柴达木盆地西部地区咸化湖盆天然气地球化学特征及成因类型判识指标——以古近系—新近系为例

根据天然气地球化学基本理论,对柴达木盆地西部（柴西）地区天然气的地球化学特征进行分析。测试和收集该地区18个油气田及含油气构造的83个天然气样品,分析其组分和C同位素数据,结果显示,该区天然气以烃类气体为主,烃类含量介于79.24%~99.81%之间,天然气比重介于0.72~1.36之间,天然气干燥系数（C1/C2+）介于1.04~617.8之间,甲烷C同位素值介于-51.4‰~-24.2‰之间,乙烷C同位素值介于-34.2‰~-17.4‰之间。在此基础上,对该区不同构造带的天然气成因类型进行研究。研究结果表明,柴达木盆地西部地区天然气类型可划分为腐泥型气、腐殖型气、混合气3类,柴西北部天然气主要为腐泥型气和混合气,少量腐殖型气;柴西南部主要为腐泥型气,少量混合气。同时,建立了天然气成因类型的判识指标,对该区的天然气地球化学特征有了较为深入的认识,对今后的天然气勘探具有指导意义。     

Thermal depolymerization of kerogen and formation of immature oil

Two Chinese immature oil shales from the continental deposits of kerogen type I and II have been thermally treated combined with the technique of supercritical fluid extraction at 630–650 K and 15–25 MPa in a semi-continuous laboratory scale apparatus. Toluence is selected as the solvent. Up to 70–80% of the kerogen matrix can be converted to a thermal bitumen and extracted simultaneously. The chemical structural parameters from the NMR, IR, XRD, ESR and EA analyses of the kerogen and the thermal bitumen show striking resemblance in nature. It implies that the thermal bitumen is primarily a depolymerized product of the kerogen. Based on the GC/MS spectra of the aliphatic eluate of the thermal bitumen, the predominance of the odd/even ratio of the alkanes and the epimeric ratios, such as 20S(20S + 20R) of C-29 steranes and 22S/(22S + 22R) of C-32 terpanes, show that the maturity of the thermal bitumen from these oil shales is comparable to that of commercial immature oils from East China. The thermal bitumen is thought to be an intermediate product of the thermal degradation of kerogen.Since the thermal bitumen is mainly composed of asphaltenes and resins, it has a structure of gel. The gel-state bitumen may turn to sol-state readily due to its low aromaticity and polarity, or due to selective adsorption of asphaltenes by clay minerals. Then the migration potential of the bitumen is enhanced.Consequently, under favorable geological conditions, the thermal depolymerization of kerogen seems to be a probable mechanism to explain the formation of immature oils.     

河南省内黄县河流地质考古研究

河流地质考古学是基于地层研究河流和考古遗址之间关系的学科。近年来我们在河南省内黄县开展的河流地质考古研究揭示了黄河复杂的演化历史,在此基础上进一步探讨了古代人类活动与周围环境的相互作用。本文主要介绍了2010~2016年我们在河南省内黄县3个全新世遗址（岸上、三杨庄和大张龙村）的地质考古工作中所取得的成果。研究区域内遗址的地层记录表明,许多考古遗址被深埋于地下,并可能影响了3000 a B.P.以来的河流沉积过程。我们在岸上遗址发掘了A、B、C、D共4处青铜时代的沟渠遗迹,这些沟渠的堆筑可能影响了后期的沉积过程并导致了遗址周边微地貌的改变;在三杨庄遗址识别出了多层不同时期的人为古土壤,包括新石器晚期、战国时期、汉代和唐代;在大张龙村发现了北宋时期黄河泛滥沉积物,其沉积过程可能受周边村落遗址的影响。根据测得的14C年代和沉积层厚度,本研究进一步对这3处遗址的沉积速率进行了估算,并与前人对华北平原沉积速率的相关研究进行了对比。结果表明,这3处遗址所显示的沉积速率自3000 a B.P.开始显著增加,与对早期历史时期黄河河道沉积速率的估算结果相吻合。因此,基于遗址的地质考古研究能够为探索人与环境的互动关系提供大量信息。未来的工作中,我们需要开展更多基于考古遗址的河流地质考古研究,以深入探讨华北平原的自然沉积过程与文明演进过程之间的关系。

     

浅析探矿权评估方法应用中存在的问题

由于探矿权勘查风险、地质前景的不可预测性,国内外对探矿权的评估方法仍处于探索阶段,不够成熟.现在探矿权评估有很多方法,但是每种评估方法都有其弊端,文章选取了3个同矿种、同矿带的某勘查区探矿权作为评估对象,这3个勘查区域勘查工作程度不同.通过对3个区块探矿权评估价值的对比分析,来浅析在各阶段各评估方法在现今探矿权评估中尚存在的问题:不管是使用何种方法对勘查区进行评估,由于采用参数不同,评估出的价值将会有很大的差距.     

