Variations of vertical velocity in the deep oceans simulated by a 1/10° OGCM

This paper analyzes variations of vertical velocity w simulated by the 1/10° Ocean General Circulation Model for the Earth Simulator (OFES). Strong w-variability is found in the deep oceans. When w is WKBJ-normalized, the standard deviation averaged over the Southern Ocean increases with depth and is larger than 8 × 10^− 3 cm/s throughout the water column below 1,500 m. Evidences are presented that link this w-variability to internal waves generated by quasi-steady currents over topography. The aliasing errors in lag-3-day correlations suggest a bottom generation of near-inertial waves. A scale analysis indicates that vertically propagating waves that can be resolved by the OFES model are waves with frequencies of the order of inertial frequency and wavelengths comparable to the order of the grid size. The vertical energy flux associated with these waves is substantial. When integrated globally, the vertical energy flux is upward in the upper 4 km and reaches maximum values of about 0.8 TW at about 1 to 2 km depth. Thus, the w-variability in the 1/10° OFES integration points not only to a strong bottom generation of near-inertial internal waves in the deep Southern Ocean but also to the possibility that the power provided by internal waves generated by non-tidal currents over topography can be comparable to the power provided by internal waves generated by tidal flows over topography.     

Assessment of three temperature reconstruction methods in the virtual reality of a climate simulation

The performance of statistical climate reconstruction methods in the pre-instrumental period is uncertain, as they are calibrated in a short instrumental period but applied to much longer reconstructions time spans. Here, the virtual reality created by a climate simulation of the past millennium with the model ECHO-G is used as a test bed of three methods to reconstruct the annual Northern Hemisphere temperature. The methods are Composite plus Scaling, the inverse regression method of Mann et al. (Nature 392:779–787, 1998) and a direct principal-components regression method. The testing methodology is based on the construction of pseudo-proxies derived from the climate model output, the application of each of these methods to pseudo-proxy timeseries, and the comparison of their result with the simulated mean temperature. Different structures of the noise have been used to construct pseudo-proxies, ranging from the simulated grid-point precipitation. Also, one sparse and one denser pseudo-proxy network, co-located with two real networks, have been considered. All three methods underestimate the simulated variations of the Northern Hemisphere temperature, but the Composite plus Scaling method clearly displays a better performance and is robust against the different noise models and network size. The most relevant factor determining the skill of the reconstruction appears to be the network size, whereas the different noise models tend to yield similar results.     

Induced seismicity during the construction of the Gotthard Base Tunnel, Switzerland: hypocenter locations and source dimensions

A series of 112 earthquakes was recorded between October 2005 and August 2007 during the excavation of the MFS Faido, the southernmost access point of the new Gotthard Base Tunnel. Earthquakes were recorded at a dense network of 11 stations, including 2 stations in the tunnel. Local magnitudes computed from Wood?CAnderson-filtered horizontal component seismograms ranged from ?1.0 to 2.4; the largest earthquake was strongly felt at the surface and caused considerable damage in the tunnel. Hypocenter locations obtained routinely using a regional 3-D P-wave velocity model and a constant Vp/Vs ratio 1.71 were about 2?km below the tunnel. The use of seismic velocities calibrated from a shot in the tunnel revealed that routinely obtained hypocenter locations were systematically biased to greater depth and are now relocated to be on the tunnel level. Relocation of the shot using these calibrated velocities yields a location accuracy of 25?m in longitude, 70?m in latitude, and 250?m in focal depth. Double-difference relative relocations of two clusters with highly similar waveforms showed a NW?CSE striking trend that is consistent with the strike of mapped faults in the MFS Faido. Source dimensions computed using the quasidynamic model of Madariaga (Bull Seismo Soc Am 66(3):639?C666, 1976) range from 50 to 170?m. Overlapping source dimensions for earthquakes within the two main clusters suggests that the same fault patch was ruptured repeatedly. The observed seismicity was likely caused by stress redistribution due to the excavation work in the MFS Faido.     

Varved sediments of Lake Yoa (Ounianga Kebir,Chad) reveal progressive drying of the Sahara during the last 6100 years

The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators.     

Sabkha and playa environments in late Proterozoic grabens,Willouran Ranges,South Australia

We have reconstructed the depositional environment of sulphate‐dolomite‐sand‐mud sequences of the Callanna Beds of the late Proterozoic Adelaidean System in three areas of the Willouran Ranges, South Australia. We interpret the Callanna Beds which represent the earliest Adelaidean sediments as having been deposited in a series of discrete shallow cratonic basins. The sequences in all three areas consist of cyclic hypersaline sand‐shale‐carbonate sheets and wedges. Hypersalinity has been inferred from a study of evaporites and their pseudomorphs, which imply basin evolution in sabkha and playa palaeoenvironments. We interpret the Callanna Beds in the Willouran Ranges to have been formed in playa lake or prograding sabkha complexes, that formed in a series of yoked half‐grabens within the tectonic setting of the Adelaide palaeorift.     

