Geochemistry, Geochronology and Lu-Hf Isotopes of Peraluminous Granitic Porphyry from the Walegen Au Deposit, West Qinling Terrane

Walegen Au deposit is closely correlated with granitic intrusions of Triassic age, which are composed of granite and quartz porphyries. Both granite porphyry and quartz porphyry consist of quartz, feldspar and muscovite as primary minerals. Weakly peraluminous granite porphyry(A/CNK=1.10–1.15) is enriched in LREE, depleted in HREE with Nb-Ta-Ti anomalies, and displays subduction-related geochemistry. Quartz porphyry is strongly peraluminous(A/CNK=1.64–2.81) with highly evolved components, characterized by lower TiO_2, REE contents, Mg~#, K/Rb, Nb/Ta, Zr/Hf ratios and higher Rb/Sr ratios than the granite porphyry. REE patterns of quartz porphyry exhibit lanthanide tetrad effect, resulting from mineral fractionation or participation of fluids with enriched F and Cl. LAICP-MS zircon U-Pb dating indicates quartz porphyry formed at 233±3 Ma. The ages of relict zircons from Triassic magmatic rocks match well with the detrital zircons from regional area. In addition, ε_(Hf)(t) values of Triassic magmatic zircons from the granite and quartz porphyries are -14.2 to -9.1(with an exception of +4.1) and -10.8 to -8.6 respectively, indicating a crustal-dominant source. Regionally, numerous Middle Triassic granitoids were previously reported to be formed under the consumption of Paleotethyan Ocean. These facts indicate that the granitic porphyries from Walegen Au deposit may have been formed in the processes of the closing of Paleotethyan Ocean, which could correlate with the arc-related magmatism in the Kunlun orogen to the west and the Qinling orogen to the east.     

扬子板块北缘花山群沉积时代及其对Rodinia超大陆裂解的制约

出露于扬子板块北缘大洪山地区的花山群自下而上由一套以砾岩为主的粗碎屑沉积和一套以砂质板岩为主的细碎屑沉积组成,伴随有拉斑玄武质岩浆活动。花山群整体变质程度不高,形成构造环境复杂,对其构造属性及其与区内所谓的花山"蛇绿混杂岩"的时空关系一直存有争议,它们对新元古代Rodinia超大陆在扬子板块北缘的汇聚-裂解响应具有重要的制约意义。笔者在花山群六房咀组下部细砂岩中采集玄武质熔结凝灰岩夹层样品1件,碎屑岩样品2件,在上覆地层南华系莲沱组采集碎屑岩样品1件;对玄武质熔结凝灰岩进行了SHRIMP锆石U-Pb同位素测年,对碎屑岩样品进行了LA-MC-ICPMS锆石U-Pb同位素测年。获得玄武质熔结凝灰岩锆石U-Pb年龄814.7±7.3 Ma;花山群的碎屑锆石U-Pb年龄谱存在三个明显的峰值:~900 Ma、~2050Ma和~2650 Ma,最显著峰值为~2650 Ma,上覆莲沱组碎屑岩年龄谱的三个峰值为:~900 Ma、~2050 Ma和~2500 Ma,最显著峰值为~2050Ma,三件碎屑岩样品均与扬子板块的碎屑锆石U-Pb年龄统计峰值一致。花山群的碎屑源区可能包括下伏中元古代打鼓石群、太古宙鱼洞子杂岩以及崆岭杂岩。结合前人年代学研究资料和区域构造成果分析,花山群沉积时代应为820~815Ma,形成于伸展构造背景,与花山"蛇绿混杂岩"不是同期同构造背景的产物;花山"蛇绿混杂岩"与花山群沉积建造依次反映了扬子板块北缘由挤压构造背景向伸展构造背景的转换过程。花山群中的碎屑沉积物与基性火山岩、火山碎屑岩属于裂解背景下形成的同时代沉积-火山建造;结合前人在扬子板块周缘发现的大量约820 Ma酸性—基性岩浆活动记录以及同时代(820~800 Ma)的沉积地层,推测花山群形成于Rodinia超大陆裂解背景之下,与超级地幔柱活动有关。     

