Light curve and O−C diagram analysis of RZ Cassiopeiae

The aim of the present paper is to analyze the light variation as well as the period changes of the eclipsing binary RZ Cas. New photometric elements are computed using the frequency-domain method. The possibility of the light-time effect and the apsidal motion is discussed.     

Pb, Sr and Nd isotope study of two co-existing magmas in the Nízke Tatry Mountains, Western Carpathians (Slovakia)

Summary Two co-existing plutonic rocks (diorite and granodiorite) were studied from an intrusion of Variscan age in the Raztocna Valley – Nízke Tatry Mountains, Western Carpathians. Geochemical analyses of major and trace elements constrain a volcanic arc as emplacement environment and give the first hints of a mixture of two magmatic end-members: the so-called Prasivá granodiorite and the Raztocna diorite. The ⁸⁷Sr/⁸⁶Sr₍₀₎ ratios vary between 0.7075 and 0.7118, the ε Nd₍₀₎ values range from −1.4 to −5.0. Common Pb isotopes reveal a dominant crustal source with minor influences from a mantle and a lower crustal source. Modelling based on Sr and Nd isotope data and using three component mixing calculations indicates that mixing of 2/3 of upper mantle material with 1/3 upper crustal material can produce the isotopic composition of the Raztocna diorite. Very minor amounts of lower crust were incorporated in the diorite. For the Prasivá granodiorite, the mixing ratio of upper mantle and upper crust is similar, but a lower crustal reservoir contributed about 5–10% of the source material.     

Intermediate-age Galactic open clusters: fundamental parameters of NGC 2627

Charge-coupled device (CCD) photometry in the Johnson V , Kron–Cousins I and Washington CMT ₁ systems is presented in the field of the poorly known open cluster NGC 2627. Four independent Washington abundance indices yield a mean cluster metallicity of  [Fe/H]=−0.12 ± 0.08  , which is compatible with the existence of a radial gradient in the Galactic disc. The resultant colour–magnitude diagrams indicate that the cluster is an intermediate-age object of 1.4 Gyr. Based on the best fits of the Geneva group's isochrones to the ( V , V − I ) and  ( T ₁, C − T ₁)  diagrams, we estimate   E ( V − I ) = 0.25 ± 0.05  and   V − M_V = 11.80 ± 0.25  for  log  t = 9.15  , and   E ( C − T ₁) = 0.23 ± 0.07  and   T ₁− M _{T 1}= 11.85 ± 0.25  for  log  t = 9.10  , respectively, assuming solar metal content. The derived reddening value   E ( C − T ₁)  implies   E ( B − V ) = 0.12 ± 0.07  and a distance from the Sun of  2.0 ± 0.4 kpc  . Using the WEBDA data base and the available literature, we re-examined the overall properties of all the open clusters with ages between 0.6 and 2.5 Gyr. We identified peaks of cluster formation at 0.7–0.8, 1.0–1.1, 1.6–1.7 and 2.0–2.1 Gyr, separated by relative quiescent epochs of ∼0.2–0.3 Gyr. We also estimated a radial abundance gradient of  −0.08 ± 0.02  , which is consistent with the most recent determinations for the Galactic disc, but no clear evidence for a gradient perpendicular to the Galactic plane is found.     

Diurnal photometric conditions at Teide observatory and long-term solar irradiance variations

Monochromatic extinction coefficients at four wavelengths have been obtained over a period of more than two years at the Observatorio del Teide (Izaña Tenerife) using a full disc, direct sunlight, quadruple photometer devoted to the detection of integral luminosity oscillations of the Sun. The mean extinction coefficients (0.13 at 500 nm) show a seasonal variation of about 15%, the best atmospheric conditions being in winter and autumn. Moreover, in anyone day the extinction coefficient in the afternoon is always lower than the one in the morning by 7%. A one-year period fluctuation, with an amplitude of 0.035 mag, has been identified in the instrumental magnitudes outside the atmosphere, and is interpreted as the variation produced by the different Sun-Earth distance from winter to summer. Finally, the study made to detect periodic time fluctuations in both, Sun's magnitude and extinction coefficients, has given null results at levels of 0.04 and 1.8%, respectively.     

Mono- and dicyclic unsaturated triterpenoid hydrocarbons in sediments from Lake Masoko (Tanzania) widely extend the botryococcene family

A mixture of C₃₃–C₃₇ botryococcenes and partially reduced derivatives was isolated from ca. 32,000 year old sediment from Lake Masoko, a freshwater crater lake in the Rungwe Range area (Tanzania). Botryococcenes and derivatives accounted for 246 μg/g dry sediment and for >92% of the hydrocarbon fraction; 1D and 2D nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry allowed the structure of the dominant botryococcene (43% of hydrocarbon fraction) to be established, after purification using high performance liquid chromatography (HPLC). The compound is a novel tetraunsaturated dicyclic C₃₄ botryococcene and is named C₃₄ masokocene. Overall, the structures of six other novel botryococcenes and four partially reduced derivatives were tentatively assigned. The structures of the new biomarkers, three dicyclic C₃₄–C₃₆ botryococcenes (or masokocenes) and seven monocyclic C₃₄–C₃₇ analogues are discussed along with their biosynthetic relationship. The high abundance of such polyunsaturated compounds preserved in 32,000 year old sediment from the lake indicates an aquatic ecosystem dominated at the time by the green alga Botryococcus braunii, as well very good preservation of the organic matter.