Spurenelemente in der Aare (Schweiz)

Instrumental neutron activation analysis was used for the determination of more than 20 trace and minor elements in water and silt samples (suspended load) of the river Aare. The samples were collected at four different locations along the river between its source and the lake of Bienne. The principal results are: 1. The concentrations of all elements investigated are much lower than WHO-limits for drinking water. 2. Human activities are responsible for an increase of some elements along the river. 3. The concentrations of dissolved trace elements are generally anticorrelated with the water flow rate. 4. The concentrations of the trace elements in particulates (in μg/l) are correlated with the flow rate of water. Except for Ca?Sr there are no significant interelement correlations for all four sampling stations.     

Die Geowissenschaft und ihre Bedeutung für die Zukunft der Zivilisation

Geoscience forms — besides Physics, Astronomy, Chemistry, and Biology — a specific domain of Science, characterized by its subjects and objects. Geoscience embraces all disciplines which are inquiring into the present configuration of the earth and its spheres, which intend to explain by natural laws the evolution of the earth and the life and which try to predict future developments. Solid bodies of the planetary system are subjects of geoscience insofar geoscientific methods can be applied. Geoscientists have profoundly contributed to the growth of the technological civilisation by discovering and exploiting sources for the supply of energy and raw materials. During the last decades the annual production of most of these materials has grown exponentially. This is shown, exemplarily, for iron, copper and mercury. Considering the exponential growth of the world population, the future life of mankind on earth is at stake because conventional resources, necessary for the maintenance of agriculture and technology, are running short and physical conditions essential for life are, because of geological reasons, finite and deteriorated by human activities. It is only by changing moral, political, economic and technical foundations of culture and civilisation that mankind can avoid extinction which was the ultimate fate of all species in the geological past. In the attempts to overcome the impending difficulties Geoscience has to play an important role of great responsibility: Only Geoscience can provide and develop by further research methods and knowledge which are necessary in order to evaluate the finite potentials available in the earth and the geological processes which both form the framework to which the future life of mankind has to be adjusted.     

The erosion history of the Central Alps: evidence from zircon fission track data of the foreland basin sediments

Fission track dating on detrital zircons of Alpine debris in the Swiss molasse basin provides information about the erosion history of the Central Alps and the thermal evolution of source terrains. During Oligocene times, only sedimentary cover nappes, and Austroalpine basement units were eroded. Incision into Austroalpine basement units is indicated by increasing importance of Cretaceous cooling ages in granite pebbles upsection. Erosion of Penninic basement units started between 25 and 20 Ma. Early Oligocene zircon FT ages show that Penninic basement units were exposed at ∼20 Ma. Deeper Penninic units of the Lepontine Dome became exposed first at ∼14 Ma, contemporaneously with the opening of the Tauern window in the Eastern Alps. A middle Miocene cooling rate of 40 °C Myr⁻¹ is deduced for the Lower Penninic units of the Lepontine Dome.     

Sensitivity of transient climate change to tidal mixing: Southern Ocean heat uptake in climate change experiments performed with ECHAM5/MPIOM

We investigate the sensitivity of the transient climate change to a tidal mixing scheme. The scheme parameterizes diapycnal diffusivity depending on the location of energy dissipation over rough topography, whereas the standard configuration uses horizontally constant diffusivity. We perform ensemble climate change experiments with two setups of MPIOM/ECHAM5, one setup with the tidal mixing scheme and the second setup with the standard configuration. Analysis of the responses of the transient climate change to CO₂ increase reveals that the implementation of tidal mixing leads to a significant reduction of the transient surface warming by 9 %. The weaker surface warming in the tidal run is localized particularly over the Weddell Sea, likely caused by a stronger ocean heat uptake in the Southern Ocean. The analysis of the ocean heat budget reveals that the ocean heat uptake in both experiments is caused by changes in convection and advection. In the upper ocean, heat uptake is caused by reduced convection and enhancement of the Deacon Cell, which appears also in isopycnal coordinates. In the deeper ocean, heat uptake is caused by reduction of convective cooling associated with the circulation polewards of 65°S. Tidal mixing leads to stronger heat uptake in the Southern Ocean by causing stronger changes in advection, namely a stronger increase in the Deacon Cell and a stronger reduction in advective cooling by the circulation polewards of 65°S. Counter-intuitively, the relation between tidal mixing and greater heat storage in the deep ocean is an indirect one, through the influence of tidal mixing on the circulation.     

Anthropogenic influence of trace metals in sediments of the Al-Qilt catchment,West Bank,Palestine: 1. Contamination factor and bonding forms

Al-Qilt catchment, located east of both the Ramallah and Jerusalem districts is strongly influenced by waste waters discharged from Israeli settlements and Palestinian urban centers. In this research, our aim was to verify the chemical status of the surface sediments from the Al-Qilt catchment during 2008/2009. For this purpose, 36 surface sediment samples were collected and analyzed with ICP/MS within the fraction of below 63 μm. The extent of contamination of trace metals from Al-Qilt sediments sites were measured by evaluating the contamination factors (CF) from digestion by aqua regia and additionally by sequential extraction steps using the BCR-method. On the basis of the calculated CF, sediments appear particularly contaminated with Zn, Cu, Ag, Sn, Cd, Hg, Bi, and B. Three regions, Wadi Sweanit, Ras Al-Qilt, and Qalandiah have been identified as critical points of contamination. Trace metal inputs to the Al-Qilt catchment need to be kept under strict control in the future since Ras Al-Qilt is considered as one of the important springs in the area and is used for domestic purposes. Moreover, it will be susceptible to pollution if no action is taken to decrease the pollution at the upstream of Al-Qilt.     

Boundary layer ion composition at Jupiter during the inbound pass of the Ulysses flyby

During the inbound segment of the Ulysses flyby of Jupiter, there were multiple incursions into the dawnside low-latitude boundary layer, as identified by Bame et al. (Science257, 1539–1542, 1992) using plasma electron data. In the present study, ion composition and spectral measurements provide independent collaborative evidence for the existence of distinct boundary layer regions. Measurements are taken in the energy-per-charge range of 0.6–60 keV/e and involve mass as well as mass-per-charge identification by the Ulysses/SWICS experiment. Ion species of Jovian magnetospheric origin (including O⁺, O²⁺, S²⁺, S³⁺) and sheath origin (including He²⁺ and high charge state CNO) have been directly identified for the first time in the Jovian magnetospheric boundary layer. Protons of probably mixed origin and He⁺ of possibly sheath (ultimately interstellar pickup) origin were also observed in the boundary layer. Sheath-like ions are observed throughout the boundary layer; however, the Jovian ions are depleted or absent for portions of two boundary layer cases studied. Ions of solar wind origin are observed within the outer magnetosphere. and ions of magnetospheric origin are found within the sheath, indicating that transport across the magnetopause boundary can work both ways, at least under some conditions. Although their source cannot be uniquely identified, the proton energy spectrum in the boundary layer suggests a sheath origin for the lower energy protons.