Intercomparison of measurements of bulk snow density and water equivalent of snow cover with snow core samplers: Instrumental bias and variability induced by observers

Manually collected snow data are often considered as ground truth for many applications such as climatological or hydrological studies. However, there are many sources of uncertainty that are not quantified in detail. For the determination of water equivalent of snow cover (SWE), different snow core samplers and scales are used, but they are all based on the same measurement principle. We conducted two field campaigns with 9 samplers commonly used in observational measurements and research in Europe and northern America to better quantify uncertainties when measuring depth, density and SWE with core samplers. During the first campaign, as a first approach to distinguish snow variability measured at the plot and at the point scale, repeated measurements were taken along two 20 m long snow pits. The results revealed a much higher variability of SWE at the plot scale (resulting from both natural variability and instrumental bias) compared to repeated measurements at the same spot (resulting mostly from error induced by observers or very small scale variability of snow depth). The exceptionally homogeneous snowpack found in the second campaign permitted to almost neglect the natural variability of the snowpack properties and focus on the separation between instrumental bias and error induced by observers. Reported uncertainties refer to a shallow, homogeneous tundra-taiga snowpack less than 1 m deep (loose, mostly recrystallised snow and no wind impact). Under such measurement conditions, the uncertainty in bulk snow density estimation is about 5% for an individual instrument and is close to 10% among different instruments. Results confirmed that instrumental bias exceeded both the natural variability and the error induced by observers, even in the case when observers were not familiar with a given snow core sampler.     

Identification and Apportionment of Sources of Ozone‐forming Potential for Proper Reduction Strategies

In this study, results of source identification and apportionment for ambient volatile organic compounds (VOCs) from a previous work were used to estimate ozone‐forming potentials (OFPs) of effective sources for developing proper strategies for reduction of tropospheric ozone pollution. The source identification and apportionment of ambient VOC pollution within Yildiz Technical University's Davutpasa Campus (Istanbul, Turkey) was done by positive matrix factorization (PMF). The results suggested five effective source groups with the emissions related with paint use and solvent use having the highest contributions (36.8 and 28.2%). The results from PMF were used along with maximum incremental reactivities to estimate potentials of individual sources for ozone formation. It was found that biogenic emissions (3.78) and traffic related emissions (gasoline and diesel vehicle exhaust) (3.83 and 3.15, respectively) have the highest potential for ozone formation in terms of grams O₃/g VOC emitted. The results were used to suggest proper source‐based reduction strategies for OFP.     

Transformation of Tobacco with ScMTII Gene‐Enhanced Cadmium and Zinc Accumulation

Genetic transformation is gaining importance for developing plant types suitable to metal accumulate and/or hyperaccumulate. In this study, the transgenic tobacco plant which transferred the ScMTII gene from Saccharomyces cerevisiae to wild type tobacco cultivar Petite Havana (SR1) was grown on soils with low and high cadmium (Cd) and zinc (Zn) concentrations in a growth chamber for 6 weeks and compared to wild type tobacco for Cd and Zn accumulation. Cadmium and Zn accumulations in the transgenic and wild type tobacco plants were increased with the increasing Cd and Zn concentrations. Unlike Zn, the transgenic plant accumulated significantly higher amount of Cd compared to the wild type control plants. Shoot Cd concentrations of transgenic tobacco in higher Cd dosages reached the above the hyperaccumulation threshold value of 100 mg Cd kg^?1 in the dry weight (DW). Transgenic tobacco accumulated 354, 400, 372, and 457 mg Cd kg^?1 DW, for 10, 20, 40, and 80 mg Cd kg^?1 soil treatments, respectively. These values are 3.5–4.5‐fold higher than that of Cd hyperaccumulation threshold value. With 10 mg kg^?1 Cd treatment, the bioconcentration factor (BCF) of transgenic tobacco plants for Cd reached up to 35 in which the threshold value for BCF should be at least 10. Our results showed that the transgenic tobacco may be used as a good Cd hyperaccumulator plant and for phytoextraction of Cd contaminated soils, but not for Zn.     

