Review on Montane Forest Eco-hydrology in Arid Area

Since the forest eco-hydrology of arid area shows a well sensitivity of the global climate change, the relationship between forest and water and the hydrological function has attracted the attention of academic communites and management departments. This paper expounds the research progress in arid mountain forest eco-hydrology, and analyses the formation and stable mechanism of forest patch pattern, the relationship between forest and water yield and the response of forest eco-hydrology to climate change from three aspects: Forest spatial pattern, hydrological process and its response to climate change. In addition, combined with the current research progress, the research emphases in the future are put forward: Strengthening the research on the coupling of vegetation pattern and hydrological process; solving the scale problem by using remote sensing technique and model; enhancing the understanding towards the hydrological function of forest; determining the suitable forest scale which can balance the relationship of ecology and hydrological effect.     

安徽省地质灾害气象预报预警模型研究

通过对基于地质环境信息平台的地质灾害气象预报预警模型构建进行了探讨。拟在先期已具备的地质灾害预警分区、地质灾害易发分区基础上,以地质灾害"易发度"、预报降雨量、有效降雨量为因子,采用logistic回归模型确定各个评价单元的预警等级,经插值计算、图斑合并,实现地质灾害气象风险预警。     

Regional debris flow susceptibility analysis based on principal component analysis and self-organizing map: a case study in Southwest China

A method was developed to analyze the susceptibilities of 541 regional basins affected by debris flows at the Wudongde Dam site in southwest China. Determining susceptibility requires information on source material quantity and occurrence frequency. However, the large number of debris flows can hinder the individual field investigation in a each small basin. Factors that may trigger debris flows can be identified using remotely sensed interpretation information. Susceptibility analysis can then be conducted based on these factors. In this study, SPOT5 satellite imagery, digital elevation models (DEM), a lithology distribution map, and rainfall monitoring data were used to identify 12 debris flow trigger factors: basin relief ratio, slope gradient in the initiation zone, drainage density, downslope curvature of the main channel, vegetation coverage, main channel aspect, topographic wetness index, Melton’s ruggedness number, lithology, annual rainfall, form factor, and cross-slope curvature of the transportation zone. Principal component analysis was used to obtain the eight principal components of these factors that contribute to susceptibility results. Then, a self-organizing map method was adopted to analyze the principal components, which resulted in a debris flow susceptibility classification. Field validation of 26 debris flow basins was used to evaluate the errors of the susceptibility classification, as well as assess the causes of such errors. The study found that principle component analysis and self-organizing map methodologies are good predictors of basin susceptibility to debris flows.     

长江河口北槽河道悬沙絮团特性及其影响因素研究

利用多种先进室内外测量仪器进行河口现场观测和室内电镜扫描获得相关资料,对长江河口北槽河道细颗粒泥沙絮凝的水沙环境、絮团的微观形态结构、絮团的粒径组成及其主要影响因素进行了综合分析和讨论。结果表明,北槽河道具有非常适宜细颗粒泥沙絮凝的潮流、盐度、含沙量和悬沙颗粒粒径等基本环境条件。北槽河道悬沙絮团形态多样,主要包括松散状絮团、蜂窝状絮团和密实状絮团。絮团主要由细粉砂和黏土类细颗粒泥沙组成,表面多粗糙不平,结构或密或疏。絮团粒径变化与潮周期动力过程密切相关,具有周期性变化特征。涨、落憩时絮团粒径较大,涨、落急时絮团粒径较小。絮团粒径涨憩大于落憩,小潮大于大潮。垂向上,絮团粒径由表层至底层逐渐增大。周期性潮流流速对北槽河道悬沙絮团粒径变化起到了控制作用。北槽细颗粒泥沙絮凝作用,是导致疏浚航道发生回淤的主要原因之一。     

