Crossover of cation partitioning in olivines: a combination of ab initio and Monte Carlo study

We report studies based on a combination of ab initio electronic structure and Monte Carlo (MC) technique on the problem of cation partitioning among inequivalent octahedral sites, M1 and M2 in mixed olivines containing Mg²⁺ and Fe²⁺ ions. Our MC scheme uses interactions derived out of ab initio, density functional calculations carried out on measured crystal structure data. Our results show that there is no reversal of the preference of Fe for M1 over M2 as a function of temperature. Our findings do not agree with the experimental findings of Redfern et al. (Phys Chem Miner 27:630–637, 2000), but are in agreement with those of Heinemann et al. (Eur J Mineral 18:673–689, 2006) and Morozov et al. (Eur J Mineral 17:495–500, 2005).     

Ecological consideration of trace element contamination in sediment cores from Sundarban wetland,India

This article reports on the concentration of selected trace elements (Mn, Zn, Cr, Cu, Ba, As, B, V, and Hg) and major elements (Fe and Al) from the intertidal sediment cores from Sundarban wetland, India. This is a typical meso-macrotidal estuarine area affected by domestic and industrial activities located upstream. The overall concentrations range is low to moderate, indicating the environmental conditions in the outfall zone (grain size, hydrodynamic regime, and confinement), which favors the in situ accumulation of pollutants. The extent of contamination from trace elements in Sundarban core sediments is evaluated through a two-pronged approach: (i) by determining the metal enrichment in the sediments through the calculation of Pollution Load Index (PLI), Enrichment Factor (EF) and Index of Geoaccumulation (I _geo), and (ii) by defining a potential level of biological risk by the use of quality criteria such as Threshold Effect Level (TEL) and Effects Range-Low (ERL) benchmarks. On the basis of the calculated indices, sediments are particularly enriched with Cr, Cu, B, V, and As. Those enrichments seem to be due to the fine granulometry of the regions with Fe and Mn oxi-hydroxides being the main metal carriers. Trace Elements input to the Sundarban wetland need to be kept under strict control in future specially with reference to As since, according to TEL and ERL benchmarks, it already appears to be associated with a potential biological risk.     

Suspended sediment yield modeling in Mahanadi River,India by multi-objective optimization hybridizing artificial intelligence algorithms

River sediment produced through weathering is one of the principal landscape modification processes on earth.Rivers are an integral part of the hydrologic cycle and are the major geologic agents that erode the continents and transport water and sediments to the oceans.Estimation of suspended sediment yield is always a key parameter for planning and management of any river system.It is always challenging to model sediment yield using traditional mathematical models because they are incapable of handling the complex non-linearity and non-stationarity.The suspended sediment modeling of the river depends on the number of factors such as rock type,relief,rainfall,temperature,water discharge and catchment area.In this study,we proposed a hybrid genetic algorithm-based multi-objective optimization with artificial neural network(GA-MOO-ANN)with automated parameter tuning model using these factors to estimate the suspended sediment yield in the entire Mahanadi River basin.The model was validated by comparing statistically with other models,and it appeared that the GA-MOO-ANN model has the lowest root mean squared error(0.009)and highest coefficient of correlation(0.885)values among all comparative models(traditional neural network,multiple linear regression,and sediment rating curve)for all stations.It was also observed that the proposed model is the least biased(0.001)model.Thus,the proposed GA-MOOANN is the most capable model,compared to other studied models,for estimating the suspended sediment yield in the entire Mahanadi river basin,India.The results also suggested that the proposed GA-MOO-ANN model is unable to estimate suspended sediment yield satisfactorily at gauge stations having very small catchment areas whereas performing satisfactorily on locations having moderate to the large catchment area.The models provide the best result at Tikarapara,the gauge station location in the extreme downstream,having the largest catchment area.     

Distribution of polycyclic aromatic hydrocarbons in recent sediments of Sundarban mangrove wetland of India and Bangladesh: a comparative approach

The present work is the first attempt to compare the data of a comprehensive study of the origin and distribution of 16 priority pollutant polycyclic aromatic hydrocarbons (PAHs) in surface sediments (<63 μm) from 18 sampling stations, 9 from Sundarban of Bangladesh and 9 from Indian counterpart. Σ19PAHs concentration in sediments showed wide variations from 208.3 to 12,993.1 ng g^?1 dry weight in Indian Sundarban, whereas 208.4 to 4,687.9 ng g^?1 in the case of Bangladesh. Fluoranthene, pyrene, benzo(b)fluoranthene, benzo(a)pyrene and dibenzo(a,h)anthracene were predominant species for both the countries. The PAH diagnostic ratios indicated that the PAHs in sediments from both the countries were of mixed source of hydrocarbons of both petrogenic and pyrolytic origin. According to the numerical effect-based sediment quality guidelines, the levels of PAHs in the Sundarban wetland of Bangladesh and India should not exert adverse biological effects. The TEQ values calculated for samples from the Bangladesh and Indian Sundarban varied from 13.68 to 1,014.75 and 1.31 to 2,451 ng g^?1 d.w. with an average of 221.02 and 358.63 ng g^?1, respectively. The overall contamination status of PAH was higher in India than Bangladesh.     

