Chromatographic study of formation conditions of rhombododecahedral diamond crystals

The results of chromatographic study of the formation of rhombododecahedral diamonds synthesized in the Fe-Ni-(Ti)-C system at 5.5–6.0 GPa and 1350–1450°C are presented, including crystals with rounded surfaces of the rhombododecahedron with parallel striation, which are morphological analogues of natural diamonds abundant at various kimberlite, lamproite, and placer deposits. Chromatography was performed at 150°C with mechanical breakup of diamonds. The stable release of methane when diamonds of habit {110} are crushed is established. It is concluded that the appearance of the habit rhombododecahedron may be related not only to the effect of temperature and pressure on crystal growth but also to reductive conditions of crystallization. At the same time, the appearance of significant amounts of hydrocarbons in the system probably results in stopping of the growth of faces {110} and {100} and, instead, formation of specific surfaces that are composed of microscopic accessories faced by planes {111}.     

Eclogites of the Late Cambrian–Early Ordovician North Kokchetav tectonic zone (northern Kazakhstan): structural position and petrology

We consider the structural position and petrology of eclogites in the North Kokchetav accretion-collision zone located north of the Kokchetav metamorphic belt formed by high- and ultrahigh-pressure rocks. In the Early Ordovician North Kokchetav tectonic zone, thin sheets of mylonite and diaphthoric gneisses with eclogites are tectonically conjugate with the volcanic and sedimentary rocks of the Stepnyak paleoisland-arc zone. Eclogites have been revealed at two sites of the North Kokchetav tectonic zone—Chaikino and Borovoe. The Chaikino eclogites formed at 800–850 °C and 18–20 kbar, and the Borovoe eclogites, at 750–800 °C and 17–18 kbar. Study of pyroxene-plagioclase symplectite replacing omphacite of the eclogites at both sites has recognized three stages of regressive magmatism: (1) formation of coarse-grained clinopyroxene-plagioclase symplectite at 760–790 °C and 11–12 kbar, (2) formation of fine-grained clinopyroxene-plagioclase symplectite at 700–730 °C and 7–8 kbar, and (3) amphibolization of pyroxene at 570–600 °C and 5–6 kbar. The Ar-Ar age of muscovite from the Borovoe mica schists hosting eclogites is 493 ± 5 Ma, which corresponds to the time of cooling of metamorphic rocks to <370 °C. Hence, the peak of high-pressure metamorphism and all recognized stages of retrograde changes are dated to the Cambrian. The geological data evidence that eclogite-schist-gneiss sheets were localized in the accretion-collision zone and became conjugate with sedimentary and volcanic rocks no later than in the Middle Ordovician.     

Relationship between the Ordovician and Carboniferous–Permian collisional events in the southeastern Tunka bald mountains, East Sayan (southwestern framing of the Siberian Platform)

Granites from the Tunka pluton of the Sarkhoi complex, located in the eastern Tunka bald mountains (East Sayan), have been dated at the Middle Ordovician (462.6 ± 7.8 Ma) by LA ICP MS. The granites of the Sarkhoi complex within the studied area cut a foldthrust structure consisting of deformed fragments of the Vendian (Ediacaran)–Early Cambrian cover of the Tuva–Mongolian microcontinent (Upper Shumak metaterrigenous formation, Gorlyk carbonate formation). The red-colored conglomerates and sandstones of the Late Devonian–Early Carboniferous(?) Sagan-Sair Formation overlie the eroded surface of the Tunka pluton granites in the eastern Tunka bald mountains. The Sagan-Sair Formation, in turn, is overlain along a low-angle thrust by a group of tectonic sheets, which comprises the volcanic and carbonate sediments of the Tolta Formation, biotitic schists, and plagiogneisses with garnet amphibolite bodies. Two nappe generations have been revealed on the basis of the described geologic relationships, the Middle Ordovician age of the Tunka pluton granites, and numerous Late Paleozoic Ar–Ar dates of syntectonic minerals from the metamorphic rocks in the area. The first thrusting stage was pre-Middle Ordovician, and the second, Late Carboniferous–Permian. The Lower Paleozoic thrust structure resulted from the accretion of the Tuva–Mongolian microcontinent to the Siberian Platform. The Late Paleozoic nappes resulted from intracontinental orogeny and the reactivation of an Early Paleozoic accretionary belt under the effect of the Late Paleozoic collisional events.     

Composition of Hydrocarbons in Synthetic Diamonds Grown in a Fe—Ni—C System (according to Gas Chromatography—Mass Spectrometry Data)

The first data of chromatography—mass spectrometry analysis of volatiles from crystals of synthetic diamonds grown in a Fe—Ni—C system at 1350–1400°С and 5.5–6.0 GPa are presented. The composition of the fluid in equilibrium with the metal-carbon melt is determined, and a comparative estimation for the compounds of different hydrocarbons and their derivatives is made. It is shown that a significant role in these processes is played by high-molecular-weight hydrocarbons; and the total share of hydrocarbons and their derivatives in the fluid compounds can exceed 86%.     

The Raigorodok stockwork gold-sulfide-quartz deposit in the North Kazakhstan gold ore province

The Raigorodok stockwork gold-sulfide-quartz deposit is located in the contact zone of a monzogabbro-diorite intrusion belonging to the Stepnyak complex (442 Ma). Two main ore formation stages have been established: early, with disseminated gold-bearing pyrite-chalcopyrite mineralization related to skarn, propylite, and K-feldspar formation, and late, with productive mineralization. The late stage was accompanied by the formation of beresite, sericite, and quartz and comprised two substages: (1) quartz-gold-pyrite-chalcopyrite mineralization and (2) quartz-carbonate-gold-polysulfide mineralization. The ⁴⁰Ar/³⁹Ar ages of beresites and sericites are 422.9 ± 4.3 Ma and 416.7 ± 4.3 Ma, respectively, which is 19-22 Myr younger than the age of the host intrusion. The deposit ores formed stepwise, at temperatures of 112-335 °C and fluid salinity of 0.7-21.2 wt.% NaCl equiv. Sulfur for skarns, propylites, beresites, and ores might have been provided by a deep magma chamber, and the carbonaceous shales of the Vendian Sharyk Formation might have been the source of gold. The isotope and geochemical data and the results of fluid inclusion study suggest that Raigorodok is an intrusion-related deposit. At the same time, the deposit has a number of signs of porphyry-epithermal ore-magmatic systems.     

Diamond stability in silicate-halogenide melts at high pressure

Chlorides of alkali metals of mantle origin and with the possibility to influence the preservation of natural diamonds were found in kimberlites of deep horizons of Udachnaya pipe (Yakutia).     

Diamond Crystallization at High Pressure: The Relative Efficiency of Metal-Graphite and Metal-Carbonate Systems

Doklady Earth Sciences - Data on the interaction of the Fe–Ni melt with CaCO3 and graphite at 5 GPa and 1400°С under the thermogradient conditions used in experiments on the growth...