Environmental isotopic evaluation of the springs located in Kazan Trona basin in Central Turkey

Kazan Trona ore field, the second discovered deposit in Central Turkey, is planned to be extracted by solution mining technology. Understanding the hydrogeology of the springs in such an area is vital since they can be affected during mining operations. The aim of this study is to provide an isotopic approach by utilizing environmental isotope techniques to the springs in the study area, thereby, to enhance the understanding of their occurrence by complementing the previous geochemical studies. Here, the isotopic signatures and the recharge elevations of the springs are demonstrated together with their field parameters. The relationship between ??D and ??¹⁸O suggest strong evaporation in some of the samples after recharge. For those springs, the unmodified signatures were determined and the recharge elevations were calculated to be between 1100 and 1248 m. These elevations correspond to Incirlik and Asmalidere Members and upper Neogene units. The relationship between Tritium and Electrical Conductivity suggested that SP-6, SP-3 and SP-4 have shallow circulation when compared to SP-7 having both the lowest tritium and highest EC value. This finding is in accordance with the geochemical data, which suggests SP-7 emerges from the deeper, older groundwater present above the trona deposit.     

Correlation analysis of vertical total electron content

It is necessary to model and analyze the ionospheric effects due to a direct relationship between Global Positioning System (GPS) applications and changes in the ionosphere. In order to monitor these changes, the ionosphere can be represented by the vertical total electron content (VTEC) which can be used to analyze ionospheric conditions from a variety of stations. In this study, 21 stations were used to carry out analysis and estimation of VTEC. Three days during a geomagnetic storm, namely, 7, 8, and 9 January 2005, are chosen for investigation. In addition, the de-correlation time of the VTEC was estimated to define ionospheric variations in time using autocorrelation analysis. The de-correlation time of the ionosphere is based on correlation times estimated by using autocorrelation functions. From the high-latitude stations, the mean of the correlation times decreased from 8 to 6 epochs during a storm. In this time period, it was found from the station results that the ionosphere was more affected at the high-latitude than at the mid-latitude region.     

Alterations of the nitrogen mineralization rates in soils of forest community depending on the ski run construction (Mount Uluda?, Bursa, Turkey)

Since 1940s, Mount Uludağ (Bithynian Olympus) has been considered famous with winter sports center in Turkey. In addition, it is one of the rare places because of its plant diversity and is also one of the important plant areas of Turkey. The ski run constructions are rapidly increased in the past decades in the alpine and subalpine belts of the mountain. Rate of nitrogen mineralization and some properties of soil were investigated in the soils of the three ski runs and undisturbed neighborhood forest sites. These ski runs are at the upper part of the forest belt in the mountain. Abies bornmuelleriana forest community is the postclimax and very sensitive to destruction. The rates of the nitrogen mineralization in the soils were determined in controlled conditions (60% water-holding capacity, 20°C). Nitrification and nitrogen mineralization were in the ski run inside where the natural recovery started, increased compared with the outside of the ski runs. Waterholding capacity, organic carbon, and total nitrogen were decreased in the massive damaged ski run, and due to these changes, the rates of mineralization and nitrification were also decreased.     

Global mass wasting during the Middle Ordovician: Meteoritic trigger or plate-tectonic environment?

