The effects of clay minerals and organic matter on nanoscale pores in Lower Paleozoic shale gas reservoirs,Guizhou, China

In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N₂ adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals.     

Geochemistry and geochronology of Late Jurassic and Early Cretaceous intrusions related to some Au (Sb) deposits in southern Anhui: a case study and review

Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui.     

Assessing rockfall susceptibility in steep and overhanging slopes using three-dimensional analysis of failure mechanisms

Rockfalls strongly influence the evolution of steep rocky landscapes and represent a significant hazard in mountainous areas. Defining the most probable future rockfall source areas is of primary importance for both geomorphological investigations and hazard assessment. Thus, a need exists to understand which areas of a steep cliff are more likely to be affected by a rockfall. An important analytical gap exists between regional rockfall susceptibility studies and block-specific geomechanical calculations. Here we present methods for quantifying rockfall susceptibility at the cliff scale, which is suitable for sub-regional hazard assessment (hundreds to thousands of square meters). Our methods use three-dimensional point clouds acquired by terrestrial laser scanning to quantify the fracture patterns and compute failure mechanisms for planar, wedge, and toppling failures on vertical and overhanging rock walls. As a part of this work, we developed a rockfall susceptibility index for each type of failure mechanism according to the interaction between the discontinuities and the local cliff orientation. The susceptibility for slope parallel exfoliation-type failures, which are generally hard to identify, is partly captured by planar and toppling susceptibility indexes. We tested the methods for detecting the most susceptible rockfall source areas on two famously steep landscapes, Yosemite Valley (California, USA) and the Drus in the Mont-Blanc massif (France). Our rockfall susceptibility models show good correspondence with active rockfall sources. The methods offer new tools for investigating rockfall hazard and improving our understanding of rockfall processes.     

Effects of different soil and water conservation measures on hydrological extremes and flood processes in the Yanhe River,Loess Plateau,China

The runoff and sediment load of the Loess Plateau have changed significantly due to the implementation of soil and water conservation measures since the 1970s. However, the effects of soil and water conservation measures on hydrological extremes have rarely been considered. In this study, we investigated the variations in hydrological extremes and flood processes during different periods in the Yanhe River Basin (a tributary of the Loess Plateau) based on the daily mean runoff and 117 flood event data from 1956 to 2013. The study periods were divided into reference period (1956–1969), engineering measures period (1970–1995), and biological control measures period (1996–2013) according to the change points of the annual streamflow and the actual human activity in the basin. The results of the hydrological high extremes (HF1_max, HF3_max, HF7_max) exhibit a decreasing trend (P?<?0.01), whereas the hydrological low extremes (HBF1_min, HBF3_min, HBF7_min) show an increasing trend during 1956–2013. Compared with the hydrological extremes during the reference period, the hydrological high extremes increased during the engineering measures period at low (<?15%) and high frequency (>?80%), whereas decreased during the biological control measures period at almost all frequencies. The hydrological low extremes generally increased during both the engineering measures and biological control measures periods, particularly during the latter period. At the flood event scale, most flood event indices in connection with the runoff and sediment during the engineering measures period were significantly higher than those during the biological control measures period. The above results indicate that the ability to withstand hydrological extremes for the biological control measures was greater than that for the engineering measures in the studied basin. This work reveals the effects of different soil and water conservation measures on hydrological extremes in a typical basin of the Loess Plateau and hence can provide a useful reference for regional soil erosion control and disaster prevention policy-making.

     

A generalized model for effective thermal conductivity of soils considering porosity and mineral composition

Acta Geotechnica - Soils have a variety of mineral compositions. Although a number of thermal conductivity models have been developed for soils, few quantitatively investigated the effect of...     