辽宁营口虎皮峪地区古元古代岩浆事件及地质意义

辽宁营口虎皮峪地区存在3期古元古代侵入岩浆活动:早期虎皮峪辽吉花岗岩成岩时代为2119±16Ma,富硅、富碱、低铝、低钙及负Eu异常显示其具有类似A型花岗岩的地球化学特征,非常低Sr高Yb的特点指示其形成压力很低,与减薄的地壳有关;第二期后松树沟奥长花岗岩成岩时代为1892±16Ma,富硅、富钠、高铝,Na2O/K2O1.35及无Eu异常或正Eu异常显示其具有埃达克质岩石的特征,中—高Sr低Yb的特点指示其形成压力较高、深度较大,与碰撞后加厚地壳底侵玄武岩的部分熔融有关;晚期南台子石英二长岩成岩时代为1850±11Ma,富碱(Na2O+K2O=11.32%~11.93%),里特曼指数δ=4.78~7.20,属碱性岩,低Sr低Yb的特点指示其形成压力中等,深度大概40~50km,是造山作用完成后板内伸展背景下的产物。上述3期岩浆事件对整个辽吉古元古代活动带的构造演化具有重要指示意义:早期辽吉花岗岩可能形成于辽吉古元古代活动带早期弧后伸展阶段;后松树沟奥长花岗岩则代表古元古代晚期碰撞后地壳加厚阶段的产物;南台子石英二长岩属后造山花岗岩,标志着辽东地区克拉通化的完成,开始进入后造山伸展演化阶段。     

离子交换树脂在地质样品Sr-Nd同位素测定中的应用

Rb-Sr和Sm-Nd同位素测年及同位素示踪方法在同位素地质年代学和同位素地球化学中有非常广泛的应用。目前,Rb-Sr和Sm-Nd同位素质谱测试方法通常需要对Rb、Sr和Sm、Nd进行分离纯化,因此,如何对地质样品中的Rb、Sr、Sm和Nd进行分离富集对测试结果准确与否起到至关重要的作用。离子交换分离法是SrNd同位素化学前处理阶段应用最广泛的分离方法,本文结合笔者近几年的研究工作,系统介绍离子交换树脂在Sr-Nd同位素测试中应用的发展过程和现状,重点介绍几类使用率较高的离子交换树脂(Dowex50W树脂、AG50W树脂、锶特效树脂、LN树脂、P507树脂等)的优缺点,以及各自的萃取反应机理,探索和讨论未来离子交换树脂在Sr-Nd同位素测试中应用的发展趋势。     

Discovery of Iapetognathus fauna from far western New South Wales: towards a more precisely defined Cambrian–Ordovician boundary in Australia

Conodont species Iapetognathus fluctivagus and Iapetonudus ibexensis are documented for the first time from Australia. The former is the primary marker internationally defining the base of the Ordovician, and the latter is also a distinctive species previously recorded only from the base of the Ordovician in North America. Both species were recovered from a single sample in the Kandie Tank Limestone of the Kayrunnera Group, located about 50 km west of White Cliffs in far western New South Wales. Other species recovered from this sample include Prooneotodus spp., Cordylodus lindstromi, Cordylodus proavus, Hirsutodontus simplex, Teridontus nakamurai and Variabiloconus sp. Recognition of the Iapetognathus fluctivagus Biozone in the Kandie Tank Limestone supports its correlation with the Green Point section (Global Stratigraphic Section and Point for the base of the Ordovician) in western Newfoundland and the Lawson Cove section of Utah (Auxiliary Stratigraphic Section and Point), as well as sections in Asia and South America. Review of other sections in Australia and elsewhere spanning the Cambrian–Ordovician boundary confirms that, in the absence of I. fluctivagus, the presence of C. lindstromi is a good proxy for this level.     

准噶尔盆地石南31井区清水河组油气水层分布规律

针对石南31井区储层岩性多变、油气水关系复杂等问题,按不同岩性识别油气层、水层和干层,据油气不同测井响应特征进一步识别油层和气层.将储层划分为细砂岩、中粗砂岩和砂砾岩3类,识别储层流体性质,分析油藏分布特征,指出油层、隔夹层平面分布特征,探讨油气水层分布规律.结果表明,石南31井区主要有4个油藏.储层所含流体有油、水和气,中北部细砂岩储层为纯油层,南部中粗砂岩储层为水层.气层从南到北分布于全区,主要位于油藏北部和东部局部区域,为今后解释工作具很好指导意义.     

基于非线性破坏准则的边坡稳定性极限分析

上限定理是求解岩土工程问题的有效工具。以上限定理为理论基础,分析边坡的稳定性问题,并考虑了岩土材料破坏准则的非线性特性。在非线性Mohr-Coulomb破坏准则下,采用条分法与极限分析上限法相结合的方法,对边坡稳定性进行分析。通过切线法引入非线性强度参数 、 ,推导了岩土材料在非线性破坏准则下的相关联流动法则,建立功能方程,推导了边坡直线滑裂面、折线滑裂面和光滑曲线滑裂面安全系数F的计算方程。采用数学规划法计算后与工程实际中常用的边坡稳定性分析方法进行对比,并获得安全系数F =1.0时的稳定性系数Ns。与已有的研究成果进行比较分析,结果表明了该方法的正确性及优越性     

