澳大利亚中部Alice Spring红色表土磁学特征分析

炎热干旱的澳大利亚中部是现代正在形成红色地表的区域。围绕中部Alice Spring地区采集了一系列红色地表样品。这些红色样品按照岩性大致可以分为三类: 砂土、沙丘砂和岩石。通过对这些样品详细的磁学测量, 发现这三类样品存在明显磁学特征差异, 红色砂土和沙丘砂样品磁化率较岩石样品高出许多(砂土和沙丘砂磁化率均值为93.82×10-8m3/kg), 红色岩石样品磁化率值最低(均值为23.2×10-8m3/kg); 三者主要磁性矿物也不尽相同; 磁颗粒均以超顺磁(SP)颗粒为主, 而单畴(SD)颗粒含量少。研究区百分比频率磁化率χfd % 均值为8.28 %, 较黄土高原西部表土(兰州为3.5 %)高出许多。该区现代年降水量约300mm, 比兰州(约330mm)还低, 成土导致百分比频率磁化率增高却比兰州明显高出几倍。这可能反映了黄土高原表土频率磁化率增高与降水量密切相关; 而在澳洲中部可能与持续高温成土条件和作用的时间存在更密切的关系。澳洲中部不论岩石还是表土均以红色为主。磁学实验表明, 砂土和沙丘砂样品均以磁铁矿为主, 三类样品普遍含一定量磁赤铁矿和赤铁矿的贡献, 与地表红色外貌相符。说明澳洲红色地表过程很可能是黑色磁铁矿颗粒表面被长期氧化条件下形成的红色磁赤铁矿/赤铁矿所包裹的现象, 使得澳洲中部广大地区岩石露头和地表沉积物, 普遍形成一层红色染色层。     

Speciation of gold in hydrosulphide-rich ore-forming fluids: Insights from first-principles molecular dynamics simulations

To shed light on gold speciation in sulfur-containing ore-forming fluids, we perform first principles molecular dynamics (FPMD) simulations to investigate gold-hydrosulphide complexing under representative geological conditions. With this advanced technique, the electronic structures of solutes and solvents are calculated with density functional theory and the thermal motions are sampled with molecular dynamics. The molecular structures, solvated structures and stabilities of possible complexes are characterized in detail and the following insights have been gained. (1) The previously hypothesized species Au(HS)(H₂S)₃ and Au(HS) are found unstable under ore-forming conditions. Au(HS)(H₂S)₃ would dissociate to LAu(HS) (L = H₂S or H₂O) and free H₂S molecules spontaneously. Au(HS) is highly reactive and tends to capture a second ligand to form a double-coordinated complex. (2) In the thin vapor-like phases of low pressures, the stable complexes include Au(HS)(H₂O), Au(HS)(H₂S) and Au(HS)₂⁻ and their relative stability is Au(HS)₂⁻ > Au(HS)(H₂S) > Au(HS)(H₂O). In dense aqueous phases of high pressures, Au(HS)(H₂S) would spontaneously deprotonate to Au(HS)₂⁻ and thus Au(HS)(H₂O) and Au(HS)₂⁻ are the stable forms. All of these complexes can retain to the upper-limit of ore-forming temperatures. (3) The gold ions in the complexes do not favor coordinating more molecules and therefore the solvations happen mainly through H-bonding interactions between the ligands and environmental waters. H-bonds are found in vapor, liquid, and dense supercritical phases, whereas in the thin supercritical phase the hydration is very weak. These results provide quantitative and microscopic basis for understanding the speciation of gold in hydrothermal fluids.     

河北省丰宁县茶棚银矿地质、地球物理特征及找矿意义

茶棚银矿位于河北省北部坝上草原向山区过渡地带,风成砂覆盖严重,示矿标志不明显,地表找矿难度大;地表矿体断续出露,而深部银矿体主要以隐伏矿体的形式赋存于近南北向展布的构造破碎带中,数量明显增多、品位变富、厚度变大;在这种特殊的景观地质特征下,利用激电中梯扫面,可发现厚覆盖状态下构造矿化蚀变带,利用EH4连续导电率测量可厘定矿化蚀变带的规模、产状并可提供隐爆角砾岩体等深部控矿地质信息,利用可控源音频大地电磁测深的中低阻陡变带和中阻带,特别是陡变带中的转折部位（形态呈耳状部位）可具体定位银矿体的赋存空间。     

适应气候变化的国际行动和农业措施研究进展

针对气候变暖采取稳健的适应措施已成为国际社会共识。该文综合了当前适应气候变化的国际谈判进展及已有的农业适应气候变化措施,指出适应资金严重不足,技术研发、应用与转让难以实施,以及适应气候变化行动实施能力的不足严重制约着适应气候变化行动的有效实施;关于农业适应气候变化的技术措施仍缺乏系统的理论研究与应用示范。在此基础上,提出了未来中国农业适应气候变化需要重点开展的研究任务,即农业气象灾变过程的新特点及其风险管理, 农业适应气候变化的大数据决策管理系统研发及适应气候变化的农业气候区划与减灾保产技术研究,以切实推进农业适应气候变化,为确保国家粮食安全与农业可持续发展提供支撑。     

