cl, and ³H) in 4 small (0.08 to 0.64 km²) tributary catchments to the Wabash River in Indiana, USA. ²²²Rn activities and ⁸⁷Sr/⁸⁶Sr ratios indicate that baseflow in 3 catchments is sourced primarily from groundwater; baseflow in the fourth is dominated by a source similar to agricultural run‐off. CFC‐12 data indicate that springs in 1 catchment are discharging significant proportions of water that recharged between 1974 (42 ± 2 years) and 1961 (55 ± 2 years). Those same springs have ³⁶Cl/Cl ratios between 1,381.08 ± 29.37 (×10^?15) and 1,530.64 ± 27.65 (×10^?15) indicating that a substantial proportion of the discharge likely recharged between 1975 (41 years) and 1950 (66 years). Groundwater samples collected from streambed mini‐piezometers in a separate catchment have CFC‐12 concentrations indicating that a large proportion of the recharge occurred between 1948 (68 ± 2 years) and 1950 (66 ± 2 years). Repeat sampling conducted in September 2015 after above‐average summer rainfall did not show significant decreases in mean apparent age. The relatively old ages observed in 3 of the catchments can be explained by geological complexities that are likely present in all 4 catchments, but overwhelmed by flow from the shallow phreatic aquifer in the fourth catchment.