Observing the critical zone on a critical budget: The Peri Lake experimental catchment

The Peri Lake Experimental Catchment, in Southern Brazil, is a small coastal lake (5 km², 7 m depth) with a total catchment area of 20 km². The catchment is mainly covered by subtropical Atlantic Forest. Peri Lake is a recreational destination, an important ecosystem for biodiversity preservation, and a major water supply source. Even though there is a clear social and economic relevance, the information on this ecosystem is scarce, especially regarding the dynamics of water balance and water quality. We built this observatory using a low-cost, low-technology monitoring system to estimate the major components of the water budget on what we called a critical budget. We monitor meteorology, rainfall interception in two plots, overland flow and groundwater connectivity in a representative hillslope; and streamflow and velocity are measured in several small headwater rivers mostly starting during 2015. Geographic information on topography, land cover, geology, soil characteristics and the location of all the equipment installed in the field are also provided. The data set can be used to understand rainfall interception in Atlantic forests, catchment connectivity and streamflow permanence in coastal areas, spatial patterns of baseflow, and the modelling of complex processes in the critical zone involving the interaction between surface and groundwater, that are important in coastal lake ecosystems. Besides being used for research and education, we hope this observatory built on a shoestring budget will encourage fieldwork particularly in underrepresented and underfunded regions of the world.     

Major moisture sources for Western and Southern India and their role on synoptic‐scale rainfall events

Although the identification of the moisture sources of a region is of prominent importance to characterize precipitation, the origin and amount of moisture towards the Indian Subcontinent and its relationship with the occurrence of precipitation are still not completely understood. In this article, the origin of the atmospheric water arriving to the Western and Southern India during a period of 5 years (1 January 2000–31 December 2004) is investigated by using a Lagrangian diagnosis method. This methodology computes budgets of evaporation minus precipitation by calculating changes in the specific humidity of thousands of air particles aimed to the study area following the observed winds. During the summer monsoon, the main supply of moisture is the Somali Jet, which crosses the equator by the West Indian Ocean. The recycling process is the main water vapour source in winter. Two additional moisture sources located over northwestern India and the Bay of Bengal are identified. A 30% increase in the moisture flux from the Indian Ocean has been related to the occurrence of strong precipitation in the area, and at the end of the monsoon, the recycling became a significant contribution to the last part of the wet season of Western and Southern India. Copyright © 2011 John Wiley & Sons, Ltd.     

New evidence for the presence of reindeer (Rangifer tarandus) on the Iberian Peninsula in the Pleistocene: an archaeopalaeontological and chronological reassessment

Reindeer (Rangifer tarandus) populations reached the Iberian Peninsula during the end of the Middle Pleistocene and there are numerous examples of this species from Late Pleistocene Mousterian and Upper Palaeolithic sites. In this paper, new evidence of reindeer in the east Cantabrian region is presented that further supports the timing of this species’ first appearance, and previous assessments are updated. To date, the presence of this species has been identified at 55 sites in the Iberian Peninsula, nearly as many as those of mammoth (Mammuthus primigenius) and woolly rhinoceros (Coelodonta antiquitatis) combined. Most of the sites with presence of reindeer (50) are located in the Cantabrian region with a clear increase in the density of sites and remains towards the Pyrenees. The remaining five sites with evidence of reindeer are located on the other side of the Pyrenees in the NW corner of Catalonia. In contrast, archaeological evidence of reindeer in the form of art (both parietal and portable) is more scarce and scattered. Evidence for the representation of these animals has been found outside the northern fringe of the Iberian Peninsula, which could reflect either long‐distance cultural communication or the movement of human groups.     

