Insights in the exhumation history of the NW Zagros from bedrock and detrital apatite fission‐track analysis: evidence for a long‐lived orogeny

We present the first fission‐track (FT) thermochronology results for the NW Zagros Belt (SW Iran) in order to identify denudation episodes that occurred during the protracted Zagros orogeny. Samples were collected from the two main detrital successions of the NW Zagros foreland basin: the Palaeocene–early Eocene Amiran–Kashkan succession and the Miocene Agha Jari and Bakhtyari Formations. In situ bedrock samples were furthermore collected in the Sanandaj‐Sirjan Zone. Only apatite fission‐track (AFT) data have been successfully obtained, including 26 ages and 11 track‐length distributions. Five families of AFT ages have been documented from analyses of in situ bedrock and detrital samples: pre‐middle Jurassic at ～171 and ～225 Ma, early–late Cretaceous at ～91 Ma, Maastrichtian at ～66 Ma, middle–late Eocene at ～38 Ma and Oligocene–early Miocene at ～22 Ma. The most widespread middle–late Eocene cooling phase, around ～38 Ma, is documented by a predominant grain‐age population in Agha Jari sediments and by cooling ages of a granitic boulder sample. AFT ages document at least three cooling/denudation periods linked to major geodynamic events related to the Zagros orogeny, during the late Cretaceous oceanic obduction event, during the middle and late Eocene and during the early Miocene. Both late Cretaceous and early Miocene orogenic processes produced bending of the Arabian plate and concomitant foreland deposition. Between the two major flexural foreland episodes, the middle–late Eocene phase mostly produced a long‐lasting slow‐ or nondepositional episode in the inner part of the foreland basin, whereas deposition and tectonics migrated to the NE along the Sanandaj‐Sirjan domain and its Gaveh Rud fore‐arc basin. As evidenced in this study, the Zagros orogeny was long‐lived and multi‐episodic, implying that the timing of accretion of the different tectonic domains that form the Zagros Mountains requires cautious interpretation.     

ENSO and solar activity signals from oxygen isotopes in diatom silica during late glacial-Holocene transition in Central Andes (18°S)

The late glacial-Holocene transition from the Lago Chungará sedimentary record in northern Chilean Altiplano (18°S) is made up of laminated sediments composed of light-white and dark-green pluriannual couplets of diatomaceous ooze. Light-white sediment laminae accumulated during short-term extraordinary diatom blooms whereas dark-green sediment laminae represent the baseline limnological conditions during several years of deposition. Diatom oxygen isotope ratios (δ¹⁸O_diatom) from 40 consecutive dark-green laminae, ranging from 11,990 to 11,450 cal year BP, show that a series of decadal-to-centennial dry–wet oscillations occurred. Dry periods are marked by relatively high isotope values whereas wet episodes are indicated by lower values. This interpretation agrees with the reconstructions of terrigenous inputs and regional effective moisture availability carried out in the lake but there is a systematic temporal disagreement between them owing to the non-linear response of the lacustrine ecosystem to environmental forcings. Furthermore, the δ¹⁸O_diatom record tracks effective moisture changes at a centennial scale. Three major phases have been established (11,990–11,800, 11,800–11,550, and 11,550–11,450 cal year BP). Each phase is defined by an increasing isotope trend followed by a sudden depletion. In addition, several wet and dry events at a decadal scale are superimposed onto these major trends. Spectral analyses of the δ¹⁸O_diatom values suggest that cycles and events could have been triggered by both El Niño-Southern Oscillation (ENSO) and solar activity. Significant ENSO frequencies of 7–9 years and 15–17 years, and periodicities of the solar activity cycles such as 11 years (Schwabe), 23 years (Hale) and 35 years (Brückner) have been recognised in the oxygen isotope time series. Time–frequency analysis shows that although solar and ENSO forcing were present at the onset of the Holocene, they were more intense during the late glacial period. The early Holocene might have been mainly governed by La Niña-like conditions that correspond to wet conditions over the Andean Altiplano.     

Hydrogeological characterization of carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias,N Spain) by means of geochemical and isotopic techniques

Chemical and isotopic analyses of groundwater from the carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias, northern Spain) were carried out. Nine springs were sampled to determine major cations and anions, as well as the stable isotopes of the water molecule (δ²H and δ¹⁸O) and sulphate (δ³⁴S) values. Also, δ³⁴S values from gypsum coming both from Triassic rocks and bottom of Jurassic sequence were also determined. The results obtained were used to classify the waters with a genetic criteria in three groups: (1) waters with a high gypsum influence, with sulphate coming from Jurassic gypsum, (2) waters without gypsum influence, where sulphate source could be atmospheric deposition from industrial processes and marine aerosol, and (3) waters with some gypsum influence, in which sulphate origin could be a combination of different sources. In relation to recharge, δ²H and δ¹⁸O values were close to those of Global Meteoric Water Line and fit a local line that suggests a meteoric origin. The estimated elevations for spring recharge are in agreement with those obtained from hydrogeological maps.     