强震前地震多重分形谱的异常及其物理解释：以乌什研究区为例

应用有关软件分析新疆乌针研究区地震活动时间分布的多重分形谱Ｄｑ－ｑ和ｆ（ａ）－ａ。发现两次６级强震发生前，多重分形谱发生显著变化。主要特征是对一定的ｑ区间奇异性强度因子ａ取值变宽，Ｄｑ－ｑ曲线变陡，ｆ（ａ）－ａ的左端点或右端点下降。     

Variability of East Asian Winter Monsoon in Quaternary Climatic Extremes in North China

In order to examine high-frequency variations of East Asian winter monsoon in Quaternary climatic extremes, two typical loess–paleosol sequences in the Chinese Loess Plateau were investigated. Sandy layers in the loess deposits, the “Upper sand” and “Lower sand” (layers L9 and L15, respectively), which represent a high-resolution record of paleomonsoon changes, have been sampled at intervals of 5–6 cm from sections at Luochuan and Xifeng. The grain size and magnetic susceptibility was measured for all samples. The grain-size results (a proxy of winter monsoon strength) indicate that the winter monsoon strength fluctuated on a millennial timescale during cold climatic extremes, with climatic events of a few hundred to a few thousand years. However, the winter monsoon was relatively stable during warm periods. The magnetic susceptibility signal (a proxy of summer monsoon intensity) is practically constant over the same period. This is tentatively explained by the assumption that the summer monsoon intensity was too low to be recorded in the magnetic susceptibility signal. The intensified winter monsoon events show periodicities in a range of 1000 to 2770 yr, with a dominant cycle of approximately 1450 yr. The detection of this oscillation in older glacial stages strongly suggests that it may be a pervasive cycle of the cold climatic phases of the Quaternary. Millennial-scale variations of the winter monsoon may be caused by instability of the westerly jet, which is determined by temperature differences between the polar and the equatorial regions.     

地壳岩石变形行为的转变及其温压条件

岩石脆延性转化 (brittle ductiletransition)和脆塑性转化 (brittle plastictransition)是不同的概念。脆延性转化指从岩石的局部变形破坏到宏观均匀流动变形的转化 ,它与宏观结构和力学行为的变化相关。脆塑性转化指脆性向晶体塑性变形的转化 ,它与力学行为和微观机制的变化相关。通过地壳中最主要的石英、长石的实验室和野外变形温压条件对比发现 ,达到相同的变形特征 ,在实验室和野外所需温压条件不同。建立变形机制图使解决这一矛盾成为可能。但受实验资料的限制 ,目前几种主要岩石的变形机制图还无法建立。因此 ,通过对实验与自然环境下变形特征及微观机制对比 ,找出两者温压条件的差别 ,就成为将实验研究结果外推解决实际地质问题的有效途径     

Distribution and controlling factors of phytoplankton assemblages in a semi-enclosed bay during spring and summer

The phytoplankton assemblages' patterns and their correlation to environmental factors were studied in Bohai Bay during spring and summer. Two zones, the northern (NWA) and southern (SWA) water area, were identified by cluster analysis based on their physical and chemical properties. Principal component analysis (PCA) showed that more phytoplankton species was found in the SWA with low nutrient concentration, while high phytoplankton abundance occurred in the NWA with high nutrient concentration. The seasonal variability in phytoplankton can be explained by water temperature, nutrient, and hydrodynamic conditions (includes mixing during spring and stratification during summer). Results of redundancy analysis (RDA) showed that silicate (SiO(4)) and soluble reactive phosphorus (SRP) were the most important environmental factors influencing the phytoplankton distribution during spring and summer, respectively. Hydrodynamics condition plays a key role in controlling variation of the environmental factors, which determined phytoplankton distribution in Bohai Bay.     

DNQ3型能见度仪故障分析及校准方法研究

为有效提高国家地面气象观测站能见度仪观测数据准确性和设备运行稳定性,对能见度仪开展日常维护、核查校准、数据质控和故障修复等工作显得尤为重要。该文通过对DNQ3型前向散射能见度仪硬件结构和基本工作原理的介绍,以及对一些典型故障进行分析,总结出能见度仪的检测维修流程,归纳了对应的故障解决措施,凝练出该型能见度仪的核查校准和疑误数据质控方法,为一线业务人员开展能见度仪常规维护、故障排查、运行监控等提供借鉴。     

长江口及济州岛邻近海域温、盐、密度的跃层现象

本文根据CTD观测资料,分析了研究海区的温、盐、密度跃层的分布与变化,讨论了逆温逆盐层的分布区域,并从跃层角度出发,分析了深层水的涌升,黄海冷水团的上边界以及台湾暖流在东海北部的影响范围。