Isotopic fingerprints of Milankovitch cycles in Pennsylvanian carbonate platform‐top deposits: the Valdorria record,Northern Spain

Sedimentary cyclic sequences deposited during the Late Palaeozoic Ice Age are widespread. Glacio‐eustatic control of the cyclic patterns is commonly accepted, and the durations of the cyclothems generally match the short‐ and long‐eccentricity Milankovitch orbital parameters. Nevertheless, geochemical fingerprints of orbital parameters are poorly documented in deep‐time sedimentary records. Here, we report on well‐exposed Bashkirian cyclothems of c. 123 ka and c. 400 ka durations from the Valdorria platform. The shorter‐term cyclothems can be grouped into longer‐term composite sequences that are consistent with generally accepted durations of c. 125 ka and c. 400 ka for Milankovitch eccentricity cycles. The stratigraphic pattern is mirrored by the isotope geochemical signals, which show distinct recurring trends. These trends are confirmed by statistical tests. Whereas intrinsic factors and/or subaerial exposure related to sea‐level lowstands might have truncated cycle patterns in tectonically stable basins, rapid subsidence of the Valdorria platform's foreland basin appears to have contributed to a faithful recording of cyclothems of different orders. The patterns and biostratigraphic constraint revealed in this study demonstrate the power of orbital forcing in imprinting sedimentary and geochemical signals in the rock record.     

Evolution in the provenance of a tectonically controlled Plio–Pleistocene alluvial system between the Variscan Iberian Massif and the Atlantic margin, Portugal

Geochemical and mineralogical data from a Pliocene to Pleistocene alluvial sequence are integrated to access the factors that control rare earth elements (REE) geochemistry and the evolution and spatial differences in provenance. The studied alluvial system is situated in a tectonic active setting at the contact between the Variscan Massif, with several Paleozoic and Precambrian units that support a coastal range, and the Atlantic margin. REE and HREE abundances are generally higher in swamp-lake than in floodplain sediments. The majority of the REE in floodplain sediments is hosted by Y and Th-bearing minerals and illite; in swamp-lake sediments is also probable an association with organic matter. The high Gd/Yb, Eu/Eu* and kaolinite content in older sediments suggest that during the earlier phases provenance was mainly from the hinterland (weathered granitic rocks and its sediment cover). The subsequent illite (Mg-rich) clay assemblages and REE patterns indicate mainly lateral input from the eastern basin edge (Palaeozoic and Precambrian metapelitic rocks). These sediments tend to have lower Gd/Yb and La/Sm than their source rocks. The analysis of the chemical index of alteration (CIA) indicates that although a north-directed fluvial axis existed at that time the “mature” basin edge units found to the south (Silurian) had a limited role in supplying sediments. This shift in provenance is attributed to the uplift of the coastal range. Afterwards, the contribution of recycled Cretaceous and Cenozoic sedimentary units increased progressively. This is demonstrated by the increase is SiO₂/TiO₂, CIA and kaolinite/illite when the climatic conditions are expected to have become less chemically aggressive.     

Rapid Analysis of 1,4‐Dioxane in Groundwater by Frozen Micro‐Extraction with Gas Chromatography/Mass Spectrometry

An innovative micro‐extraction of aqueous samples coupled with gas chromatography/mass spectrometry in selected ion‐monitoring mode (GC/MS‐SIM) was developed to selectively analyze for 1,4‐dioxane with low part‐per‐billion detection sensitivity. Recoveries of 1,4‐dioxane ranged from 93% to 117% for both spiked laboratory reagent water and natural groundwater matrices, the later having elevated organic carbon content (8.34 ± 0.31 mg/L as total organic carbon). We observed that freezing the aqueous sample along with the extraction solvent enhanced the extraction efficiency, minimized physical interferences, and improved sensitivity resulting in a limit of detection for 1,4‐dioxane to approximately 1.6 μg/L. This method substantially reduces the labor, time, reagents and cost, and uses instruments that are commonly found in analytical laboratories. This method requires a relatively small sample volume (200 μL), and can be considered a green analytical method as it minimizes the use of toxic solvents and the associated laboratory wastes.     