Mass wasting at continental margins on a global scale during the Middle Ordovician has recently been related to high meteorite influx. Although a high meteorite influx during the Ordovician should not be neglected, we challenge the idea that mass wasting was mainly produced by meteorite impacts over a period of almost 10 Ma. Having strong arguments against the impact-related hypothesis, we propose an alternative explanation, which is based on a re-evaluation of the mass wasting sites, considering their plate-tectonic distribution and the global sea level curve. A striking and important feature is the distribution of most of the mass wasting sites along continental margins characterised by periods of magmatism, terrane accretion and continental or back-arc rifting, respectively, related to subduction of oceanic lithosphere. Such processes are commonly connected with seismic activity causing earthquakes, which can cause downslope movement of sediment and rock. Considering all that, it seems more likely that most of this mass wasting was triggered by earthquakes related to plate-tectonic processes, which caused destabilisation of continental margins resulting in megabreccias and debris flows. Moreover, the period of mass wasting coincides with sea level drops during global sea level lowstand. In some cases, sea level drops can release pore-water overpressure reducing sediment strength and hence promoting instability of sediment at continental margins. Reduced pore-water overpressure can also destabilise gas hydrate-bearing sediment, causing slope failure, and thus resulting in submarine mass wasting. Overall, the global mass wasting during the Middle Ordovician does not need meteoritic trigger.     

Eocene tonalite–granodiorite from the Havza (Samsun) area,northern Turkey: adakite-like melts of lithospheric mantle and crust generated in a post-collisional setting

ABSTRACT

Eocene intermediate to felsic plutons of different sizes and compositions are widespread in the Eastern Pontides Orogenic Belt in northern Turkey. Of these, the Ta?l?k Tepe pluton in the Havza (Samsun) area is fine-to-medium-grained, with granular, porphyritic, and micrographic textures, and include mafic microgranular enclaves (MMEs). LA-ICP-MS U-Pb zircon dating yielded emplacement ages of 42.9 (± 1.4) and 40.5 (± 1.3) Ma for the host granodioritic pluton and the dioritic MMEs, respectively. Petrochemically, the host pluton has I-type, high-K calc-alkaline, and metaluminous-to-slightly peraluminous features (A/CNK = 0.95–1.06). The host pluton also shows geochemical features of adakite-like rocks with high SiO₂ (67–68 wt%) and Al₂O₃ (15.5–16.0 wt%) content and Ba/La (17–23), Sr/Y (40.7–61.6), and La_N/Yb_N (14.4–23.7) ratios and low Y (8.2–9.9 ppm) and Yb_N (3.1–4.4) contents. Whole-rock major and trace element variations suggest that fractional crystallisation played a significant role in the pluton evolution. The N-MORB normalised trace element patterns of the pluton are similar to those of MMEs with enrichment in large-ion lithophile elements, Th and Ce, and negative Nb and Ti anomalies. Chondrite-normalised rare earth element plots show moderate-to-highly enriched concave patterns (La_N/Lu_N = 14.2–21.6) with insignificant negative Eu anomalies (Eu_N/Eu* = 0.86–1.14), all of which imply hornblende fractionation during magmatic evolution. The pluton samples have ⁸⁷Sr/⁸⁶Sr ratios of 0.704767 to 0.704927, ¹⁴³Nd/¹⁴⁴Nd ratios of 0.512767–0.512774, εNd values of (+2.52) – (+2.65), and δ¹⁸O values of 7.9–9.7‰. The isotopic compositions of the host pluton and MMEs are similar to I-type granitoids derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. Combined with regional studies, these new data suggest that the parental magma of the studied adakite-like pluton was generated from the lithospheric mantle and then modified by fractional crystallisation and assimilation in a post-collisional setting.     

Failure analysis of the granite for a dam foundation

This paper presents the numerical and experimental investigation of a dam foundation. The site consists of granite and especially weathered granite. Numerical and analytical analyses have been conducted to evaluate suitability of the granite for a dam foundation. Mohr–Coulomb failure criterion has been used to calculate the compressive strength of the rock mass. Finite element implementation of Mohr–Coulomb criterion has been used for deformation and settlement analysis. Packer testing and in-situ estimation of rock mass deformability using the Goodman jack have been performed. The results of the evaluations show that very small normal and differential settlements can be expected in structural regions due to dam construction, and the compacted concrete dam can safely be constructed on either the competent granite or the weathered granite. However, the dam foundation on the weathered granite has high conductivity potential problems for the reservoir.