丹凤地区秦岭岩群片麻岩锆石U-Pb年龄:北秦岭地体中-新元古代岩浆作用和早古生代变质作用的记录

秦岭岩群被认为是出露于北秦岭地体内最古老的前寒武纪基底岩石,记录了北秦岭造山带的地壳形成和演化历史。本文报道丹凤-西峡地区五件秦岭岩群片麻岩锆石U-Pb年龄结果,限定其形成和变质时代,探讨北秦岭地体的构造归属。定年结果表明,岩浆成因锆石颗粒的年龄集中在1400～1600Ma左右和850～950Ma左右,记录两期主要岩浆活动。6粒锆石具有变质成因特征,低Th/U比值(0.03),206Pb/238U年龄变化在510～465Ma之间,加权平均值477±18Ma。这一古生代变质叠加时代与北秦岭地体南北缘高压变质作用时代基本一致,说明秦岭岩群遭受到北秦岭造山带俯冲-碰撞造山过程的变质作用。秦岭岩群主要形成于中元古代晚期至新元古代早期,基底岩石缺乏早元古代和太古代岩浆活动的记录。在岩浆作用时代上,北秦岭地体与广泛发育新元古代中-晚期岩浆作用的扬子陆块北缘有差别,也不同于晚太古代-早元古代的华北陆块南缘,可能是中-新元古代形成的独立微陆块。     

REE, Mn, Fe, Mg and C, O Isotopic Geochemistry of Calcites from Furong Tin Deposit, South China: Evidence for the Genesis of the Hydrothermal Ore-forming Fluids

The Furong tin deposit in the central Nanling region, South China, consists of three main types of mineralization ores, i.e. skarn-, altered granite- and greisen-type ores, hosted in Carboniferous and Permian strata and Mesozoic granitic intrusions. Calcite is the dominant gangue mineral intergrown with ore bodies in the orefield. We have carried out REE, Mn, Fe, and Mg geochemical and C, and O isotopic studies on calcites to constrain the source and evolution of the ore-forming fluids. The calcites from the Furong deposit exhibit middle negative Eu anomaly (Eu/Eu*= 0.311–0.921), except for one which has an Eu/Eu* of 1.10, with the total REE content of 5.49–133 ppm. The results show that the calcites are characterized by two types of REE distribution patterns: a LREE-enriched pattern and a flat REE pattern. The LREE-enriched pattern of calcites accompanying greisen-type ore and skarn-type ore are similar to those of Qitianling granite. The REE, Mn, Fe, and Mg abundances of calcites exhibit a decreasing tendency from granite rock mass to wall rock, i.e. these abundances of calcites associated with altered granite-type and greisen-type ores are higher than those associated with skarn-type ores. The calcites from primary ores in the Furong deposit show large variation in carbon and oxygen isotopic compositions. The δ¹³C and δ¹⁸O of calcites are −0.4 to −12.7‰ and 2.8 to 16.4‰, respectively, and mainly fall within the range between mantle or magmatic carbon and marine carbonate. The calcites from greisen and altered granite ores in the Furong deposit display a negative correlation in the diagram of δ¹³C versus δ¹⁸O, probably owing to the CO₂-degassing of the ore-forming fluids. From the intrusion to wall-rock, the calcites display an increasing tendency with respect to δ¹³C values. This implies that the carbon isotopic compositions of the ore-bearing fluids have progressively changed from domination by magmatic carbon to sedimentary carbonate carbon. In combination with other geological and geochemical data, we suggest that the ore-forming fluids represent magmatic origin. We believe that the fluids exsolved from fractionation of the granitic magma, accompanying magmatism of the Qitianling granite complex, were involved in the mineralization of the Furong tin polymetallic deposit.     

Implication of coupled natural and human systems in sustainable rangeland ecosystem management in HKH region

The sustainable development of rangeland ecosystems, the vital ecosystems providing many important ecosystem services for millions of people in the Hindu Kush-Himalaya region is presently confronted with a number of challenges. A coupled natural and human systems approach is needed to facilitate effective collaboration among social scientists, bio/physical scientists, and management practitioners to better understand how people interact with the environment in which they live. In pursuing this argument, three existing case studies, i.e. Indigenous rangeland management in Himalayan Nepal, Cultivated Grassland Systems in Eastern Qinghai-Tibetan Plateau, and Grassland Restoration in Central Qinghai-Tibetan Plateau were synthesized in this paper to address the importance of coupled natural and human systems in promoting sustainable rangeland ecosystem management in the Hindu Kush-Himalaya (HKH) region. It was concluded although the research sites and objectives were very different, that these three case studies had many commonalities that addressed the complex interactions and feedbacks between natural and human systems, and highlighted the integration of various tools and techniques from the ecological and social sciences, as well as other disciplines, in sustainable rangeland management. These case studies have offered unique interdisciplinary insights into complexities that cannot be gained from ecological or social research alone. The results from these case studies can be applied to many other coupled systems at local, national, and global levels.     

