Determination of the regional deformation rates of Shanghai and Kashima VLBI stations based on ITRF97

The vertical deformation rates (VDRs) and horizontal deformation rates (HDRs) of Shanghai VLBI station in China and Kashima and Kashima34 VLBI stations in Japan were re-analysed using the baseline length change rates from Shanghai to 13 global VLBI stations, and from Kashima to 27 stations and from Kashima34 to 12 stations, based on the NASA VLBI global solution glb1123 (Ma, 1999). The velocity vectors of the global VLBI stations were referred to the ITRF97 reference frame, and the Eulerian vectors of different models of plate motion were used for comparative solutions. The VDR of Shanghai station is estimated to be −1.91±0.56 mm/yr, and those of Kashima and Kashima34 stations, −3.72±0.74mm/yr and −8.81±0.84mm/yr, respectively. The difference between the last two was verified by further analysis. Similar estimates were also made for the Kokee, Kauai and MK_VLBA VLBI stations in mid-Pacific.     

Morphological characters of the two-ribbon flare of 1981 May 13 and their explanation

We give a summary of the morphology of the two-ribbon flare of 1981 May 13. One striking feature is that the Ha flare began at about 0338' UT and the double-ribbon structure was formed about 0346, $\text{before}$ the impulsive phase of the radio 3 cm burst at 04 11 UT. The 3 cm radio burst flux beginning at 03 33 UT showed only slow, stepwise increases lasting half an hour until the impulsive phase and this type of increase is usually regarded to be a typical thermal process. Each step in the radio flux corresponded to a variation in the Ha flare, showing that the radio and Hα emissions during this period came from the same thermal source. In this paper, we explain this behaviour in terms of Hyder's model: we think that the magnetic trough supporting the solar prominence rose for some reason, causing the prominence matter (the dark filaments) to fall along the magnetic lines and to hit the chromosphere and trigger off the flare. We give rough estimates of the energy density, the height of prominence and the infall matter at the different radio increments. We also give a qualitative explanation for the appearances of the single-peak structure in the radio burst at 0411 and the covering of the sunspot shortly after at 04 13 and propose several possible mechanisms.     

Comparison of methods to model the gravitational gradients from topographic data bases

A number of methods have been developed over the last few decades to model the gravitational gradients using digital elevation data. All methods are based on second-order derivatives of the Newtonian mass integral for the gravitational potential. Foremost are algorithms that divide the topographic masses into prisms or more general polyhedra and sum the corresponding gradient contributions. Other methods are designed for computational speed and make use of the fast Fourier transform (FFT), require a regular rectangular grid of data, and yield gradients on the entire grid, but only at constant altitude. We add to these the ordinary numerical integration (in horizontal coordinates) of the gradient integrals. In total we compare two prism, two FFT and two ordinary numerical integration methods using 1" elevation data in two topographic regimes (rough and moderate terrain). Prism methods depend on the type of finite elements that are generated with the elevation data; in particular, alternative triangulations can yield significant differences in the gradients (up to tens of Eötvös). The FFT methods depend on a series development of the topographic heights, requiring terms up to 14th order in rough terrain; and, one popular method has significant bias errors (e.g. 13 Eötvös in the vertical–vertical gradient) embedded in its practical realization. The straightforward numerical integrations, whether on a rectangular or triangulated grid, yield sub-Eötvös differences in the gradients when compared to the other methods (except near the edges of the integration area) and they are as efficient computationally as the finite element methods.     

Sedimentary cycles of trace elements in Salawusu River Valley since 150 ka BP

The paper makes some analyses on 11 trace elements in the Milanggouwan stratigraphical section in the Salawusu River valley, which is regarded as a prototype geology-palaeoclimate record since 150 ka BP. The results show that the content and variation of trace elements has experienced remarkably regular changes in the pace with coarse and fine sedimentary cycles of palaeo-aeolian sands to its overlying fluvio-lacustrine facies or/and palaeosols. The trace elements with chemical properties of relatively active (V, Sr, Cu, Ni, As) and relatively stable (P, Pb, Rb, Mn, Nb, Zr) are a manifestation of the corresponding 27 changeable cycles between peak and valley values, appearing a multi-fiuctuational process line of relative gathering and migration since then. The low numerical value distribution of these two types of trace elements in the aeolian sand facies represents erosion and accumulation under wind force during the cold-dry climate. Whereas their enrichments in both fluvio-lacustrine facies and palaeosols are related to the valley’s special low-lying physiognomic position between the Ordos Plateau and the Loess Plateau under the warm and humid climate conditions. The above relatively migrated and gathered change of the trace elements is the result of 27 climatic cycles of cold-dry and warm-humid, which is probably caused by repeated alternations of winter monsoon and summer monsoon in the Mu Us Sandy Land influenced by the climate vicissitudes in northern hemisphere during glacial and interglacial periods since 150 ka BP.     

Dynamic processes of a simple linear dune—a study in the Taklimakan Sand Sea, China

Samples of dune sands, surveys of the morphology and field measurements of wind velocity and direction of a simple linear dune in Taklimakan Sand Sea show that the airflow and sand flux vary with the change of wind direction on the dune surface. Decrease of the airflow stress on the lee flank does not result in much decrease of the sand flux because of the low threshold shear velocities and the airflow conditions. There are no significant relations between the sand flux on the lee flank and the angle of incidence of the airflow. The low threshold shear velocities and the maintenance of the sand flux at the lee flank are the main mechanisms keeping the linear shape of the dunes. Measurements of the sand flux shows that it reaches a maximum on the crest of the dune. The grain size of the transported sands has some differences compared to that of the dune surface. The sands transported are finer than that on the dune surface, but better sorted under the influence of the medium to low wind activity. The field experiment results exhibit that it is possible for the dunes to be shaped as linear dunes during the processes of accumulation and elongation.     