近60年来长江河口河势变化及其对水动力和盐水入侵的影响I.河势变化

河势是影响河口水动力和盐水入侵基本因子。本文利用20世纪50和70年代长江河口海图,数值化岸线和水深,结合2012年长江河口实测水深资料,分析长江河口自50年代以来的河势变化。长江河口为分汊河口,50年代仅为二级分汊,至70年代才形成三级分汊,四口入海的河势格局。70年代相比于50年代,北支淤浅严重,其上、中、下段容积变化分别为-64.13×106、-306.60×106和-639.27×106 m3,对应的变化率分别为-16.30%、-22.74%和-25.69%,均显著减小;南支的上、中、下段容积变化分别为-28.61×106、-35.69×106和126.43×106 m3,相应的变化率分别为-1.30%、-2.12%和4.36%;北港由于崇明浅滩和横沙浅滩的淤浅,下段容积明显减小,其上段和下段容积变化分别为109.21×106和-797.14×106 m3,对应的变化率分别为5.01%和-15.25%;南港上段由于河道淤浅容积减小,下段北由于铜沙浅滩被冲开形成北槽,导致水深变深、容积增加,其上段、下段北和下段南容积变化分别为-238.95×106、203.58×106和153.34×106 m3,对应的变化率分别为-8.96%、6.85%和3.26%。2012年相比于70年代,北支由于大量淤浅和围垦容积大幅减小,其上、中、下段容积变化分别为-199.06×106、-504.61×106和-654.12×106 m3,对应的变化率分别为-60.45%、-48.44%和-35.38%;南支的上、中、下段容积变化分别为92.34×106、193.01×106和-163.62×106 m3,相应的变化率分别为4.24%、11.73%和-5.40%;北港上段青草沙水库的围垦和下段横沙东滩的围垦造成面积和容积减小,其上段和下段容积变化分别为-154.64×106和-511.79×106 m3,对应的变化率分别为-6.75%和-11.55%;南港由于上段河道刷深而下段九段沙以及南汇边滩淤浅、围垦,导致其容积上段增加,下段减小,上段、下段北和下段南容积变化分别为136.39×106、-658.28×106和-1266.11×106 m3,对应的变化率分别为5.62%、-20.73%和-26.06%。     

Study of Influence of Regional Geodynamic Background on Strata Behaviors in China's Tongxin Mine

Strata behaviors are mainly affected by regional geodynamic background. The influence of rock mass stress and energy distribution on strata behaviors in the Tongxin mine is studied in terms of regional tectonic movement, seismic activity and tectonic stress field. The results show that the extrusion lifting movement of Kouquan fault adjacent to the Tongxin mine results in the stress concentration in the rock of the Carboniferous coal bed and accumulation of a large amount of elastic energy and forms structural background of Tongxin mine. Due to various seismic activities in the mine area, the strain energy is known to reach much higher levels, up to 0.5×10⁸ J^1/2. Since the stratigraphic structure is sensitive to the mining operation, the strain energy could cause strong strata behaviors. A special geological structure model of the Tongxin mine is established based on the geodynamic division method. The distribution of regional structure stress field is determined by the rock mass stress analysis system. Based on this model, Tongxin mine is divided into five areas with high stress, eight areas with low stress and eight areas with gradient stress. The strong strata behaviors mostly occur in high stress areas. These results could provide guidance to predict the strength of regional or mine pressure and control strata behavior in different areas.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

The August 27, 2014, rock avalanche and related impulse water waves in Fuquan,Guizhou, China

At about 8:30 p.m. on 27 August 2014, a catastrophic rock avalanche suddenly occurred in Fuquan, Yunnan, southwestern China. This landslide and related impulse water waves destroyed two villages and killed 23 persons. The impulse waves occurred after initiation of the landslide, caused by the main part of the slide mass rapidly plunging into a water-filled quarry below the source area. The wave, comprising muddy water and rock debris, impacted the opposite slope of the quarry on the western side of the runout path and washed away three homes in Xinwan village. Part of the displaced material traveled a horizontal distance of about 40 m from its source and destroyed the village of Xiaoba. To provide information for potential landslide hazard zonation in this area, a combined landslide–wave simulation was undertaken. A dynamic landslide analysis (DAN-W) model is used to simulate the landslide propagation before entering the quarry, while Fluent (Ansys Inc., USA) is used to simulate the impulse wave generation and propagation. Output data from the DAN-W simulation are used as input parameters for wave modeling, and there is good agreement between the observed and simulated results of the landslide propagation. Notably, the locations affected by recordable waves according to the simulation correspond to those recorded by field investigation.     

五硼酸铷溶液的物化性质及物种分布

碳酸铷、硼酸化学计量比混合,蒸发溶液,直至五硼酸铷RbB5O8·4H2O晶体析出。经粉末X射线衍射（XRD）、拉曼光谱（Raman spectroscopy）、热重/微商热重/差示扫描量热（TG/DTG/DSC）、原子吸收光谱等实验方法,确定其化学组成及结构。298.15、333.15K时测量溶液的物理化学性质（密度、电导、pH）,并与经验方程进行拟合,研究五硼酸铷溶液的物化性质随浓度、温度的变化规律。根据文献报道的平衡常数,实验测量的pH数据,采用牛顿迭代法进一步研究五硼酸铷溶液中主要存在的硼酸根离子对类型、含量以及物种的形成。