A Multi‐Element Ion‐Pair Extraction for Trace Metals Determination in Environmental Samples

A multi‐element ion‐pair extraction method was described for the preconcentration of Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) ions in environmental samples prior to their determinations by flame atomic absorption spectrometry (FAAS). As an ion‐pair ligand 2‐(4‐methoxybenzoyl)‐N′‐benzylidene‐3‐(4‐methoxyphenyl)‐3‐oxo‐N‐phenyl‐propono hydrazide (MBMP) was used. Some analytical parameters such as pH of sample solution, amount of MBMP, shaking time, sample volume, and type of counter ion were investigated to establish optimum experimental conditions. No interferences due to major components and some metal ions of the samples were observed. The detection limits of the proposed method were found in the range of 0.33–0.9 µg L^?1 for the analyte ions. Recoveries were found to be higher than 95% and the relative standard deviation (RSD) was less than 4%. The accuracy of the procedure was estimated by analyzing the two certified reference materials, LGC6019 river water and RTC‐CRM044 soil. The developed method was applied to several matrices such as water, hair, and food samples.     

Hydrodynamics of Canal Istanbul and its impact in the northern Sea of Marmara under extreme conditions

Ocean Dynamics - The Bosphorus, located at the junction of Asia and Europe, controls the transports of water, material, and energy between the Black Sea (BS) and the Mediterranean Sea. The Canal...     

Leaky Aquifer Models to Simulate the Well Flow in Fractured Aquifers with Linear Interporosity Flow

Following Hemker and Maas (1987) the models of two or three leaky aquifers are applied to simulate the flow to vertical wells operating in the fractured or dual porosity aquifers. The software WellTest (WT) (Székely 2015) is used for calculating the drawdown and discharge rate variation. The comparative analysis with the independent analytical solutions by Boulton and Streltsova-Adams (1978), Warren and Root (1963), Kazemi et al. (1969) concluded with acceptable agreement between the WT simulation and the alternate calculation methods. The selected field tests have been conducted in fractured limestone aquifers. The pumping test west of Copenhagen shows an example of fractured aquifer with considerable negative skin effect at the well face. The flowing well Wafra W1 in Kuwait operates in the two-zone aquifer exhibiting sufficient vertical recharge via leakage beyond a circular domain of estimated radius of 2460 m.     

Quality control and homogeneity of Turkish precipitation data

Outlier trimming and homogeneity checking/correction were performed on the monthly precipitation time series of various lengths from 267 stations in Turkey. Outlier values are usually found during dry summer months, and are concentrated mostly over the southern parts of the country, where the dry period is most pronounced, implying natural extremes rather than wrong measurements. Homogeneity analysis was done using the Standard Normal Homogeneity Test, on an individual monthly basis, which led to many non‐testable series due to lack of reference stations, especially during summer months. Yet, remaining testable months were usually helpful for the assessment of homogenity, revealing a well distributed set of stations that proved to be homogeneous. There were still a number of stations which either could not be tested efficiently, or were classified as inhomogeneous. Lack of metadata is argued to be largely responsible for inefficient homogeneity testing. Copyright © 2008 John Wiley & Sons, Ltd.     

Determining the weights of two types of artificial reefs required to resist wave action in different water depths and bottom slopes

The interaction between waves and artificial reefs (ARs; a hollow cube weighing 8.24 kN (0.84 t) and a water pipe weighing 1.27 kN (0.13 t)) in shallow waters was investigated with respect to variations in design weight, orientation (for cube; 45° and 90° angles, for pipe; 0°, 90°, and 180° angles to flow), depth (1–20 m), and bottom slope (10^?1, 30^?1, and 50^?1). Physics equations and FLUENT software were used to estimate resisting and mobilising forces, and drag coefficients. Drag coefficients for the hollow cube were 0.76 and 0.85 at 45° and 90° angles to the current, respectively, and 0.97, 0.38, and 1.42 for the water pipe at 0°, 90°, and 180° angles to the current, respectively. Deepwater offshore wave conditions at six stations were transformed into shallow nearshore waters representative of the artificial reef site. Waters deeper than 12 and 16 m are safe to deploy blocks with angles of 45° and 90°, respectively. However, water pipes constructed at angles of 90° and 180° to the current were estimated as being unstable for 365 out of 720 cases at all stations (only one station was stable for all cases). Water pipes angled at 0° were found to be stable in all 360 cases. Slope had a significant effect on weight and depth. Results from this study provide an important reference for engineers performing projects aiming to increase the performance and service life of ARs.     

Infinitesimal orbits around lagrange points in the elliptic,restricted three-body problem

This study presents a method of obtaining asymptotic approximations for motions near a Lagrange point in the planar, elliptic, restricted three-body problem by using a von Zeipel-type method. The calculations are carried out for a second-order escape solution in the proximity of the equilateral Lagrange point, L ₄, where the primaries' orbital eccentricity is taken as the small parameter .     

Aquifer heterogeneity determination through the slope method

In arid‐region wadis, groundwater storage lies within shallow Quaternary alluvium deposits, which are connected with the present‐day hydrological cycle and, therefore, are replenished due to occasional runoff and flash flood occurrences. The groundwater resources are precious in these environments; therefore, their potentiality must be assessed with care in the best manner. The aquifer potentiality is calculated after the storativity and transmissivity parameter estimations, which require rather long‐duration field tests with restrictive assumptions in the theoretical model developments, such as the homogeneity and isotropy. It is the main purpose of this paper to expose the fundamentals of the slope‐matching procedure (SMP) and its application for short‐duration field tests in arid‐region aquifers. In this manner, the subsurface hydrogeological behaviours of the bored land pieces at and around the well locations are prospected in a detailed and refined manner. It is shown that in many cases the classical techniques are appropriate, inconvenient and inapplicable with conclusive reliable results and conclusions. The application of the SMP is presented for some aquifer tests from the central western part of the Kingdom of Saudi Arabia. Copyright © 2007 John Wiley & Sons, Ltd.     

A new spatial prediction model and its application to wind records

Summary Contour maps of any meteorological variable cannot give radius or area of influences around the measurement station by considering the records at surrounding sites. The main purpose of this paper is to propose a trigonometric point cumulative semivariogram (TPCSV) concept for deciding on a spatial dependence function and then its use for regional prediction. The TPCSV provides a unique opportunity for the establishment of a regional objective prediction method whereby the radius of influence helps to predict wind velocity at any site by using the weighted averages. The spatial correlations and weightings are obtained through the TPCSV provided that the distance between two sites is known. If the slope of TPCSV is greater than 80° after some distance, then beyond this distance the regional correlation is considered as negligible. The implementation of the proposed methodology is presented for 68 wind velocity measurement stations in Turkey. The proposed method yields the least prediction error compared with other objective methodologies. It is seen that areas of influence at Central Anatolia are generally bigger than coastal areas of Turkey.