Timing of the Nihewan formation and faunas

Magnetostratigraphic dating of the fluvio-lacustrine sequence in the Nihewan Basin, North China, has permitted the precise timing of the basin infilling and associated Nihewan mammalian faunas. The combined evidence of new paleomagnetic findings from the Hongya and Huabaogou sections of the eastern Nihewan Basin and previously published magnetochronological data suggests that the Nihewan Formation records the tectono-sedimentary processes of the Plio-Pleistocene Nihewan Basin and that the Nihewan faunas can be placed between the Matuyama-Brunhes geomagnetic reversal and the onset of the Olduvai subchron (0.78-1.95 Ma). The onset and termination of the basin deposition occurred just prior to the Gauss-Matuyama geomagnetic reversal and during the period from the last interglaciation to the late last glaciation, respectively, suggesting that the Nihewan Formation is of Late Pliocene to late Pleistocene age. The Nihewan faunas, comprising a series of mammalian faunas (such as Maliang, Donggutuo, Xiaochangliang, Banshan, Majuangou, Huabaogou, Xiashagou, Danangou and Dongyaozitou), are suggested to span a time range of about 0.8-2.0 Ma. The combination of our new and previously published magnetostratigraphy has significantly refined the chronology of the terrestrial Nihewan Formation and faunas.     

圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药

采用环境友好的圆盘固相萃取新技术富集水体中有机氯农药和有机磷农药,分别用微池电子捕获检测器(μECD)和火焰光度检测器(FPD)气相色谱法检测,实现了水中有机氯和有机磷农药残留物的测定。结果表明,16种有机氯农药的平均回收率为64.7%~102%,精密度(RSD,n=6)为2.9%~15%;13种有机磷农药的平均回收率为65.9%~104%,精密度(RSD,n=6)为1.7%~17%。方法快速、灵敏、低污染,可用于水体中多种有机氯农药和有机磷农药的残留分析。     

气相色谱法测定地下水中六六六结果的不确定度评定

依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。     

火试金法测定铜精矿中金含量结果的不确定度评定

对火试金法测定铜精矿中金含量的结果进行不确定度评定。分析了铜精矿样品称量、铜精矿样品的不均匀性和配料处理,以及金粒称量等因素对金含量测量结果不确定度的影响,并得出火试金法测量铜精矿中金含量的扩展不确定度。     

Sulfide-driven arsenic mobilization from arsenopyrite and black shale pyrite

We examined the hypothesis that sulfide drives arsenic mobilization from pyritic black shale by a sulfide-arsenide exchange and oxidation reaction in which sulfide replaces arsenic in arsenopyrite forming pyrite, and arsenide (As−1) is concurrently oxidized to soluble arsenite (As+3). This hypothesis was tested in a series of sulfide-arsenide exchange experiments with arsenopyrite (FeAsS), homogenized black shale from the Newark Basin (Lockatong formation), and pyrite isolated from Newark Basin black shale incubated under oxic (21% O₂), hypoxic (2% O₂, 98% N₂), and anoxic (5% H₂, 95% N₂) conditions. The oxidation state of arsenic in Newark Basin black shale pyrite was determined using X-ray absorption-near edge structure spectroscopy (XANES). Incubation results show that sulfide (1 mM initial concentration) increases arsenic mobilization to the dissolved phase from all three solids under oxic and hypoxic, but not anoxic conditions. Indeed under oxic and hypoxic conditions, the presence of sulfide resulted in the mobilization in 48 h of 13-16 times more arsenic from arsenopyrite and 6-11 times more arsenic from isolated black shale pyrite than in sulfide-free controls. XANES results show that arsenic in Newark Basin black shale pyrite has the same oxidation state as that in FeAsS (−1) and thus extend the sulfide-arsenide exchange mechanism of arsenic mobilization to sedimentary rock, black shale pyrite. Biologically active incubations of whole black shale and its resident microorganisms under sulfate reducing conditions resulted in sevenfold higher mobilization of soluble arsenic than sterile controls. Taken together, our results indicate that sulfide-driven arsenic mobilization would be most important under conditions of redox disequilibrium, such as when sulfate-reducing bacteria release sulfide into oxic groundwater, and that microbial sulfide production is expected to enhance arsenic mobilization in sedimentary rock aquifers with major pyrite-bearing, black shale formations.     

