Flood inundation modeling using MIKE FLOOD and remote sensing data

A coupled 1D-2D hydrodynamic model, MIKE FLOOD was used to simulate the flood inundation extent and flooding depth in the delta region of Mahanadi River basin in India. Initially, the 1D model MIKE 11 was calibrated using river water level and discharge data of various gauging sites for the monsoon period (June to October) of the year 2002. Subsequently, the calibrated set up was validated using both discharge and water level data for the same period of the year 2001. The performance of calibration and validation results of MIKE 11 were evaluated using different performance indices. A bathymetry of the study area with a spatial resolution of 90m was prepared from SRTM DEM and provided as an input to the 2D model, MIKE 21. MIKE 11 and MIKE 21 models were then coupled using lateral links to form the MIKE FLOOD model set up for simulating the two dimensional flood inundations in the study area. Flood inundation is simulated for the year 2001 and the maximum flood inundation extent simulated by the model was compared with the corresponding actual inundated area obtained from IRS-1D WiFS image.     

Dwellers’ perception toward the Urban services of Panskura Municipality,India: an application of importance-performance models

The provision of urban service and citizens’ satisfaction is an important key issue in urban planning. Importance-performance analysis (IPA) is an effective and widely applicable technique to explore consumer’s satisfaction. IPA helps to prioritize the management strategies for urban services using the IPA. Purpose of the present study is to assess the performance of urban services and citizen’s satisfaction level of Panskura municipality using IPA models and improvement index. A total of 629 valid household responses are collected with the help of the door-to-door primary survey technique. The study reveals that all the selected seven urban services have significant importance-performance gap except water supply. Residents of the Panskura municipality are very much satisfied with the water supply service because of the very minimum improvement score. The combined result of IPA matrices and improvement index suggests residents are dissatisfied to a great extent with the performance of four urban services, i.e. health, economy, transportation and sanitation. These urban services require a problem-solving urgent action for restoration of the performance status. The improvement and prioritization of urban service are also required to fulfil the demand of target groups.

     

Vp/Vs ratios in the Yellowstone National Park region, Wyoming

In this paper we study the variation of V_p/V_s and Poisson's ratio (δ) in the Yellowstone National Park region, using earthquakes which were well recorded by a local seismic network. We find that the average V_p/V_s value within the geothermally active Yellowstone caldera is about 7% lower than in the area outside the caldera. Within the caldera itself there may be a further 2–7% reduction of V_p/V_s in the hydrothermally active Norris Geyser Basin, the Upper and Lower Geyser Basins, and the Yellowstone Lake and Mud Volcano regions. After considering various possible causes for V_p/V_s changes, such as geologic and structural differences, thermal effects, partial melting, and hydrothermal activity, we conclude that the most plausible explanation for the observed V_p/V_s reduction is the presence of hot-water at temperatures and pore-pressures near the water steam transition in the caldera geothermal reservoirs.     

Thermodynamic mixing properties of Mg(Al,Cr)2O4 spinel crystalline solution at high temperatures and pressures

Three Al-Cr exchange isotherms at 1,250°, 1,050°, and 796° between Mg(Al, Cr)₂O₄ spinel and (Al, Cr)₂O₃ corundum crystalline solutions have been studied experimentally at 25 kbar pressure. Starting from gels of suitable bulk compositions, close approach to equilibrium has been demonstrated in each case by time studies. Using the equation of state for (Al, Cr)₂O₃ crystalline solution (Chatterjee et al. 1982a) and assuming that the Mg(Al, Cr)₂O₄ can be treated in terms of the asymmetric Margules relation, the exchange isotherms were solved for Δ G ^*, and . The best constrained data set from the 1,250° C isotherm clearly shows that the latter two quantities do not overlap within three standard deviations, justifying the choice of asymmetric Margules relation for describing the excess mixing properties of Mg(Al, Cr)₂O₄ spinels. Based on these experiments, the following polybaric-polythermal equation of state can be formulated: , P expressed in bars, T in K, G _m ^ex and W _G,i ^Sp in joules/mol. Temperature-dependence of G _m ^ex is best constrained in the range 796–1,250° C; extrapolation beyond that range would have to be done with caution. Such extrapolation to lower temperature shows tentatively that at 1 bar pressure the critical temperature, T _c, of the spinel solvus is 427° C, with dT_c/dP≈1.3 K/kbar. The critical composition, X _c, is 0.42 , and changes barely with pressure. Substantial error in calculated phase diagrams will result if the significant positive deviation from ideality is ignored for Al-Cr mixing in such spinels.     

An internally consistent set of thermodynamic data for twentyone CaO-Al2O3-SiO2- H2O phases by linear parametric programming

The technique of linear parametric programming has been applied to derive sets of internally consistent thermodynamic data for 21 condensed phases of the quaternary system CaO-Al₂O₃-SiO₂-H₂O (CASH) (Table 4). This was achieved by simultaneously processing:

1. calorimetric data for 16 of these phases (Table 1), and
2. experimental phase equilibria reversal brackets for 27 reactions (Table 3) involving these phases.

Calculation of equilibrium P-T curves of several arbitrarily picked reactions employing the preferred set of internally consistent thermodynamic data from Table 4 shows that the input brackets are invariably satisfied by the calculations (Fig. 2a). By contrast, the same equilibria calculated on the basis of a set of thermodynamic data derived by applying statistical methods to a large body of comparable input data (Haas et al. 1981; Hemingway et al. 1982) do not necessarily agree with the experimental reversal brackets. Prediction of some experimentally investigated phase relations not included into the linear programming input database also appears to be remarkably successful. Indications are, therefore, that the thermodynamic data listed in Table 4 may be used with confidence to predict geologic phase relations in the CASH system with considerable accuracy. For such calculated phase diagrams and their petrological implications, the reader's attention is drawn to the paper by Chatterjee et al. (1984).     

