http://www.sciencedirect.com/science/article/pii/S1674987114000310

This paper presents a compilation of recent U-Pb(zircon) ages of late Carboniferous—early Permian(LCEP) calc-alkaline batholiths from Iberia,together with a petrogenetic interpretation of magma generation based on comparisons with Mesozoic and Tertiary Cordilleran batholiths and experimental melts.Zircon U-Pb ages distributed over the range ca.315—280 Ma,indicate a linkage between calc-alkaline magmatism,Iberian orocline generation and Paleotethys subduction.It is also shown that Iberian LC-EP calcalkaline batholiths present unequivocal subduction-related features comparable with typical Cordilleran batholiths of the Pacific Americas active margin,although geochemical features were partially obscured by local modifications of magmas at the level of emplacement by country rock assimilation.When and how LC-EP calc-alkaline batholiths formed in Iberia is then discussed,and a new and somewhat controversial interpretation for their sources and tectonic setting(plume-assisted relamination) is suggested.The batholiths are proposed to have formed during the subduction of the Paleotethys oceanic plate(Pangaea self-subduction) and,consequently,they are unrelated to Variscan collision.The origin of the Iberian batholiths is related to the Eurasian active margin and probably represents the inception of a Paleotethyan arc in the core of Pangaea.     

Geochemical constraints on the stability of zeolites and C-S-H in the high pH reaction of bentonite

Cement-bentonite interactions will occur in deep geological repositories for high level radioactive waste. We performed laboratory experiments in order to constrain some previous geochemical and mineralogical uncertainties in the formation of secondary minerals in the high pH reaction of FEBEX bentonite at moderate temperatures.The reactivity of a Mg-homoionic FEBEX bentonite was studied at 25, 60 and 90 °C in batch reactors using two solutions representative of short and long time evolution stages of cement degradation. These solutions were periodically renewed in order to maintain a constant pH regime for a period of almost 2 years.Chabazite and merlinoite were observed to be the main zeolites that formed at 60 °C, while merlinoite was the dominant zeolite formed at 90 °C with the hyperalkaline (K-Na-OH) solution. The alkaline experiments (Ca-OH solution) showed minor reactivity and negligible mineralogical alteration, but the overall results suggest that the reaction tends to equilibrium conditions between C-S-H and montmorillonite at high temperature and metastable conditions at low temperature. The montmorillonite dissolution rates were calculated for all experiments, showing good agreement with previous calculations.     

Silver-Bearing and Associated Minerals in El Zancudo Deposit, Antioquia, Colombia

The occurrence and the chemical compositions of ore minerals (especially the silver‐bearing minerals) and fluid inclusions of the El Zancudo mine in Colombia were investigated in order to analyze the genetic processes of the ore minerals and to examine the genesis of the deposit. The El Zancudo mine is a silver–gold deposit located in the western flank of the Central Cordillera in Antioquia Department. It consists mainly of banded ore veins hosted in greenschist and lesser disseminated ore in porphyritic rocks. The ore deposit is associated with extensive hydrothermally altered zones. The ores from the banded veins contain sphalerite, pyrite, arsenopyrite, galena, Ag‐bearing sulfosalts, Pb‐Sb sulfosalts, and minor chalcopyrite, electrum, and native silver. Electrum is included within sphalerite, pyrite, and arsenopyrite, and is also partially surrounded by pyrite, arsenopyrite, sphalerite, and tetrahedrite. Native silver is present in minor amounts as small grains in contact with Ag‐rich sulfosalts. Silver‐bearing sulfosalts are argentian tetrahedrite–freibergite solid solution, andorite, miargyrite, diaphorite, and owyheeite. Pb‐Sb sulfosalts are bournonite, jamesonite, and boulangerite. Two main crystallization stages are recognized, based on textural relations and mineral assemblages. The first‐stage assemblage includes sphalerite, pyrite, arsenopyrite, galena and electrum. The second stage is divided into two sub‐stages. The first sub‐stage commenced with the deposition and growth of sphalerite, pyrite, and arsenopyrite. These minerals are characterized by compositional growth banding, and seem to have crystallized continuously until the end of the second sub‐stage. Tetrahedrite, Pb‐Cu sulfosalts, Ag‐Sb sulfosalt, and Pb‐Ag‐Sb sulfosalts crystallized from the final part of the first sub‐stage and during the whole second sub‐stage. However, one Pb‐Ag‐Sb sulfosalt, diaphorite, was formed by a retrograde reaction between galena and miargyrite. The minimum and maximum genetic temperatures estimated from the FeS content of sphalerite coexisting with pyrite and the silver content of electrum are 300°C and 420°C, respectively. These estimated genetic temperatures are similar to, but slightly higher than the homogenization temperatures (235–350°C) of primary fluid inclusions in quartz. The presence of muscovite in the altered host rocks and gangue suggest that the pH of the hydrothermal solutions was close to neutral. Most of the sulfosalts in this deposit have previously been attributed as the products of epithermal mineralization. However, El Zancudo can be classified as a xenothermal deposit, in view of the low pressure and high temperature genetic conditions identified in the present study, based on the mineralogy of sulfosalts and the homogenization temperatures of the fluid inclusions.     