草簇状石墨烯片限域Pd纳米粒子及其催化应用(英文)

通过氨基离子液体改性石墨烯,并将其固载于堇青石表面,作为负载型Pd催化剂的载体.所制备的Pd催化剂经加氢老化后,表面石墨烯呈草簇状结构,将Pd纳米粒子限域于片层内,有效防止了Pd的流失和团聚.在重要的工业反应对羧基苯甲醛(4-CBA)加氢中,此结构催化剂与传统的钯碳催化剂相比,表现出很好的稳定性     

几种空气质量预报方法的预报效果对比分析

目前应用于我国各个城市空气质量预报业务的预报方法主要有三种 :数值模式预报、统计预报和综合经验预报。这几种预报方法都有其各自的优势 ,同时也存在一些不足。应用以上方法对天津市市区进行空气质量业务预报 ,通过实测资料与预报结果进行对比分析 ,给出这几种方法在天津市区空气质量预报中的预报效果客观评价。     

用远场辐射场反演云闪放电参数

用地面电磁场遥感闪电放电参数无论是在实际应用还是理论研究中都具有重要意义。文中基于电流传输线模式 ,提出了一种用单站远场VLF/LF辐射场反演云内放电参数的简便方法。当传输线电流从底部传播到顶部的时间只有几微秒时 ,整个传输线的VLF/LF辐射可以近似成偶极子辐射 ,即远场辐射场与电流的时间变化率和传输线长度的乘积成正比。因此 ,对远场辐射场做时间积分就能获得完整的电流矩波形 (上升沿有所加宽 ) ,而且传输线模式中的重要参数 ,电流从底部传播到顶端经历的时间 ,也可以近似地用辐射场时间积分幅度与辐射场幅度之比来估计。这一方法具有估计云闪双极性大脉冲辐射过程的放电参数的潜力。     

可解释性长短期记忆模型用于预测湖泊总磷浓度变化

对湖泊总磷的变化预测和来源识别对水资源调度和流域生态治理有着重要的意义,然而复杂的生化反应和水动力条件导致的非平稳性给湖泊总磷浓度的准确预测带来极大的困难。为克服这一挑战,本文引入了基于加权回归的季节趋势分解(seasonal and trend decomposition using Loess,STL)技术和夏普利加法(SHapley additive exPlanations,SHAP)结合长短期记忆网络(long short-term memory neural network,LSTM)和门控循环单元(gated recurrent unit,GRU)构建了一个可解释的预测框架,以增强对湖泊总磷浓度演变的预测并提高其可解释性。研究表明:(1)在骆马湖总磷浓度的预测中,该框架拥有较好的预报精度(R²=0.878),优于LSTM和卷积长短期记忆模型(convolutional neural networks and long short term memory network,CNN-LSTM)。当预测时间步长增加到8 h时,该框架有效提高了总磷浓度的预测精度,平均相对误差和均方根误差分别降低了47.1%和33.3%。从预测趋势来看,骆马湖在汛期的总磷平均浓度为0.158 mg/L,相较于非汛期的平均浓度,增加了202.1%。(2)运河来水是骆马湖总磷浓度最重要的影响因素,贡献权重为60.0%,并且不同断面(三湾、三场)的污染源受水动力、气象等因素的影响存在显著的时空差异。本文凸显了神经网络模型在预警水体污染方面的可实施性,并且为提高传统神经网络的学习能力和可解释性的开发与验证提供了重要方向。     

太湖表层沉积物多环芳烃的空间分布、来源及其风险

随着太湖流域社会与经济的发展,多环芳烃(PAHs)在各种环境介质中逐渐累积,污染日益严重,可能对太湖生态环境及周边人体健康构成威胁。为探究太湖沉积物PAHs的来源及生态风险,于2021年12月在太湖采集30个表层沉积物样品,利用气相色谱-质谱联用仪(GC-MS)检测样品中16种PAHs含量;利用受体模型和苯并[a]芘(BaP)毒性当量法进行来源解析及生态风险评估,并将各来源贡献与毒性当量浓度相结合,量化源风险。结果表明,太湖表层沉积物中16种PAHs总含量介于124~592 ng/g之间,平均值为294 ng/g,中值为279 ng/g;高环多环芳烃(HMW PAHs)为主要组分,占∑PAHs的67%。高含量区域位于竺山湾、梅梁湾、贡湖湾和西太湖,与国内外其他湖泊沉积物相比,太湖沉积物PAHs含量处于较低水平。源解析的结果表明,太湖表层沉积物中PAHs交通排放源贡献率为29.1%、煤炭燃烧源贡献率为26.7%、生物质燃烧源贡献率为28.7%、石油源贡献率为15.6%。生态风险评价结果表明,交通排放源、生物质燃烧源、煤炭燃烧源和石油源的BaP毒性当量含量(TEQ_BaP)均值分别为19.34、17.81、16.33和9.1 ng/g,均小于70 ng/g,几乎处于无风险水平。西太湖、贡湖湾和梅梁湾的部分区域ΣTEQ_BaP大于70 ng/g属于潜在风险区,具有一定潜在毒性。在后续的污染治理中应重点关注太湖西北部地区污染物的排放。本研究可为沉积物中PAHs污染的研究提供数据支撑,为地方政府精准、高效地管控PAHs污染提供理论依据。