祁连山不同植被类型对积雪消融的影响

为研究祁连山植被对积雪消融的影响, 利用人工调查积雪深度逐日变化量和积雪盖度变化, 并结合空气雪面感热通量(SH)观测, 对祁连山水源林生态站排露沟流域海拔2 600～2 700 m青海云杉林、灌丛林、林缘、阳坡草地在2003-2007年的积雪消融进行了研究, 每年的观测从10月降雪开始到翌年5月积雪消融完结束, 共获取数据134 400个. 结果表明: 当SH<0时, 积雪消融停止;当SH>0时, 积雪消融开始;植被可以减缓积雪消融速率, 有植被的地方消融速率减慢, 反之则加快;不同植被消融速率大小顺序为草地>林缘>灌木林>乔木林;同一植被、不同坡向消融速率不同, 半阳坡云杉林＞半阴坡云杉林＞阴坡云杉林. 积雪含水率随气温升高而增大, 1月融化积雪占整个积雪的5%, 2月增大到28%, 大量积雪在3月消融, 占55%. 从坡位看, 下坡消融速率最大;在一个垂直带上, 低海拔消融速率大于高海拔. 温度是影响积雪消融的主要因子, 积雪消融速率随温度升高而增大, 反之则减小.     

ADCM测流数据后处理探索

声学多普勒剖面测流(ADCP-Acoustic Doppler Current Profilers)是当今水文领域进行流量测验的新技术.声学多普勒流速仪ADCM(ADCM-Acoustic Doppler Current Meter)用于对水文站点的流量测验,可以实现流速信息采集的自动化,但对收集到信息的后处理提出了新的要求.本文旨在探索采用自主开发程序的方式,建立声学多普勒流速仪速度、断面特性、水位等数据序列的数学模型,进而实现ADCM洲流数据快速后处理.     

真空堆载联合预压加固软基中孔隙水压力消散规律研究

通过实测资料分析了真空堆载联合预压中不同深度的孔隙水压力、超孔隙水压力、相对超孔隙水压力随时间的变化规律,并对孔压变化的原因进行了微观解释。结果表明:(1)处理区外侧,孔压变化主要由地下水位下降引起,受真空影响较小;(2)在处理区内,孔压变化受真空负压、土体渗透性和堆载荷载的影响。真空作用下的渗流是孔压消散的主要方式,土体渗透性的强弱影响着孔压消散的速度,消散的孔压转化成有效应力,促使土颗粒移动,对孔隙水产生挤压,这使孔压消散呈脉动性特征。     

GPS卫星反射信号增强技术研究

本文根据GPS卫星反射信号在海洋参数测量、无源雷达目标探测以及大地测绘中的应用,从天线接收、信号处理运算和多路径信号抵消角度,详细地研究了GPS卫星反射信号增强技术,给出了相应天线和电路结构及信号处理方法,并进行了计算机仿真,结果表明所提出的技术能增强GPS卫星反射信号。     

中国对虾(Penaeus chinensis)四倍体诱导研究

利用光控和行为学原理,控制中国对虾在适当时候产卵,在一定的时刻以温度休克和细胞松弛素的方法诱导受精卵发育成为四倍体。作者发展了对虾染色体制备技术,以中肠和触角腺、精巢为材料,从后期幼体直到8～9cm左右次成虾均获得较好的分裂中相。染色体倍性检测结果表明,最好的四倍体诱导成功率达66.7％。共获得10cm左右的实验对虾几千尾。初步观察表明,四倍体中国对虾具有一定的生长优势。