贵州岩溶区地下河开发利用及其工程地质问题

<正> 一、前言云贵东部贵州高原亚热带岩溶化原野具有层状地貌的特点。岩溶地貌成因类型为溶蚀;溶蚀、侵蚀;溶蚀、构造三种。形成有峄顶齐高的峰丛、峰林与洼地、谷地;有中低山与沟谷、坡立谷、洼地;还有河流深切的峡谷、深谷与两岸阶地、台丘、平台,构成了多种组合类型。这些类型间隔而多级的分布在不同的高程上,总的趋势是由西往东形成阶梯状大斜坡,海拔高程由2900米,下降到400米,从而构成了岩溶地貌景观的“多层性”和“叠加性”。在这个多级型地块上,占全省面积(17.64万平方公里)73％的碳酸盐岩层,所形成的地下河和种类繁多的岩溶形态,主要受控于众所周知的岩性、构造、古水文网和现代水文网。      

基于相机摄影测量的冰面反照率反演方法研究

雪冰反照率是冰川与积雪能量平衡计算的关键参数,也是观测的难点. 为测量冰面反照率,试验采用相机摄影测量技术,在祁连山十一冰川开展了自动拍摄、并利用共线方程进行冰川正射制图,在此基础上于2012年7月28日-8月18日在冰川表面开展了不同海拔梯度的反照率观测. 通过统计分析晴天与阴天观测反照率与对应点相机拍摄获取的RGB归一化指数之间的关系,对十一冰川进行冰面反照率参数化方法研究. 结果表明：晴天冰面反照率与RGB归一化指数存在明显的指数关系,拟合R²达到0.79;而阴天的统计关系较差,线性拟合R²仅为0.52. 据此尝试利用晴天的拟合公式对整个冰面进行反照率参数化,计算表明：在晴天冰川表面地形阴影区的反照率存在低估现象,而无阴影区的反照率估算结果可信度较高. 利用2013年的反照率观测数据进行了参数化方案的验证,结果表明：观测值与模拟值平均误差仅为0.037,表明利用RGB影像对反照率参数化具有一定的可用性和可靠性.     

1961-2010年西北干旱区极端降水指数的时空变化分析

结合绝对阈值和百分位法定义极端降水事件的优点,提出了一种更灵敏的检测极端降水事件的方法. 该方法不仅能检测出常用降水指数无法检测到的降水量稀少地区尤其干旱区的极端降水事件,同时也能过滤掉其检测到的降水量丰富地区的虚假极端降水事件. 此方法首次被应用于统计1961年1月至2010年2月西北干旱区72个气象站点的年和季节的极端降水指数（大降水和强降水指数）,并分析了极端降水指数的时间变化趋势及其空间分布特征. 结果表明：西北干旱区春（3-5月）、秋（9-11月）、冬（12月至次年2月）三季极端降水指数无显著（P>0.05）变化趋势,夏季（6-8月）大降水的频率和降水量以及大降水降水量占总降水量的比重都显著增加;新疆地区极端降水指数为增加趋势的区域基本都分布在海拔较高（约海拔1 000 m以上）的地区;西北干旱区东部极端降水指数变化趋势的空间分布有明显的季节差异,表现为夏、秋季大部分地区为增加趋势,冬、春季大部分地区为减小趋势.     

桃林闪锌矿的矿物学特征

本文研究了桃林铅锌矿闪锌矿的化学成分、晶胞参数、红外光谱及物理性质《比重、硬度和反射率)等方面的待征。讨论了成分、结构与物理性质之间的关系,并探讨了矿床成因。     

基于孔压静力触探的岩土参数正态性检验方法对比

岩土参数的正态分布是岩土工程可靠分析的基本假定之一。目前,岩土工程参数的正态性检验以KS （Kolmogorov-Smirnov）检验为主,然而诸多研究表明,对于小样本数据,KS检验的正态性检验结果并不可靠。本文以废黄河泛滥沉积相粉土中的孔压静力触探（CPTU）锥尖阻力q_t数据为研究对象,首先采用ANOVA （方差分析）检验,从CPTU测试资料中进行总体的样本筛选,然后应用SW （Shapiro-Wilk）检验、KS检验、LF （Lilliefors）检验和AD （Anderson-Darling）检验等4种正态性检验方法,在不同样本容量条件下,对测试数据进行正态性检验评价。当测试数据的样本容量充足时,分析结果表明：SW检验结果最为严格,KS检验结果最不保守,而LF检验和AD检验的严格性介于两者之间;对于常规岩土工程设计,采用KS检验结果即可满足稳定性分析要求,对于复杂岩土工程设计,采用SW检验对设计参数进行正态性检验,可降低设计的不确定性。     

Corrosion behavior of anodic oxidized TiO<Subscript>2</Subscript> film in seawater

TiO₂ films were formed on metallic titanium substrates by the anodic oxidation method in H₂SO₄ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO₂ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO₂ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO₂ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO₂ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.     

ELECTROCHEMICAL CORROSION BEHAVIOR OF STEEL IN THE JUNCTURE AREA OF SEA CLAY AND SAND

Corrosion behavior of steel in the juncture area of sea clay and sand was studied. The results show that galvanic corrosion occurred between steel samples buried in sea clay and sand, and that the polarity of the galvanic cell reversed after some testing later. The cause of reversing of polarity is discussed.     

APPLICATION OF CLAYS TO REMOVAL OF RED TIDE ORGANISMS Ⅰ.COAGULATION OF RED TIDE ORGANISMS WITH CLAYS

Coagulation of red tide organism cells with clays is discussed in theory and the effects of some fac-tors on it are studied.A quantitative model is presented which describes how the coagulation varies withpH in solution.According to the model,within the pH-range between pH_(zpc_a)and pH_(zpc_b),V_R is negativeand the coagulation is strong and strongest at pH=(pH_(zpc_a)+pH_(zpc_b))/2.It is also demonstrated that whenthe diameter of clay particles is close to that of cells,the collision probability is low,resulting in weakercoagulation.The model results have been corroborated by experiments and so are scientific and theoreticalbases for application.