Response of base-isolated buildings to wind loading

The response of base-isolated buildings to gusting wind is analysed theoretically based on experimental data obtained in a boundary layer wind tunnel. A comparison is made with the response evaluated using existing codes. A special procedure, similar to that of current codes, for computing the alongwind and torsional responses of base-isolated buildings is presented.     

Element zoning trends in olivine phenocrysts from a supposed primary high-magnesian andesite: an electron- and ion-microprobe study

Electron and ion-probe microanalysis have been used to obtain zoning profiles for major and trace elements in olivine phenocrysts from a high-magnesian andesite from Shodo-Shima island, southwest Japan. This rock was previously thought to represent undifferentiated, primary magma. Some crystals have unzoned cores, while others show cores which are reversely zoned with respect to Mg/ (Mg+Fe), Ni, Mn and Cr. In addition, some Ni profiles show a normally zoned hump at the most central portions of the reversely zoned crystals. All crystals show normally zoned rims. The Li concentrations are constant throughout the cores of all crystals studied, but rise sharply, by a factor of up to at least six, in the rims. The Ca and Co concentrations are essentially constant throughout all the crystals. Mechanisms for producing the observed zoning profiles are discussed, and it is concluded that the reverse zoning was produced by the introduction of crystals into a less differentiated magma than that in which they grew. The reversely zoned crystals could therefore represent xenocrysts which were introduced into an undifferentiated magma, or phenocrysts introduced into a more primitive magma by a magma mixing process. The Ni profiles are used to estimate the residence time of these crystals in the more primitive magma. The following trace element partition co-efficients have been estimated for the olivine-groundmass system in this rock: D ^Ni=16; D ^Mn=1.1; D ^Co=4.2; D ^Ca =0.02; D ^Ti=0.005; D ^V=0.05; D ^Sc=0.2; D ^Na=0.0002. Studies of trace element zoning will become increasingly important as the new generation of trace element microprobes become available but a larger database of experimentally determined values for trace element partition coefficients and diffusion coefficients in crystals and magmas, and a better understanding of other disequilibrium processes are required to fully exploit the new data.     

Oxidation state and electronic configuration determination of copper in tetrahedrite group minerals by L-edge X-ray absorption spectroscopy

L-edge X-ray absorption spectroscopy employing a synchrotron radiation source has been used to study the electronic structure and valency of Cu in the chemically and structurally complex tetrahedrite group of minerals. Mechanical mixtures of Cu²⁺O and Cu⁺FeS₂ were used to estimate the relative cross sections of Cu²⁺ and Cu⁺; the absorption of Cu²⁺ at 931 eV is 25 times greater than that of Cu⁺ at 945 eV. Using this calibration, Cu²⁺/Cu ratios were found to vary from 0.00 to 0.054 in the tetrahedrite samples studied; the highest proportion of Cu²⁺ occurs in synthetic tetrahedrites with a composition close to Cu₁₂Sb₄S₁₃. This study reveals the utility of the technique for determining the valence state of copper in complex minerals, allowing the crystal chemistry to be more fully characterised.     

Reaction relationships of chrome-spinels in igneous rocks — further evidence from the layered intrusions of Rhum and Mull,Inner Hebrides,Scotland

Compositions of chrome-spinels in peridotites from the layered igneous rocks of Rhum and of the Ben Buie intrusion, Mull, show evidence of post-depositional reaction relationships with the cumulus olivine and/or the intercumulus liquid. Some seam-forming spinels in the Ben Buie intrusion are highly aluminous, more so than those in the Rhum intrusion. Occasional zoned spinels, in both intrusions, show enrichment in Al towards their rims. The evidence suggests that the spinel reaction trend involving Cr-Al exchange proceeds in the direction of Al-enrichment. Equilibrium between chrome-spinel and cumulus olivine appears to have been attained rarely, thus limiting the application of the olivine-spinel geothermometer.     

