微波消解-电感耦合等离子体质谱法测定海泡石中的稀土元素

海泡石是一种纤维状含水的富镁硅酸盐黏土矿,其中的稀土元素含量在1×10~(-7)～1×10~(-5)之间,目前还没有建立海泡石中稀土元素的国家标准分析方法。测定岩石中的稀土元素主要是采用电感耦合等离子体质谱法(ICP-MS),样品前处理一般采用封闭溶矿和碱熔,但这两种处理方法耗时较长,效率不高。本文通过比较硝酸-氢氟酸-过氧化氢、硝酸-氢氟酸、硝酸-过氧化氢三种样品前处理方法,确定使用硝酸-氢氟酸溶矿,然后进行微波消解同时赶去氢氟酸,避免氢氟酸与稀土元素生成难溶的氟化物,再采用ICP-MS法测定15种稀土元素的含量。由于海泡石中的镁含量较高,为降低基体效应,以~(103)Rh和~(185)Re作内标补偿基体效应和校正灵敏度漂移,各元素测定值的准确性显著提高,回收率为91. 2%～110. 9%,检出限为0. 002～0. 011μg/L,精密度≤2. 79%。本方法与封闭酸溶ICP-MS法的分析结果吻合较好,且用酸量少(7 mL),溶矿效率高(1 h),检出限更低。     

基于重力及重力梯度数据的位场偏移成像

为了验证位场偏移快速成像方法的有效性以及对比基于重力和重力梯度数据的偏移成像的效果,笔者利用MATLAB编写了重力及重力梯度数据位场偏移成像的算法,并进行了模型正演计算,发现基于梯度数据的偏移成像的横向分辨率、抗噪性和抗背景场能力好于重力数据的偏移成像,并且能够较好的确定模型的中心埋深。将此方法应用于葫芦岛市黑鱼沟的某铅锌矿洞的深度计算中,验证了该方法的有效性。     

准噶尔盆地吉木萨尔凹陷梧桐沟组层序地层划分

准噶尔盆地吉木萨尔凹陷二叠系梧桐沟组作为一套重要的储集岩,具有良好的油气成藏前景,但对其层序划分及地层沉积样式的认识一直存在争议。在构造背景分析的基础上,结合岩芯、测井及地震资料,对研究区梧桐沟组层序地层划分及地层沉积样式研究表明,梧桐沟组沉积时期构造强度较弱,地形较为平缓,地层在全区稳定分布;中晚二叠世盆地发生造山运动,吉木萨尔凹陷东南边缘区域经过构造抬升,上部地层遭受不同程度的剥蚀,形成了现今"底平顶削"的地层样式。以凹陷中部少数地层保存较全的井的地层叠加样式分析为基础,通过井-震结合识别不同类型界面,特别是最大湖泛面,建立了区域层序地层格架,即梧桐沟组为一个完整的长期基准面旋回(三级层序),并在其内部识别出5个中期旋回。梧桐沟组地层在不同的层序发育时期表现出不同的旋回叠加样式:下段沉积时期,即最大湖泛面以下,随着可容纳空间的增大,地层表现为明显的退积叠加样式;上段沉积时期,即最大湖泛面以上,随着可容纳空间的减小,地层表现为明显的进积叠加样式,符合沉积物体积分配原理。     

Mid-Cretaceous Hothouse Climate and the Expansion of Early Angiosperms

The remarkable transition of early angiosperms from a small to a dominant group characterized the terrestrial ecosystem of the Cretaceous. This transition was instigated and promoted by environmental changes. Mid-Cretaceous is characterized by major geological events that affected the global environment. δ18O, palaeothermometer TEX86, and other climatic indices from marine sediments suggest rapid temperature increase during mid-Cretaceous despite occasional short cooling events. Simultaneously, terrestrial deposits in East Asia changed from coal-bearing to shale, then to red beds and evaporites. Plant assemblages and other paleoclimate indicators point to rapid aridification for mid-Cretaceous terrestrial environments. In addition, the wildfires were frequently spread all over the earth by the numerous charcoal evidence during the Mid-Cretaceous. Thus, we speculate that the seasonally dry and hot conditions of mid-Cretaceous created a fiery hothouse world. Early angiosperms increased in abundance and diversity and evolved from a few aquatic species to terrestrial herbaceous and then to the diversified flora of today. Angiosperms showed rapid physiological evolution in vein density and leaf area that improved photosynthesis and water absorption. These ecophysiological changes made early angiosperms well adapted to the hot and dry environment in mid-Cretaceous. Moreover, these physiological changes facilitated the fire–angiosperm cycles in mid-Cretaceous that likely further stimulated the early angiosperm evolution.     