Spatial variability of N2O concentrations and of denitrification-related factors in the surficial groundwater of a catchment in Northern Germany

N₂O concentrations and denitrification-related factors (NO₃, SO₄, dissolved organic carbon (DOC) and CO₂) were investigated in the surface groundwater of a catchment in northern Germany, the Fuhrberger Feld Aquifer (FFA). We sampled 79 plots that were selected according to the three criteria of land use, historical land use conversion (1954–1995) and groundwater level. We sampled three sites within each plot. The sampling depth was 0.5 m below the groundwater surface.We found no indication for the occurrence of autotrophic denitrification in the surface groundwater. Heterotrophic denitrification was identified as the main process for N₂O accumulation. The variability of N₂O concentrations on the plot-scale was extremely high and was poorly explained by the three sampling criteria. Other denitrification-related variables such as NO₃, SO₄ and DOC were less variable. The selection criteria land use and groundwater level clearly influenced the order of magnitude of N₂O concentrations in the surface groundwater. Under arable land, high NO₃ concentrations resulted in high N₂O concentrations. The surface groundwater under forest and pasture was almost NO₃-free and had also very small N₂O concentrations. Plots where the distance from the soil surface to the groundwater surface was large (>1 m up to 3.4 m) showed higher N₂O concentrations in the surface groundwater than plots where the distance was small (<1 m). A larger distance from the soil surface to the groundwater leads to a longer residence time and more decomposition of DOC in the soil. Consequently the less bioavailable DOC could inhibit the efficiency of the heterotrophic denitrification in the groundwater, yielding more N₂O. Elevated organic carbon levels in plots with historic land use conversion (pasture to arable) were very stable and did not influence N₂O concentrations. The high within plot variability showed that an upscaling of N₂O from the plot-scale to the catchment-scale is possible as long as the groundwater level regime and the land use do not change.     

The seasonal cycle in coupled ocean-atmosphere general circulation models

We examine the seasonal cycle of near-surface air temperature simulated by 17 coupled ocean-atmosphere general circulation models participating in the Coupled Model Intercomparison Project (CMIP). Nine of the models use ad hoc “flux adjustment” at the ocean surface to bring model simulations close to observations of the present-day climate. We group flux-adjusted and non-flux-adjusted models separately and examine the behavior of each class. When averaged over all of the flux-adjusted model simulations, near-surface air temperature falls within 2?K of observed values over the oceans. The corresponding average over non-flux-adjusted models shows errors up to ～6?K in extensive ocean areas. Flux adjustments are not directly applied over land, and near-surface land temperature errors are substantial in the average over flux-adjusted models, which systematically underestimates (by ～5?K) temperature in areas of elevated terrain. The corresponding average over non-flux-adjusted models forms a similar error pattern (with somewhat increased amplitude) over land. We use the temperature difference between July and January to measure seasonal cycle amplitude. Zonal means of this quantity from the individual flux-adjusted models form a fairly tight cluster (all within ～30% of the mean) centered on the observed values. The non-flux-adjusted models perform nearly as well at most latitudes. In Southern Ocean mid-latitudes, however, the non-flux-adjusted models overestimate the magnitude of January-minus-July temperature differences by ～5?K due to an overestimate of summer (January) near-surface temperature. This error is common to five of the eight non-flux-adjusted models. Also, over Northern Hemisphere mid-latitude land areas, zonal mean differences between July and January temperatures simulated by the non-flux-adjusted models show a greater spread (positive and negative) about observed values than results from the flux-adjusted models. Elsewhere, differences between the two classes of models are less obvious. At no latitude is the zonal mean difference between averages over the two classes of models greater than the standard deviation over models. The ability of coupled GCMs to simulate a reasonable seasonal cycle is a necessary condition for confidence in their prediction of long-term climatic changes (such as global warming), but it is not a sufficient condition unless the seasonal cycle and long-term changes involve similar climatic processes. To test this possible connection, we compare seasonal cycle amplitude with equilibrium warming under doubled atmospheric carbon dioxide for the models in our data base. A small but positive correlation exists between these two quantities. This result is predicted by a simple conceptual model of the climate system, and it is consistent with other modeling experience, which indicates that the seasonal cycle depends only weakly on climate sensitivity.     

Humic acids: Their detergent qualities and potential uses in pollution remediation

Humic acids are amphiphilic species whose behavior in aqueous solution suggests that they form pseudomicelles–aggregates akin to the micelles familiar from synthetic surfactant chemistry. It is thought that humic pseudomicelles can be formed by both intramolecular coiling and intermolecular association, depending on the molecular weight, structural characteristics, and polydispersity of the humic acid in question. The process does not feature a critical micelle concentration. Experimental evidence indicates that metal ions enhance the detergent character of dissolved humic acid by facilitating the coiling and folding of the polymer chains. A recently conceived alternative model suggests that humic acids consist of relatively small subunits that associate through weak molecular interactions. This view appears to run counter to certain experimental observations, but deserves careful attention. The strong association between metal ions and solid humic acid makes it possible to use an inexpensive commercial grade for the decontamination of polluted water. A continuous elution process through a column packed with humic acid allows for the removal of both heavy metals and organic xenobiotics from aqueous solution.     

Radial transpression ridges: A new structural feature of complex impact craters

Abstract— The gravity‐driven collapse of complex impact craters induces the mass transfer of large rock volumes. In distal parts of a crater, inward movements dominate; whereas in the centre of an impact structure, outward movements occur if the central uplift collapses. The particle trajectory field is centro‐symmetric, which signifies that the conditions for plane‐strain deformation are not fullfilled. Converging particle trajectories can be compensated either by a bulk thickening of inward sliding masses (folding, repetition of rock units along thrust faults, plastic flow) or by the formation of localised radial transpression ridges (RTR) at the edges of individual landslides. In these transpression ridges, material is uplifted to accommodate the converging mass flow. Different modes of uplift are possible including radial folding, lateral overthrusting, and the formation of positive flower structures. A simple geometric model is used to estimate the amount of transpression thickening and bulk thickening of inward sliding masses on the base of volumetric considerations. The existence of RTRs is confirmed by structural investigations at the Siljan impact structure, Sweden, as well as at other complex impact craters on Earth.