Stable (C,O) and radiogenic (Sr,Nd) isotopes of carbonates as indicators of magmatic and post-magmatic processes of phoscorite-series rocks and carbonatites from Catalão I,central Brazil

The Late-Cretaceous Catalão I contains stockworks of thin dykes of phoscorite-series rocks, which can be subdivided into P1 (olivine-bearing, phoscorites) and P2/P3 (olivine-lacking, nelsonites). Dolomite carbonatites (DC) are intimately associated with nelsonites, as pockets and dykes. The P2 apatite nelsonite, the P3 magnetite nelsonite, and, to a lesser extent DC, host the Catalão I niobium mineralization. C–O isotopes signatures in carbonates reveal several distinct magmatic and post-magmatic processes. Limpid carbonates with stable isotopic mantle-like composition show Rayleigh fractionation and are interpreted as primary, while those with brittle-turbid aspect, and higher oxygen isotope composition, probably underwent recrystallization by interaction with H₂O-rich fluids. A group of samples shows higher oxygen compositions and lower carbon values, which could be explained by degassing of carbonatite magma during cooling. A degassing pattern, parallel to magmatic degassing but at higher oxygen and lower carbon compositions, observed in carbonate veins, may indicate degassing of fracture filling fluids. Furthermore, C–O isotopes of carbonate from monazite-bearing carbonatite have a positive correlation, indicating a distinct, late-stage carbo-hydrothermal event. Though the Catalão I nelsonites and phoscorites are of igneous origin, they underwent several post-magmatic events, which sometimes overprinted partially or entirely the magmatic isotope signature.     

Barnacles as biomonitors of metal contamination in coastal waters

The use of barnacles as biomonitors of metal contamination in coastal waters worldwide is reviewed as a critique compilation of the reported studies and presents resume-tables of available data for future reference. The barnacle body reflects both short and long-term metal level environmental variations and the metal bioaccumulation occurs mainly in their granules (relatively inactive pools). The barnacle body is considered as good biomonitoring material and different barnacle species could bioaccumulate metal concentration ranges of 40–153,000 μg/g of Zn, 20–22,230 μg/g de Fe, 1.5–21,800 μg/g of Cu, 5.9–4742 μg/g of Mn, 0.1–1000 μg/g of Pb, 0.7–330 μg/g of Cd, 0.4–99 μg/g of Ni and 0.2–49 μg/g of Cr. However, as the plates (‘shells’) of barnacle exoskeletons can be affected by metal levels in coastal waters, mainly in their composition and morphology, they are not considered good biomonitoring material. Despite this, the use of a specific barnacle species or group of species in a specific region must firstly be carefully validated and the interpretation of the contaminant bioaccumulation levels should involve specific environmental variations of the region, physiological parameters of the barnacle species and the relationship between the potential toxicity of the contaminant for the environment and their significance for the barnacle species. Barnacles, particularly a widespread cosmopolitan species such as Amphibalanus amphitrite, have a great potential as biomonitors of anthropogenic contamination in coastal waters and have been used worldwide, including Europe (United Kingdom, Turkey, Poland, Croatia, Spain and Portugal), Asia (India and China), Oceania (Australia), North America (Florida, Massachusetts and Mexico) and South America (Brazil). The use of barnacle species as biomonitors of metal contamination in coastal waters is considered an important and valuable tool to evaluate and predict the ecological quality of an ecosystem.     

优视摄影测量方法及精度分析EI北大核心CSCD

无人机最优路径规划和精准数据采集是复杂城市场景三维重建的关键问题。优视摄影测量利用被摄对象的概略模型,结合密集采样的初始视点生成和采样点可重建性约束的视点优化技术,实现最小数据采集代价下的精确三维模型重建。本文首先研究了优视摄影测量的基本原理;然后利用优视摄影测量技术进行真实场景的无人机影像采集,并结合激光扫描点云进行空三精度分析和Mesh模型质量验证。试验结果表明,优视摄影测量显著提高了Mesh模型的重建质量;对于倾斜摄影难以观测的部分建筑物立面区域,精度提升达到3~5倍;与倾斜摄影相比,优视摄影测量能建立稳健影像连接,实现较高的绝对定位精度。