An improved ionosphere interpolation algorithm for network RTK in low-latitude regions

A traditional interpolation algorithm with the linear interpolation method (LIM) using a fixed number of reference stations is widely used in network RTK to obtain the ionospheric delays for the users. In low-latitude regions, where the ionosphere is relatively active, however, large interpolation errors exist, especially for satellites at low elevation angles. Considering the characteristics of “coinciding ionospheric pierce points (CIPPs)” with a similar nature of ionospheric delays, an improved interpolation algorithm is proposed. In this algorithm, all stations with CIPPs are used to establish the interpolation model; thus, more precise interpolation model is achieved. To validate the performance of the proposed algorithm, data from some reference stations in Guangdong Province of China were used, and the results are compared with those with the traditional interpolation algorithm. Numerical analysis shows that the interpolation accuracy of the proposed algorithm increases by 10–30% compared with the traditional one. Since the number of reference stations is flexible, the proposed algorithm can also balance the model accuracy with the computation burdens. In addition, the proposed algorithm is less affected by the selection of master reference station. In terms of network RTK on-the-fly positioning, the time-to-first-fix is reduced when replacing the traditional interpolation algorithm with the proposed one.     

粤西河台金矿田糜棱岩XRD特征及其地质意义

粤西河台金矿区位于钦州湾—杭州湾（钦—杭）结合带南段的云开地区,是典型的受韧性剪切带控制的金矿。然而,对于剪切带中有利于金成矿的地质环境及其成矿过程仍然存在争议。本文在对河台矿区高村矿床进行详细野外地质调查的基础上,通过X射线衍射（XRD）对含金剪切带中各类糜棱岩系列岩石进行系统研究,建立应力变化—成分变异的对比序列,从而进一步揭示剪切变形与金矿化的关系。结果显示,剪切带中白（绢）云母的含量在9%~40%,并且在初糜棱岩、无矿糜棱岩、含矿糜棱岩、无矿超糜棱岩、含矿超糜棱岩中含量呈现出逐渐递增的趋势。白（绢）云母主要为2M1型,b0值分布在0.55505~0.99002 nm之间,在初糜棱岩、无矿糜棱岩和无矿超糜棱岩中逐渐增高,分别形成在低压、中压和高压环境。可见,从初糜棱岩到超糜棱岩,随着变形强度的增加,热液活动也随之增强,从而新生成了大量白（绢）云母。然而,在含矿的糜棱岩和超糜棱岩中还存在一些低压白云母,推测其可能是在后期脆性裂隙中由于流体活动所新形成的。因此,成矿可能经历了两个阶段,即早期的韧性剪切变形阶段导致金的初步富集,后期叠加的脆性破裂阶段形成具有工业品位的矿体。另外,无矿超糜棱岩的石英含量（29.8%）明显低于糜棱岩（44.2%）,推测在形成石英脉型矿体过程中,部分热液可能来自于其围岩超糜棱岩。因此,相对于初糜棱岩和糜棱岩,超糜棱岩中更有利于金矿的形成。     

The nonlinear time lag multivariable grey prediction model based on interval grey numbers and its application

Natural Hazards - The linear relationship of the original grey prediction model is too single, and the original grey prediction model does not consider the time delay of the effect of the current...     

基于孔压静力触探的岩土参数正态性检验方法对比

岩土参数的正态分布是岩土工程可靠分析的基本假定之一。目前,岩土工程参数的正态性检验以KS （Kolmogorov-Smirnov）检验为主,然而诸多研究表明,对于小样本数据,KS检验的正态性检验结果并不可靠。本文以废黄河泛滥沉积相粉土中的孔压静力触探（CPTU）锥尖阻力q_t数据为研究对象,首先采用ANOVA （方差分析）检验,从CPTU测试资料中进行总体的样本筛选,然后应用SW （Shapiro-Wilk）检验、KS检验、LF （Lilliefors）检验和AD （Anderson-Darling）检验等4种正态性检验方法,在不同样本容量条件下,对测试数据进行正态性检验评价。当测试数据的样本容量充足时,分析结果表明：SW检验结果最为严格,KS检验结果最不保守,而LF检验和AD检验的严格性介于两者之间;对于常规岩土工程设计,采用KS检验结果即可满足稳定性分析要求,对于复杂岩土工程设计,采用SW检验对设计参数进行正态性检验,可降低设计的不确定性。     

水—粮食—能源—生态系统关联研究进展

传统的水—粮食—能源关联对生态系统的支持与反馈能力考虑不足,增加了协同保障区域水—粮食—能源安全的难度.综述了近年来国际上水—粮食—能源—生态系统关联框架的搭建,发现有必要从生态系统服务的角度统筹水、粮食、能源等资源部门的社会治理过程.基于生态系统类型,可分为农业、河流、森林、草地和城市生态系统的5种常见关联结构,但目前针对森林和草原生态系统的研究相对不足.量化评估中子系统边界的确定,关联预测中多主体对关联的影响,整合优化中结合资源管理和生态修复是难点所在.未来可以从把握区域特征、扩充指标体系、整合模型需求和优化国土空间4个方向入手优化水—粮食—能源—生态系统关联结构,为区域可持续发展提供整体决策依据.