Stable isotope geochemistry and structural elements of the Sabina region (Central Apennines, Italy)

Various tectonic features are present in the Meso-Cenozoic basin units of the Sabina region (Central Apennines, Italy): Mio-Pliocene northeasterly verging thrusts are followed by Plio-Pleistocene, N-S oriented right-lateral strike-slip faults. Stable isotope geochemistry and examination of meso- and microstructures show that strain conditions differed through the course of tectonic history. Carbon and oxygen isotope analyses of the calate-filled extensional fractures, the sigmoidal veins present between stylolitic cleavage surfaces, and fault plane surfaces with differing motion, demonstrate those different geneses.
The "C/'" C of the older calcite-filling fractures (present both in the thrust and the strike-slip systems) suggests a deposition from shallow, fresh water circulation. Furthermore, the calcite fill of en echelon systems, that occur in the southernmost Plio-Pleistocene units, is clearly the result of a more recent, right-lateral strike-slip movement, connected with shallow water circulation within Mesozoic limestones.
The sigmoidal vein fills are derived from solid-state pressure solution processes which were the result of strike-slip movement. The deformation pattern related to the older thrust system is similar, but less intense; this also demonstrates general recrystallization processes in a closed system.
This suggests that the total shortening of the deformed sections is lower than that obtained on the basis of solution on stylolitic planes, because a sigruficant volume of dissolved carbonates remained in the system.
Stable isotope analysis also confirms that the deformational history of strongly cleaved rocks in the Sabina region took place in two phases and that extensional fractures formed before stylolithic planes, as suggested by structural and field observations.     

Simulating methane emission from a Chinese rice field as influenced by fertilizer and water level

Natural and agricultural wetlands are considered to be the major sources of global atmospheric methane (CH₄). A one‐dimensional model was developed to simulate methane emission and used to examine the influence of various physical processes on the rate of methane emission. Three processes involved in the methane emission are implemented in the model: production, reoxidation and transport. Three transport pathways were considered: diffusion across water–air or soil–air interfaces, ebullition and diffusion through plants. These pathways are influenced by soil properties, plant growth, water‐table conditions, temperature and external inputs (e.g. fertilizer). The model was used to examine the seasonal variation of the methane emission at a rice field in Hunan, China, which was observed during a field experiment for consecutive (early and late) rice seasons in 1992. The observed seasonal variations of methane emission, and role of plants in transporting methane to the atmosphere, are captured by the model simulation. Further model applications were conducted to simulate effects of fertilizer and water‐level condition on the methane emission. The results indicate that unfermented organic fertilizer produces a higher methane emission rate than mineral fertilizer. The simulations with treatments of a deep‐water covering and constant moisture reduced the methane emission. The rice field study provides a framework for further development of the model towards simulations based on spatially distributed variables (e.g. water table, soil temperature and vegetation) at a regional scale. Copyright © 2003 John Wiley & Sons, Ltd.     

Tensile stresses around boreholes due to transient fluid flow

We present solutions for the effective stress induced by gas flow through a porous solid into a borehole resulting from sudden pressure reduction. Tensile effective stress that exceeds the strength of the solid will lead to borehole failure. This has applications to the intentional creation of cavities, relevant to the efficient recovery of coalbed methane, and the avoidance of borehole stability problems in conventional gas production.     

Speciation of trace metals in sediments of a tropical estuary

Axial surveys were performed in the two river tributaries of the Cochin estuary, SW India during November 1988. Surficial sediments were subjected to sequential chemical extractions to delineate five metal fractions, namely, exchangeable, carbonate bound, easily reducible, organic/sulfide bound, and residual. The results indicated selective accumulation of Mn and Ni in carbonate bound and organic/sulfide forms, along with marginal amounts of Co in the exchangeable fraction. Large portions of Fe and Cr occurred in the residual fraction, whereas composite fractionation of Zn species was noticed. The exchangeable fractions of Fe and Cr as well as of easily reducible cobalt were below detection limits. The levels of Cr and Zn indicate anthropogenic inputs in this estuary, whereas Co and Ni show regional contamination exceeding natural levels. The analytical speciation procedure helps to deduce the sedimental diagenetic processes in the estuarine environment.     

Late Oligocene-Miocene syn-/-late-orogenic successions in Western and Central Mediterranean Chains from the Betic Cordillera to the Southern Apennines*

The identification of syn- and late-orogenic flysch deposits, extending from the Betic Cordillera to the Southern Apennines, assists in the reconstruction of the tectonic-sedimentary evolution of the perimediterranean chains. A microplate was located between the European and African Plates during the Late Jurassic–Early Cretaceous, bordered northwards by the Piemontese Ocean and southwards by another (North Africa ‘Flysch’ Basin or Maghrebian) Ocean. The Piemontese Ocean and the northern margin of the microplate were structured from the Late Cretaceous to the Eocene to create an Eo-alpine Chain. The southern margin of the microplate was deformed in the Aquitanian, when the internal areas of the Maghrebian Ocean were characterized by syn-orogenic flysch deposits. This episode culminated with metamorphism (25–22 Ma) and nappe emplacement, which destroyed the former palaeogeography and created an orogenic belt (AlKaPeCa). Afterwards, a lower Burdigalian late-orogenic cycle started in the deformed area, which as a result of the opening of the Algero-Provençal Basin, caused the fragmentation of the AlKaPeCa, its thrusting on the ‘Flysch’ Basin and the collision with the North Africa and South Iberia Margins. These latter were folded and thrusted, the ‘Flysch’ Units pushed over the External Domain and also back-thrusted. Langhian late-orogenic deposits suture the new tectonic features. Finally, the whole orogen was thrust onto the foredeep during the Middle–Late Miocene.