渭北煤田合阳县北中深部控煤构造样式分析

依据野外地表地质观测及地震、钻探最新的深部地质资料,结合对区域控煤构造认识,运用构造解析、构造应力场及地质力学分析等研究思路与方法,讨论了研究区控煤构造特征、构造样式以及成因。研究结果表明：研究区共有三类六种控煤构造样式,即挤压构造样式（宽缓褶皱、叠加褶皱）、走滑构造样式（反＂S＂型褶皱、＂入＂字型构造）及伸展构造样式（掀斜断块、堑垒构造）,其中以伸展构造样式发育为主要特征;研究区由东南向西北,构造变形强度由强变弱,先后经历了印支期南北向挤压、燕山中期北西向挤压和喜马拉雅期北东向挤压-走滑与北西-南东向伸展断陷作用;晚期形成的正断层不仅破坏了煤层的连续性,而且成为奥灰水储集和运移的主要通道,增大了底板突水的可能性,使煤炭资源开发受到影响。     

Geochemistry of environmentally sensitive trace elements in Permian coals from the Huainan coalfield, Anhui, China

To study the geochemical characteristics of 11 environmentally sensitive trace elements in the coals of the Permian Period from the Huainan coalfield, Anhui province, China, borehole samples of 336 coals, two partings, and four roof and floor mudstones were collected from mineable coal seams. Major elements and selected trace elements were determined by inductively coupled plasma optical emission spectrometry (ICP-OES), inductively coupled plasma mass spectrometry (ICP-MS), and hydride generation atomic absorption spectrometry (HAAS). The depositional environment, abundances, distribution, and modes of occurrence of trace elements were investigated. Results show that clay and carbonate minerals are the principal inorganic constituents in the coals. A lower deltaic plain, where fluvial channel systems developed successively, was the likely depositional environment of the Permian coals in the Huainan coalfield. All major elements have wider variation ranges than those of Chinese coals except for Mg and Fe. The contents of Cr, Co, Ni, and Se are higher than their averages for Chinese coals and world coals. Vertical variations of trace elements in different formations are not significant except for B and Ba. Certain roof and partings are distinctly higher in trace elements than underlying coal bench samples. The modes of occurrence of trace elements vary in different coal seams as a result of different coal-forming environments. Vanadium, Cr, and Th are associated with aluminosilicate minerals, Ba with carbonate minerals, and Cu, Zn, As, Se, and Pb mainly with sulfide minerals.     

U–Pb and Re–Os geochronology and geodynamic setting of the Dabaoshan polymetallic deposit, northern Guangdong Province, South China

The Dabaoshan polymetallic deposit in northern Guangdong Province contains iron, copper, lead, zinc, molybdenum, tungsten and sulfur mineral resources. Porphyry-type Mo(W) and skarn-type Mo-W mineralization occurs along the internal and external contact zones of the granodioritic porphyry, respectively. LA-ICP-MS U–Pb dating of zircons from two granodioritic porphyry samples yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 175.8 ± 1.5 Ma (MSWD = 0.037) and 175.0 ± 1.7 Ma (MSWD = 0.41). They can be pooled together to yield a combined weighted age of 175.4 ± 1.6 Ma (MSWD = 0.26), which is interpreted as the emplacement age of the granodioritic porphyry. Re–Os dating of three molybdenite samples from porphyry and skarn ores yielded consistent model ages of 163.2 ± 2.3 Ma to 165.2 ± 2.4 Ma, with a weighted mean of 163.9 ± 1.3 Ma (MSWD = 0.81), which is the age of Mo–W mineralization. These ages are consistent with the molybdenite Re–Os model age (164.7 ± 3 Ma) measured by Mao et al. (2004a) for the stratiform Cu–Pb–Zn orebody, and they can yield a weighted mean of 164.0 ± 2.5 Ma (MSWD = 0.16). This implies that Mo–W and Cu–Pb–Zn mineralization in the Dabaoshan polymetallic deposit are the products of one mineralization event. The mineralization in the deposit coincides closely with that of Mo-polymetallic mineralization (164–149 Ma) elsewhere in the Nanling region, comprising an important polymetallic metallogenic belt of south China, and corresponds to the second episode of Mesozoic metallogenesis in South China. Combined with previous studies, we suggest that the Dabaoshan polymetallic deposit is related to post-collisional lithosphere extension in the Nanling region of South China. Geological data and Pb isotopic evolution diagrams, together with stable isotopic data of fluid inclusions (δ¹⁸O = − 3.75–7.0‰, δD = − 50.7 to − 56.1‰) and ore sulfides (δ³⁴S = − 2–3‰), suggest a genetic relationship between the Dabaoshan polymetallic deposit, the granodioritic porphyry and the dacitic porphyry. These data, combined with the Re content (64.7 to 102.4 ppm) of molybdenite, indicate that the ore-forming components were derived from mixed crustal and mantle sources.