Solar cycle dependence of polar coronal holes

A study has been made of the polar coronal holes in relation to solar cycle activity. Important results obtained are: (i) the peak of the frequency distribution of coronal hole size shifts towards lower values as the solar cycle advances towards maximum, this being true for both the north and south polar holes, (ii) coronal hole size decreases with the increase of sunspot number.     

The Relative Lyapunov Indicator: An Efficient Method of Chaos Detection

A recently introduced chaos detection method, the relative Lyapunov indicator (RLI) is investigated in the cases of symplectic mappings and of a continuous Hamiltonian system. It is shown that the RLI is an efficient and easy-to-calculate numerical tool in determining the true nature of individual orbits, and in separating ordered and regular regions of the phase space of dynamical systems. An application of the RLI for stability investigations of some recently discovered exoplanetary systems is also presented.     

The Parameterization of the Ground State and Its Applications to Planetary Systems

Natural systems tend to minimize their energy. Hence an important problem in astrophysics is the parametrization of the ground state. In this context a quantum statistical approach is very useful. The problem of the variational approximation of the density matrix is extended towards a parametrization of the ground state. With an analogy to the semiclassical approach, a classical approach to the variational principle in the parametrization of the ground state is elucidated and its applications are discussed. We find that planetary systems tend to have circular orbits in an effort to attain the ground state. The results of this paper may be useful for the modern problem of detecting planets around bright stars.     

Assessment of Land Surface Subsidence Due to Underground Metal Mining Using Integrated Spaceborne Repeat-Pass Differential Interferometric Synthetic Aperture Radar (DInSAR) Technique and Ground Based Observations

Differential interferometric synthetic aperture radar (DInSAR) is a novel remote sensing technique to measure earth surface deformation. It is capable of obtaining dense information related to the deformation of a large area efficiently, economically and effectively. Therefore, DInSAR is a promising technology for monitoring the earth surface deformation related to some natural hazardous events, such as earthquake, volcano eruption, land subsidence, landslide. In present study, Conventional DInSAR technique have been applied to a mineral rich zone, coming under the Khetri copper belt, a part of Northern Aravali range of hillocks in India, predominant with mining activities since late 1960’s to address the possibility of deformation phenomena due to hard rock underground metal mining. Four interferometric SAR data sets of Radarsat-2 was used for the study area to address the subsidence/uplift phenomena. Further, results obtained from conventional DInSAR technique using Radarsat-2 data sets compared with results obtained from ground based observation technique for its validity. In both the techniques, deformation results obtained in terms of average subsidence rate in mm (quarterly basis) of points under study within mining zone of Mine-A has well agreed to each other. Further, it has been observed that average subsidence rate in mm (quarterly basis) obtained from space based observation and ground based observation are 5.6 and 6.67, respectively over the points under study in mining zone of Mine-A.     

Shock waves in a dusty plasma having q-nonextensive electron velocity distribution

The dust-acoustic shock waves have been theoretically investigated using reductive perturbation technique. An unmagnetized four-component dusty plasma system consisting of nonextensive q-distributed electrons, Boltzmann distributed ions, and negatively as well as positively charged dust particles has been considered. The solution of Burgers equation in planar geometry is numerically analyzed. It has been observed that the nonextensive q-distribution of electrons has a significant role in the formation of shock waves. The relevance of our results to astrophysics as well as laboratory plasmas are briefly discussed.     

Bifurcations of electron acoustic traveling waves in an unmagnetized quantum plasma with cold and hot electrons

Bifurcations of nonlinear electron acoustic solitary waves and periodic waves in an unmagnetized quantum plasma with cold and hot electrons and ions has been investigated. The one dimensional quantum hydrodynamic model is used to study electron acoustic waves (EAWs) in quantum plasma. Applying the well known reductive perturbation technique (RPT), we have derived a Korteweg-de Vries (KdV) equation for EAWs in an unmagnetized quantum plasma. By using the bifurcation theory and methods of planar dynamical systems to this KdV equation, we have presented the existence of two types of traveling wave solutions which are solitary wave solutions and periodic traveling wave solutions. Under different parametric conditions, some exact explicit solutions of the above waves are obtained.