The relationship between groundwater and natural vegetation in Qaidam Basin

To accurately evaluate ecological risks trigged by groundwater exploitation, it must be clarified the relationship between vegetation and groundwater. Based on remote sensing data sets MOD13Q1, groundwater table depth (WTD) and total dissolved solids (TDS), the relationship between groundwater and natural vegetation was analyzed statistically in the main plain areas of Qaidam Basin. The results indicate that natural vegetation is groundwater-dependent in areas where WTD is less than 5.5 m and TDS is less than 7.5 g/L. Aquatic vegetation, hygrophytic vegetation and hygrophytic saline-alkali tolerant vegetation are mainly distributed in areas with WTD <1.1 m. Salt-tolerant and mesophytic vegetation mainly occur in areas with WTD of 1.4-3.5 m, while the xerophytic vegetation isprimarily present in areas where WTD ranges from 1.4 m to 5.5 m. Natural vegetation does not necessarily depend on groundwater in areas with WTD >5.5 m. For natural vegetation, the most suitable water TDS is less than 1.5 g/L, the moderately suitable TDS is 1.5-5.0 g/L, the basically suitable TDS is 5.0-7.5 g/L, and the unsuitable TDS is more than 7.5 g/L.     

An assessment of Arctic cloud water paths in atmospheric reanalyses

The role of Arctic clouds in the recent rapid Arctic warming has attracted much attention. However, Arctic cloud water paths(CWPs) from reanalysis datasets have not been well evaluated. This study evaluated the CWPs as well as LWPs(cloud liquid water paths) and IWPs(cloud ice water paths) from five reanalysis datasets(MERRA-2,MERRA, ERA-Interim, JRA-55, and ERA5) against the COSP(Cloud Feedback Model Intercomparison Project Observations Simulator Package) output for MODIS from the MERRA-2 CSP(COSP satellite simulator) collection(defined as M2 Modis in short). Averaged over 1980–2015 and over the Arctic region(north of 60°N), the mean CWPs of these five datasets range from 49.5 g/m~2(MERRA) to 82.7 g/m~2(ERA-Interim), much smaller than that from M2 Modis(140.0 g/m~2). However, the spatial distributions of CWPs, show similar patterns among these reanalyses, with relatively small values over Greenland and large values over the North Atlantic. Consistent with M2 Modis, these reanalyses show larger LWPs than IWPs, except for ERA-Interim. However, MERRA-2 and MERRA underestimate the ratio of IWPs to CWPs over the entire Arctic, while ERA-Interim and JRA-55 overestimate this ratio. ERA5 shows the best performance in terms of the ratio of IWPs to CWPs. All datasets exhibit larger CWPs and LWPs in summer than in winter. For M2 Modis, IWPs hold seasonal variation similar with LWPs over the land but opposite over the ocean. Following the Arctic warming, the trends in LWPs and IWPs during 1980～2015 show that LWPs increase and IWPs decrease across all datasets, although not statistically significant. Correlation analysis suggests that all datasets have similar interannual variability. The study further found that the inclusion of re-evaporation processes increases the humidity in the atmosphere over the land and that a more realistic liquid/ice phase can be obtained by independently treating the liquid and ice water contents.     

Landscape Effects of Land Consolidation Projects in Central China——A Case Study of Tianmen City,Hubei Province

The goal of land consolidation in China is still to develop agricultural production. The study of landscape effects of land consolidation projects （LCPs） faces many difficulties because of the lack of government＇s interest and data. This paper, taking Tianmen City of Hubei Province in Central China as an example, presents a methodology for analyzing landscape effects of LCPs by GIS and Fragstats3.3. It describes landscape effects with indexes of Patch Density （PD）, Largest Patch Index （LPI）, Landscape Shape Index （LSI）, Interspersion and Juxtaposition Index （IJI）, Aggregation Index （AI）, and Shannon＇s Diversity Index （SHDI）, showing more regular shape, simpler structure and less habitat diversity after LCPs. It computes ten landscape indexes of four categories of patches including Cultivated Land, Road, Water Channel, and River and Pond. The indexes show that 1） cultivated land becomes more fragmental in patch area, less irregular in patch shape and more concentrated in block; 2） the transport capacity of roads and irrigation and drainage capacity of water channels have been improved; 3） the landscape change of river and pond can be summarized as decreasing scale, more regular shape, reducing connectivity and diversity of the class. LCPs can facilitate agricultural production as well as protect cultivated land and food security. However, it is doubted that the increase of cultivated land from LCPs results from the reducing in landscape diversity of water area.     

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