Influence of coastal wind on surface ozone and nitrogen oxides in suburban Shanghai

Surface ozone, NO, NO₂, and NO _x were measured at a coastal site (Shihua) and a nearby inland site (Zhujing) in suburban Shanghai for the whole year of 2009. More days with ozone pollution in a longer time range were observed at the coastal site than the inland site. The diurnal variations of NO _x concentrations were obviously higher at Zhujing station, while those of ozone concentrations were higher at Shihua station, indicating their different air pollution conditions. Coastal wind has significant influence on the levels and characteristics of the air pollutants. The ozone concentrations during maritime winds (MW) were much higher than those during continental winds (CW) at each of the site, while the NO and NO₂ concentrations were both opposite. The ozone concentrations at Shihua station were much higher than those at Zhujing station, while the NO and NO₂ concentrations were both opposite. The ozone concentrations at both of the two sites showed a distinct “weekend effects” and “weekdays effects” patterns during CW and MW, respectively. Correlation analysis of the pollutants showed that, the compounds during MW were more age than those during CW, and the compounds at Shihua were more age than those at Zhujing. The air pollutions at both of the two sites are mainly associated with the pollutants emitted in this region instead of long range transport.     

年代际气候变率问题的研究

对年代际气候变率的研究工作和主要结果作了综合评述，并对该领域的研究前景作了一定的阐述。     

对流层氮氧化物光化学转化特征研究

应用大气光化学模式研究了日间影响NOx光化学转化率的主要物理化学因子.探讨了在不同NMHC/NOx比值时,NOx光化学特征及其转化产物的变化规律.结果表明,影响NOx转化率的主要因子是阳光辐射强度和NMHC/NOx比值.但在NMHC/NOx比值很低时,光强的增加并不能显著提高NOx转化率.温度和初始臭氧浓度对NOx转化率的影响次之.相对湿度对NOx转化率的影响较小.在不同NMHC/NOx比值下,NOx转化特征和产物有很大区别.NMHC/NOx比值高时,产物中PAN＞HNO3.NMHC/NOx比值中(低)时,产物主要是HNO3,PAN等有机氮不到10%(1%).最后初步比较了模拟和观测的NOy组成.     

湿位涡守恒条件下西南涡的发展

运用高分辨率数值预报模式 (HIRLAM)模拟了一次中国西南地区在多种活跃天气系统影响下 ,西南涡的发展过程。分析了东亚季风、青藏高压、地形等多种尺度与不同高低空环流形势配合以及在湿位涡守恒条件下对流发展时 ,潜热及不稳定能量的释放 ,对中尺度涡旋和强对流发生发展的作用 ,探讨了西南涡和局地降水增强与消亡的成因与理论 ,并具有实用意义     

三维地闪监测数据分析与校验

选取福建省2015年三维系统地闪资料,采用同期雷电定位系统(ADTD)资料对其时空分布特征进行分析,利用雷电流峰值记录仪数据对2套系统地闪探测效率和定位误差校验,同时结合IEEE工作组和电力行业推荐的概率公式对三维系统地闪雷电流分布特征进行分析。结果表明:(1)2套系统监测到全省地闪密度空间分布趋势比较一致,在三明西南部地区及福州西部零星地区,三维系统地闪密度更低。(2)2套系统地闪频次年变化和日变化均呈单峰变化特征,但年变化中的10—12月,以及日变化中的09:00—12:00,三维系统监测到地闪频次更少。(3)三维系统地闪回击探测效率为40%,平均定位误差为2.75km。(4)在0~50kA区间,相比于负极性地闪,三维系统正极性地闪雷电流幅值分布更加集中,在26~84kA区间三维地闪雷电流幅值相比于IEEE推荐值和规程推荐值偏大。     

Long-term changes (1980–2003) in total ozone time series over Northern Hemisphere midlatitudes

Long-term changes in total ozone time series for Arosa, Belsk, Boulder and Sapporo stations are examined. For each station we analyze time series of the following statistical characteristics of the distribution of daily ozone data: seasonal mean, standard deviation, maximum and minimum of total daily ozone values for all seasons. The iterative statistical model is proposed to estimate trends and long-term changes in the statistical distribution of the daily total ozone data. The trends are calculated for the period 1980–2003. We observe lessening of negative trends in the seasonal means as compared to those calculated by WMO for 1980–2000. We discuss a possibility of a change of the distribution shape of ozone daily data using the Kolmogorov-Smirnov test and comparing trend values in the seasonal mean, standard deviation, maximum and minimum time series for the selected stations and seasons. The distribution shift toward lower values without a change in the distribution shape is suggested with the following exceptions: the spreading of the distribution toward lower values for Belsk during winter and no decisive result for Sapporo and Boulder in summer.     

震后快速钻探:历史、现状与未来

大地震发生后立即在断层带上进行钻探可以帮助我们获取更多的地震信息,尤其是可获得决定断层动态破裂的摩擦水平和强度,观测断层的愈合过程及可能触发余震的应力变化,并可获取控制破裂过程的重要的物理和化学属性。在2008年11月由国际大陆科学钻探项目（ICDP）和南加州地震中心（SCEC）联合在日本东京举办的为期3天的“震后快速钻探：历史、现状与未来”研讨会上,     

地震应急现场网络传输方案的选择

地震现场的通讯环境极为复杂,公共的网络接入模式在地震时往往很难保证现场与后方指挥中心之间的实时文件传输和视频通信。本文根据地震带来的破坏程度的不同,针对地震现场的具体通信情况,以及地震应急工作中现场网络通信的需求,提出多项确保地震现场局域网络和后方指挥中心之间通信畅通的解决方案。     

地震重现时间间隔概率分布函数选择的必要条件

地震重现时间间隔的分布规律研究对于短期和中长期地震预测、地震灾害预防和救援有着重要的理论和实际意义,如果能够确定地震重现时间间隔的概率密度函数(probability density function-pdf),则在统计学的意义上,能够对地震再次发生的概率进行评估和预测.在地震重现时间间隔的pdf研究中,一个核心问题是如何判断某个pdf是否能够有效地描述地震重现时间间隔分布特征.作者提出利用特征地震重现时间间隔数据的变化系数(COV)与其偏度(S),变化系数与其峰度(K)的相关关系对所选择的pdf的适用性进行判别.研究表明,常用的一些概率密度函数(对数正态分布、gamma分布、Weibull分布和指数分布)并不合适作为描述特征地震的重现时间间隔分布的数学模型.     

Structure refinement of astrophyllite

The crystal structure of astrophyllite K₂Na(Fe, Mn, Mg,□)₇[Ti₂(Si₄O₁₂)₂|O₃](OH, F)₄ has been refined. The dimensions of the triclinic unit cell are: a = 0.5359(2) nm,b = 1.1614(4) nm, c = 1.1861(4) nm, α= 113.16(2)°, β= 103.04(2)°,γ= 94.56(2)°,V = 0.6495(5) nm³, Z= 1, space group P1, R=0.057 for 5308 reflections |F_o|>3σ|F_o|. According to structural and compositional differences the monoclinic astrophyllite K₂NaNa(Fe, Mn)₄Mg₂Ti2[Si₄O₁₂]₂(OH)₄(OH, F)₂ and astrophyllite should be considered as two different mineral species. Astrophyllite, monoclinic astrophyllite, bafertisite and lamprophyllite contain heteropolyhedral sheets which topologically are related with Si, O sheets of mica where one or several SiO₄ tetrahedra are replaced by TiO _n polyhedra. Therefore this heterophyllotitanosilicate series represents a kind of functional substitution in inorganic crystals.