地勘单位经济运行中关键环节管理与执行力问题探讨

对地勘单位经济运行中的资金管理、成本管理、制度管理等三个关键环节的作用及运行状况进行分析,指出其运行过程中存在的三个共性问题,即制度不健全,经营机制不完善;成本管理滞后,经济效益不明显;资金管理不规范,经济运行质量不高。地勘单位经济运行执行力就是地勘单位实现经济运行目标的能力。提高地勘单位经济运行执行力的关键是解决经济运行中存在的问题,为此提出了建立健全制度、完善经营机制,强化资金管理、确保生产经营正常进行,加强成本管理、提高经济运行质量等对策和措施。探索地勘单位提升管理水平,增强管理执行力,推动煤田地质经济健康持续发展。     

Last glacial terrestrial vegetation record of leaf wax n-alkanols in the northern South China Sea: Contrast to scenarios from long-chain n-alkanes

Long-chain n-alkanols and n-alkanes in core sediments from the northern South China Sea (SCS) were measured to make a comparison during terrestrial vegetation reconstruction from ~42 ka to ~7 ka. The results showed that terrestrial vegetation record from long-chain n-alkanes matched well with previous studies in nearby cores, showing that more C₄ plants developed during the Last Glacial Maximum (LGM) and C₃ plants dominated in the interglacial period. However, these scenarios were not revealed by terrestrial vegetation reconstruction using long-chain n-alkanols, which showed C₃ plant expansion during the LGM. The discrepancy during the interglacial period could be attributed to the aerobic degradation of functionalized long-chain n-alkanols in the oxygen-rich bottom water, resulting in poor preservation of terrestrial vegetation signals. On the other hand, the different advantages of functionalized n-alkanols and non-functional n-alkanes to record local and distal vegetation signals, respectively, may offer a potential explanation for the contradiction during the LGM when the SCS was characterized by low-oxygen deep water. Nevertheless, large variations on n-alkyl lipid compositions in C₃/C₄ plants could play a part in modulating sedimentary long-chain n-alkanols and n-alkanes toward different vegetation signals, thereby suggesting that caution must be taken in respect to the terrestrial vegetation reconstruction using long-chain n-alkanes and long-chain n-alkanols.     

Simulating the influence of various nutrient sources on hypoxia off the Changjiang River Estuary

Hypoxia is increasingly reported off the Changjiang River Estuary with the confluence of multiple high volume nutrient sources. The Regional Ocean Modeling System coupled with a biological model was used to analyze the effect of different nutrient sources on the development of hypoxia off the Changjiang River Estuary. By comparing to observed data, our model suitably captured the regional dynamics of chlorophyll a, dissolved oxygen, and nutrient concentration. A series of sensitivity experiments were conducted to investigate the hypoxia response to the various nutrient sources, such as loading from the Changjiang River, Kuroshio and Taiwan Warm Current. Our model results indicated that nutrients from different sources significantly influenced the hypoxia off the Changjiang River Estuary, and it was mostly affected by nutrients sourced from the Kuroshio. The nutrients input from the Changjiang River had larger impacts on the hypoxia in the north of 30°N than that in the south of 30°N. The nutrients sourced from the Taiwan Strait had a least influence on the hypoxia off the Changjiang River Estuary.     

利用H/V方法研究琼北火山区的浅表层地质变化特征

海南琼北活火山作为华南沿海重要的第四纪火山, 一直受到国内外学者的广泛关注, 目前对该火山的形成演化已开展了大量深部地质结构的研究, 但对其表层地质结构特征仍然缺乏详细了解。水平-垂直频谱比法(简称H/V方法)已被广泛应用于浅表层地质结构的研究, 本文基于35个便携式微功耗地震仪组成的流动台阵观测数据, 采用经典全波场H/V_(full)和瑞利波椭圆率H/V_(Ray)分析方法, 获得了琼北火山区H/V曲线峰值频率(F₀)和放大倍数(A₀)的空间变化特征。琼北火山区H/V曲线峰值频率变化强烈, 以长流-仙沟断裂为界, 断裂西南侧很难从H/V曲线中获取清晰的F₀和A₀, 而断裂东北侧则存在明显的F₀和A₀。结合已有地质资料, 本文认为长流-仙沟断裂西南侧处于凹陷区, 其浅表层火山岩未发生明显的风化作用, 而东北侧位于隆起区域, 地表火山岩受到了比较严重的风化作用。这一研究结果表明, H/V方法可反映表层火山岩的风化状态, 火山岩出露场地H/V曲线的峰值频率和放大倍数随风化作用程度的增强而表现得更加明显。本研究为琼北火山区浅表火山岩风化状态和地震危险性评估提供了重要的信息支撑。     

海洋透光率仪的设计及其在初级生产力研究中的应用*

海洋浮游植物光合作用固碳在全球碳循环中扮演着极为重要的角色, 获取不同光衰减对应的海水深度, 对于采集水样用于海洋初级生产力的研究具有重要意义。本研究于国际上首次开发了无缆便携式海洋透光率仪, 特殊的光学结构设计和光谱滤光技术使得光谱响应在波段400~700nm范围内超过了同类海洋传感器, 特定光衰减下对应的深度误差小于0.5m。将本设备应用于南海中尺度涡旋初级生产力的研究中, 在采样率和自动化方面验证了仪器的便携性; 通过对涡旋中初级生产力的空间分布规律进行分析, 检验了仪器数据结果的可靠性。海洋透光率仪在价格、准确性、可靠度和操作的便携性上具有不可比拟的优势, 将在未来海洋生态环境的研究中发挥重要作用。     

壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。     

基于CiteSpace的国内外海洋空间规划研究发展态势分析

海洋空间规划是一个对海洋资源可持续开发利用的规划和管理过程。文章采用可视化工具CiteSpace,基于WOS核心合集和CNKI数据库,系统梳理分析2000—2020年海洋空间规划领域的国内外研究主题及其突现词演变路径。结果表明:当前国内外海洋空间规划相关研究数量总体呈上升趋势,美国、澳大利亚和英国3国占比超过50%,各机构间合作度较高、跨国交流活跃;国际方面,栖息地、海洋保护区域、渔业发展、生物多样性是热点研究方向,国内则更加关注陆海统筹和可持续发展;近20年来,国际研究趋势变化为"空间规划体系的构建-空间规划尺度的拓展及跨界研究-经验总结与环境保护",国内规划时期则从"空间规划政策综合管理-具体功能区划分-可持续发展"不断发展;在此基础上提出未来深入探索的重点领域以及建议。