Consequences of inter-specific competition among multiple adaptive species in Daisyworld

Summary We investigate the consequences of Darwinian selection in a daisymodel with uniform temperature, inter-specific competition and multiple daisies. The assumption of a higher competition between species than within them allows for the coexistence of more than two species in equilibrium. Thus, it is the first time that a high biodiversity with equal environment-altering traits at the same trophic level in a daisymodel is reported under stationary conditions. Adaptation in the biota occurs through mutations, leading to changes in the optimum temperature in order to achieve the maximum growth rate at the individual level. We study the planetary sensitivity (i.e. the variation of the global mean temperature due to a 1% change in solar radiation) as a function of the strength of the inter-specific competition and of the number of different species that grow in the model. We find the following: 1) by fixing the parameter that defines the strength of the inter-specific competition, the planetary sensitivity increases as biodiversity increases; 2) by keeping constant the number of different species in the planet, the planetary sensitivity also increases as competition between species increases. In any case, however, the planetary sensitivity associated with adaptive daisies is much greater than that obtained from non-adaptive species. However, the range of mean solar radiation where biota grows in the planet is substantially larger for adaptive species than for non-adaptive ones. This result suggests that adaptation of multiple species with the same environmental-altering traits may not imply a strong regulation of the mean planetary temperature, which differs with recent studies that analyse adaptation of single species. Similar results are obtained by using a constrained adaptation and non-uniform temperatures.     

Reconstruction of the environmental history of a coastal insular system using shallow marine records: the last three millennia of the Cíes Islands (Ría de Vigo,NW Iberia)

The coastal lagoon‐beach complex at the Cíes Islands located at the opening of the Ría de Vigo (NW Iberia) is an important ecosystem currently threatened by anthropogenic impacts and climate variations. We used multiproxy marine sediment analyses to reconstruct the millennial environmental dynamics of this insular system and, in particular, the recent history of its coastal lagoon. Geophysical surveys were used to obtain bathymetry and identify the major sedimentary units of its closest submarine basin as well as their sediment sources. Core samples were taken in the middle and distal parts of the sedimentary body, where several prograding sedimentary units are thinner, allowing continuous sampling of the facies. Lithological, textural, elemental and chronological analyses were carried out on two cores. The detailed palynological studies on one of the cores included the analyses of the pollen, non‐pollen palynomorphs and dinocysts dating back three millennia. Our results revealed noticeable environmental changes affecting this area during the last 3000 years, due mainly to changing climate and oceanic conditions but also to the impact of historic human occupation of the islands. Several cold events (the 2.8 ka BP event and the Little Ice Age) characterized by enhanced upwelling alternated with warmer stormy periods of prevailing downwelling conditions in the ria. These circumstances altered the balance amongst the lacustrine, marsh, dune and lagoon systems, opening ephemeral inlets and modifying the trophic stage of the shallow waters surrounding the archipelago. Here we provide a background of the human and climatic impacts affecting these highly sensitive habitats, which may serve to improve their future management strategies.     