Ephesite,Na(LiAl2) [Al2Si2O10] (OH)2: I. thermal stability and standard state thermodynamic properties

Ephesite, Na(LiAl₂) [Al₂Si₂O₁₀] (OH)₂, has been synthesized for the first time by hydrothermal treatment of a gel of requisite composition at 300≦T(° C)≦700 and \(P_{H_2 O}\) upto 35 kbar. At \(P_{H_2 O}\) between 7 and 35 kbar and above 500° C, only the 2M₁ polytype is obtained. At lower temperatures and pressures, the 1M polytype crystallizes first, which then inverts to the 2M₁ polytype with increasing run duration. The X-ray diffraction patterns of the 1M and 2M₁ poly types can be indexed unambiguously on the basis of the space groups C2 and Cc, respectively. At its upper thermal stability limit, 2M₁ ephesite decomposes according to the reaction (1) $$\begin{gathered} {\text{Na(LiAl}}_{\text{2}} {\text{) [Al}}_{\text{2}} {\text{Si}}_{\text{2}} {\text{O}}_{{\text{10}}} {\text{] (OH)}}_{\text{2}} \hfill \\ {\text{ephesite}} \hfill \\ {\text{ = Na[AlSiO}}_{\text{4}} {\text{] + LiAl[SiO}}_{\text{4}} {\text{] + }}\alpha {\text{ - Al}}_{\text{2}} {\text{O}}_{\text{3}} {\text{ + H}}_{\text{2}} {\text{O}} \hfill \\ {\text{nepheline }}\alpha {\text{ - eucryptite corundum}} \hfill \\ \end{gathered}$$ Five reversal brackets for (1) have been established experimentally in the temperature range 590–750° C, at \(P_{H_2 O}\) between 400 and 2500 bars. The equilibrium constant, K, for this reaction may be expressed as (2) $$log K{\text{ = }}log f_{{\text{H}}_{\text{2}} O}^* = 7.5217 - 4388/T + 0.0234 (P - 1)T$$ where \(f_{H_2 O}^* = f_{H_2 O} (P,T)/f_{H_2 O}^0\) (1,T), with T given in degrees K, and P in bars. Combining these experimental data with known thermodynamic properties of the decomposition products in (1), the following standard state (1 bar, 298.15 K) thermodynamic data for ephesite were calculated: H _f,298.15 ⁰ =-6237372 J/mol, S _298.15 ⁰ =300.455 J/K·mol, G _298.15 ⁰ =-5851994 J/mol, and V _298.15 ⁰ =13.1468 J/bar·mol.     

Lithogeochemistry as an indicator of uranium and tin mineralization, South Mountain Batholith, Nova Scotia, Canada

Uranium and tin occurrences in the South Mountain Batholith are preferentially found in or near a para-intrusive rock suite which is characterized by strong granophile element enrichments. Furthermore, bodies which show a Th-enrichment trend with increasing differentiation appear to be more favorable exploration targets than spatially associated bodies in which Th is depleted.     

Non‐stationary seismic response of tanks with soil interaction by wavelets

A wavelet‐based random vibration theory has been developed for the non‐stationary seismic response of liquid storage tanks including soil interaction. The ground motion process has been characterized via estimates of statistical functionals of wavelet coefficients obtained from a single time history of ground accelerations. The tank–liquid–soil system has been modelled as a two‐degree‐of‐freedom (2‐DOF) system. The wavelet domain equations have been formulated and the wavelet coefficients of the required response state are obtained by solving two linear simultaneous algebraic equations. The explicit expression for the instantaneous power spectral density function (PSDF) in terms of the functionals of the input wavelet coefficients has been obtained. The moments of this PSDF are used to estimate the expected pseudo‐spectral acceleration (PSA) response of the tank. Parametric variations are carried out to study the effects of tank height, foundation natural frequency, shear wave velocity of soil and ratio of the mass of tank (including liquid) to the mass of foundation on the PSA responses of tanks. Copyright © 2001 John Wiley & Sons, Ltd.     

Experimental and thermodynamic study of heterogeneous and homogeneous equilibria in the system NaAlSiO4-SiO2

Internally consistent thermodynamic datasets available at present call for a further improvement of the data for nepheline (Holland and Powell 1988; Berman 1991). Because nepheline is a common rock-forming mineral, an attempt has been made to improve on the present state of knowledge of its thermodynamic properties. To achieve that goal, two heterogeneous reactions involving nepheline, albite, jadeite and a-quartz in the system NaAlSiO₄-SiO₂ have been reversed bylong duration runs in the range 460 ≤ T(°C) ≤ 960 and 10 ≤ P(kbar) ≤ 22. Given sufficiently long run times, thealbite run products approach internal equilibrium with respect to their Al,Si order-disorder states. Using appropriate thermochemical, thermophysical, and volumetric data, Landau expansion for albite, and the relevant reaction reversals, a refined thermodynamic dataset (Δ_fH_i⁰ and S_i⁰) has been derived for nepheline, jadeite, a-quartz, albite, and monalbite. Our refined data agree very well with theircalorimetric counterparts, but have smaller uncertainties. The refined dataset for Δ_fH_i⁰ and S_i⁰, including their uncertainties and correlation, help generate the NaAlSiO₄-SiO₂ phase diagram including 2a confidence interval for eachP-T curve (Fig. 5). Editorial responsibility: W. Schreyer