A rootless suture and the loss of the roots of a mountain chain: The Variscan belt of NW Iberia

Ophiolites of different Paleozoic ages occur in North-West (NW) Iberia in a rootless suture representing the remnants of the Rheic Ocean. Associated allochthonous terranes in the hanging- and foot-walls of the suture derive from the former margins, whereas the relative autochthon corresponds to the Paleozoic passive margin of northern Gondwana. The Paleozoic tectonic evolution of this part of the circum-Atlantic region is deduced from the stratigraphical, petrological, structural and metamorphic evolution of the different units and their ages. The tectonic reconstruction covers from Cambro-Ordovician continental rifting and the opening of the Rheic Ocean to its Middle to Upper Devonian closure. Then, the Variscan Laurussia–Gondwana convergence and collision is briefly described, from its onset to the late stages of collapse associated with the demise of the orogenic roots.     

Trace Metals (Cd,Cu, Hg,and Pb) Accumulation Recorded in the Intertidal Mudflat Sediments of Three Coastal Lagoons in the Gulf of California,Mexico

²¹⁰Pb geochronologies of Cd, Cu, Hg, and Pb fluxes were obtained from the intertidal mudflat sediments of the coastal lagoons Chiricahueto, Estero de Urías, and Ohuira in the Mexican Pacific. The Cu and Hg sediment concentrations at the three lagoons fell within the ranges of 6–76 μg g⁻¹ and 0.1 to 592 ng g⁻¹, respectively; Chiricahueto and Estero de Urías sediments had comparable Cd and Pb concentrations within the ranges of 0.2–2.1 μg g⁻¹ and 10–67 μg g⁻¹, respectively; whereas in Ohuira lagoon, Cd concentrations were lower (0.1–0.5 μg g⁻¹) and Pb concentrations were higher (115–180 μg g⁻¹) than in the other lagoons. The metal fluxes (μg cm⁻² y⁻¹) for the three lagoons fell within the ranges of 0.02–0.15 for Cd, 0.7–6.0 for Cu, 0.001–0.045 for Hg, and 0.7–20 for Pb. The Hg pollution in Estero de Urías was attributed to the exhausts of the thermoelectric plant of Mazatlan and the metal enrichment in Chiricahueto and Ohuira was related to the agrochemical wastes from the croplands surrounding these lagoons.     

Shallow structure beneath the Central Volcanic Complex of Tenerife from new gravity data: Implications for its evolution and recent reactivation

We present a new local Bouguer anomaly map of the Central Volcanic Complex (CVC) of Tenerife, Spain, constructed from the amalgamation of 323 new high precision gravity measurements with existing gravity data from 361 observations. The new anomaly map images the high-density core of the CVC and the pronounced gravity low centred in the Las Cañadas caldera in greater detail than previously available. Mathematical construction of a sub-surface model from the local anomaly data, employing a 3D inversion based on “growing” the sub-surface density distribution via the aggregation of cells, enables mapping of the shallow structure beneath the complex, giving unprecedented insights into the sub-surface architecture. We find the resultant density distribution in agreement with geological and other geophysical data. The modelled sub-surface structure supports a vertical collapse origin of the caldera, and maps the headwall of the ca. 180 ka Icod landslide, which appears to lie buried beneath the Pico Viejo–Pico Teide stratovolcanic complex. The results allow us to put into context the recorded ground deformation and gravity changes at the CVC during its reactivation in spring 2004 in relation to its dominant structural building blocks. For example, the areas undergoing the most significant changes at depth in recent years are underlain by low-density material and are aligned along long-standing structural entities, which have shaped this volcanic ocean island over the past few million years.     

Changes in the Diffuse CO2 Emission and Relation to Seismic Activity in and around El Hierro, Canary Islands

Significant changes in the diffuse emission of carbon dioxide were recorded in a geochemical station located at El Hierro, Canary Islands, before the occurrence of several seismic events during 2004. Two precursory CO₂ efflux increases started thirteen and nine days before two seismic events of magnitude 2.3 and 1.7, which took place near El Hierro Island, Canary Islands, on March 23 and April 15, reaching a maximun value of 51.1 and 46.2 g m⁻² d⁻¹, respectively, five and eight days before the two seismic events. Other similar increases started thirteen and five days before the occurrence of two seismic events of magnitude 1.3 and 1.5 which took place on October 15 and 21 respectively, reaching the maximum values four and one day before the earthquakes. These changes were not related to variations in atmospheric or soil parameters. The Material Failure Forecast Method (FFM), which analyzes the rate of precursory phenomena, was successfully applied to forecast the first seismic event that took place in El Hierro Island in 2004.     

Spatio-temporal analysis of potential aquifer recharge: Application to the Basin of Mexico

Regional estimates of aquifer recharge are needed in data-scarce regions such as the Basin of Mexico, where nearly 20 million people are located and where the Basin’s aquifer system represents the main water source. In order to develop the spatio-temporal estimates of aquifer recharge and to analyze to what extent urban growth has affected aquifer recharge, this work presents a daily soil water balance which uses different vegetation and soil types as well as the effect of topography on climatological variables and evapotranspiration. The soil water balance was applied on a daily time step in the Basin of Mexico for the period 1975–1986, obtaining an annually-lumped potential recharge flow of 10.9–23.8 m³/s (35.9–78.1 mm) in the entire Basin, while the monthly values for the year with the largest lumped recharge value (1981 = 78.1 mm) range from 1 m³/s (0.3 mm) in December to 87.9 m³/s (23.7 mm) in June. As aquifer recharge in the Basin mainly occurs by subsurface flow from its enclosing mountains as Mountain Block Recharge, urban growth has had a minimal impact on aquifer recharge, although it has diminished recharge in the alluvial plain.