A Comparative Analysis of Photospheric Bright Points in an Active Region and in the Quiet Sun

We present a comparative study of photometric and dynamic properties of photospheric bright points (BPs) observed at the disk centre in the active region (AR) NOAA 10912 and in the quiet Sun. We found that the average concentration of BPs is 54% larger in the AR than in the quiet Sun. We also measure a decrease of the BP concentration and an increase of their size moving away from the AR centre. However, these variations can be ascribed to the variation of the spatial resolution and image quality in the field of view of the AR dataset. We also found that BPs in the quiet Sun are associated with larger downflow motions than those measured within the AR. Finally, from our measurements of contrast and velocity along the line of sight, we deduced that BPs are less bright in high magnetic flux density regions than in quiet regions, due to a lower efficiency of convection in the former regions.     

Kinetics of biodegradation of diesel fuel by enriched microbial consortia from polluted soils

Three microbial consortia were isolated from three polluted soils located at an oil refinery and acclimated to grow on diesel fuel as the sole carbon source. Batch experiments were then conducted with the three consortia to study the kinetics of diesel biodegradation. The effects of temperature (25, 30 and 35?°C) and diesel concentration (0.5, 1 and 3?%) on the biodegradation of diesel were analysed. Several species were identified in the acclimated microbial consortia, and some of them appeared in more than one consortium. Thermal inhibition was observed at 35?°C. In the rest of experiments, over 80?% of the substrate was degraded after 40?h of treatment. These results proved the good feasibility of using the polluted sites as sources of mixed consortia for hydrocarbon degradation. However, diesel degradation efficiencies and rates were very similar, suggesting that the acclimation process produced mixed consortia with very similar characteristics; in this context, origin of the soil sample was not a decisive factor. A simple Monod-type kinetic model was used to simulate the biodegradation process, and accurate results were obtained. The ?? _max values were between 0.17 and 0.34?h^?1. The results of this study revealed that the consortia can function at high concentrations of hydrocarbons without any sign of growth inhibition, which is important for the design of bioreactors for wastewater treatment with high concentrations of fuel.     

Pattern Recognition in a Bimodal Aquifer Using the Normal-Score Ensemble Kalman Filter

The ensemble Kalman filter (EnKF) is now widely used in diverse disciplines to estimate model parameters and update model states by integrating observed data. The EnKF is known to perform optimally only for multi-Gaussian distributed states and parameters. A new approach, the normal-score EnKF (NS-EnKF), has been recently proposed to handle complex aquifers with non-Gaussian distributed parameters. In this work, we aim at investigating the capacity of the NS-EnKF to identify patterns in the spatial distribution of the model parameters (hydraulic conductivities) by assimilating dynamic observations in the absence of direct measurements of the parameters themselves. In some situations, hydraulic conductivity measurements (hard data) may not be available, which requires the estimation of conductivities from indirect observations, such as piezometric heads. We show how the NS-EnKF is capable of retrieving the bimodal nature of a synthetic aquifer solely from piezometric head data. By comparison with a more standard implementation of the EnKF, the NS-EnKF gives better results with regard to histogram preservation, uncertainty assessment, and transport predictions.     

Habitat Affects Survival of Translocated Bay Scallops, Argopecten irradians concentricus (Say 1822), in Lower Chesapeake Bay

Bay scallop (Argopecten irradians) populations existed in Chesapeake Bay until 1933, when they declined dramatically due to a loss of seagrass habitat. Since then, there have been no documented populations within the Bay. However, some anecdotal observations of live bay scallops within the lower Bay suggest that restoration of the bay scallop is feasible. We therefore tested whether translocated adults of the southern bay scallop, Argopecten irradians concentricus, could survive during the reproductive season in vegetated and unvegetated habitats of the Lynnhaven River sub-estuary of lower Chesapeake Bay in the absence of predation. Manipulative field experiments evaluated survival of translocated, caged adult scallops in eelgrass Zostera marina, macroalgae Gracilaria spp., oyster shell, and rubble plots at three locations. After a 3-week experimental period, scallop survival was high in vegetated habitats, ranging from 98% in their preferred habitat, Z. marina, to 90% in Gracilaria spp. Survival in Z. marina was significantly higher than that in rubble (76%) and oyster shell (78%). These findings indicate that reproductive individuals can survive in vegetated habitats of lower Chesapeake Bay when protected from predators and that establishment of bay scallop populations within Chesapeake Bay may be viable.