A pre- and post-MARPOL Annex V summary of Hawaiian monk seal entanglements and marine debris accumulation in the northwestern Hawaiian Islands, 1982-1998

Entanglements of Hawaiian monk seals, Monachus schauinslandi, were documented in the northwestern Hawaiian Islands (NWHI) from 1982 to 1998, and debris which presented a threat of entanglement was inventoried and removed from 1987 to 1996. A total of 173 entanglements was documented. The number of entanglements did not change after implementation of MARPOL Annex V in 1989. Pups and juvenile seals were more likely to become entangled than older seals, and became entangled primarily in nets, whereas entanglement of subadults and adults was more likely to involve line. The subpopulation of seals at Lisianski Island experienced the most entanglements, although Lisianski did not accumulate the most debris. Localized high entanglement rates may gravely affect individual monk seal subpopulations. Accumulation of debris has not diminished since implementation of Annex V, nor has occurrence of derelict drift nets abated since a 1989 moratorium. Debris washing ashore has likely been circulating in the North Pacific Ocean for some time.     

Flow and deposition of pyroclastic granular flows: A type example from the 1975 Ngauruhoe eruption,New Zealand

Small-volume pyroclastic density currents (PDCs) are generated frequently during explosive eruptions with little warning. Assessing their hazard requires a physical understanding of their transport and sedimentation processes which is best achieved by the testing of experimental and numerical models of geophysical mass flows against natural flows and/or deposits. To this end we report on one of the most detailed sedimentological studies ever carried out on a series of pristine small-volume PDC deposits from the 1975 eruption of Ngauruhoe volcano, whose emplacement were also witnessed during eruption. Using high-resolution GPS surveys, a series of lateral excavations across the deposits, and bulk sedimentological analysis we constrained the geomorphology, internal structure and texture of the deposits with respect to laterally varying modes of deposition.     

波西米亚块体西部长周期电磁研究(英文)

在波西米亚块体西南部做了一条长周期电磁剖面 ,它靠近德国超深钻的位置。用一个二维合成模型对数据做了大体的拟合 ,模型走向东西 ,近地表盖层高度地不均匀畸变。畸变层显示强烈的各向异性 ,优势电导方向为NW -SE至NNW -SSE。讨论了深部区域结构的几个不同的模型 ,其中一个模型可以解释由MT和GDS数据显示的主方向的偏差 ,还讨论了沿特别剖面得到的结果与区域地电结构的关系     

3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.     

The distribution of uranium in some basic igneous cumulates and its petrological significance

The distribution of uranium in the minerals and rocks of the Skaergaard, Rhum and Bushveld layered igneous intrusions has been investigated by the delayed neutron analytical technique. The uranium concentration in the minerals depends, in part, upon the nature of the cumulate from which they were separated. In those minerals from adcumulates, pyroxene contains the most uranium and olivine the least. The uranium content of a basic igneous cumulate is shown to be useful as an indicator of the relative amount of mesostasis in the rock, provided uranium-bearing cumulus minerals such as apatite are absent. The amount of mesostasis sometimes changes rapidly from one layer to another.     

Holocene sedimentation in Lake Winnipeg, Manitoba, Canada: implications of compositional and textural variations

Two seismic facies were recognized in the sedimentary sequence overlying acoustic basement in Lake Winnipeg. The upper facies, which overlies a regional unconformity, is termed the Lake Winnipeg Sequence. Based on the seismostratigraphy, lithostratigraphy, and radiocarbon dates of approximately 4000 and 7000 yr BP from material collected directly over the unconformity in the southern and northern parts of the lake, respectively, this facies has been interpreted as representing Holocene sedimentation. Results of compositional and textural analyses of the Holocene sediment (Winnipeg sediment) from thirteen long (>2 m) cores indicate a transgressional sequence throughout the basin. In the South Basin, the generally fining upward sequence is characterized at the base by silt-sized detrital carbonate minerals, quartz and feldspar which decrease in concentration upward. In this basin, the high carbonate content and V/Al and Zn/Al ratios are indicative of a Paleozoic and Cretaceous provenance for sediment derived from glacial deposits through shoreline erosion and fluvial transport, via the Red River. Sedimentation in the central part of the lake and the North Basin is attributed to shoreline erosion of sand and gravel beaches. Consequently, the texture of these sediments is generally coarser than in the South Basin, and the composition primarily reflects a Paleozoic and Precambrian provenance. The basin-wide decrease in Ca, total carbonate minerals, dolomite and calcite concentrations upward in the cores is reflected by a decrease in the detrital carbonate component in all but the most northern cores. Other basin-wide trends show an upward increase in organic content in all cores. An increase in grain size near the top of most cores suggests a major, basin-wide change in sedimentation within the last, approximately 900 years in the South Basin.