A novel method for evaluating proneness of gas outburst based on gas-geological complexity

The gas outburst, resulting in substantial economic losses and even casualties, is the biggest obstacle in coal mines, mostly caused by an imbalance of gas-geological structure. For accurately measuring this proneness, in this paper, a novel evaluation method was proposed based on the gas-geology theory. In this method, a standardization model of statistical units was presented first, which was used to standardize and quantify the 12 chosen gas-geological factors; and then, an associated function was established for computing the gas-geological complexity index (GCI). With increasing GCI values, the evaluated area was divided into four grades: simple, medium, complex, and extremely complex region, in which the associated proneness of outbursts was SAFE, POTENTIAL, HIGH, STRONG, respectively. Taking the XueHu Coal Mine as an example, site verification was carried out with a good result. Research and application indicate that (1) gas outburst is unbalanced and closely related to the complex of the gas geological structure, showing a greater GCI leads to a higher outburst possibility; (2) the most likely area for the gas outburst is the extremely complex region and the transition zone between adjacent areas with different GCI grades; (3) upgrading-targeted control measures are the best way for preventing and controlling disasters caused by the gas and outburst unbalanced distribution. This novel method provided a reliable quantity approach for predicting and zonally managing gas outbursts and improving the effectiveness of outbursts prevention.

     

超声心动图联合64排CT心血管造影在法洛四联症诊断中的应用研究

目的:通过对比单纯超声心动图和超声心动图联合64排CT心血管造影对肺动脉狭窄部位的诊断准确性,对肺动脉主干、左、右肺动脉内径、右心室流出道内径以及患儿肺血管发育情况的预测准确率,并通过相关性分析说明超声心动图和64排CT心血管造影两种方法对左右心室各指标测量结果的密切相关性,从而阐明联合应用两种方法在提高法洛四联症心血管成像诊断准确率中的重要意义。方法:分别采用超声心动图和超声心动图联合64排CT心血管造影诊断肺动脉狭窄部位以及评价患儿肺血管发育情况,并与手术后实际诊断结果比较;采用超声心动图和超声心动图联合64排CT心血管造影测量肺动脉主干、左、右肺动脉内径以及右心室流出道内径,并与手术后实际测得结果比较;相关性分析说明超声心动图和64排CT心血管造影两种方法对左右心室各指标测量结果的相关情况。结果:超声心动图联合64排CT心血管造影诊断肺动脉狭窄部位的准确率为91.5%,明显高于单纯超声心动图的准确率68.1%(相似文献   

Zircon U–Pb ages and Hf isotope compositions of migmatites from the North Qinling terrane and their geological implications

Migmatites are predominant in the North Qinling (NQ) orogen, but their formation ages are poorly constrained. This paper presents a combined study of cathodoluminescence imaging, U–Pb age, trace element and Hf isotopes of zircon in migmatites from the NQ unit. In the migmatites, most zircon grains occur as new, homogeneous crystals, while some are present as overgrowth rims around inherited cores. Morphological and trace element features suggest that the zircon crystals are metamorphic and formed during partial melting. The inherited cores have oscillatory zoning and yield U–Pb ages of c. 900 Ma, representing their protolith ages. The early Neoproterozoic protoliths probably formed in an active continental margin, being a response to the assembly of the supercontinent Rodinia. The migmatite zircon yields Hf model ages of 1911 ± 20 to 990 ± 22 Ma, indicating that the protoliths were derived from reworking of Palaeoproterozoic to Neoproterozoic crustal materials. The anatexis zircon yields formation ages ranging from 455 ± 5 to 420 ± 4 Ma, with a peak at c. 435 Ma. Combined with previous results, we suggest that the migmatization of the NQ terrane occurred at c. 455–400 Ma. The migmatization was c. 50 Ma later than the c. 490 Ma ultra‐high‐P (UHP) metamorphism, indicating that they occurred in two independent tectonic events. By contrast, the migmatization was coeval with the granulite facies metamorphism and the granitic magmatism in the NQ unit, which collectively argue for their formation due to the northward subduction of the Shangdan Ocean. UHP rocks were distributed mainly along the northern margin and occasionally in the inner part of the NQ unit, indicating that they were exhumed along the northern edge and detached from the basement by the subsequent migmatization process.     

云南水氡群体异常特征

采用非均匀度方法,分别提取滇西北、滇中北、滇西南、滇东南和滇东北地区水氡观测资料的地震前兆群体异常。结果表明,该方法能满足水氡观测点所在地区成组中强地震的中、短临预报要求;且该方法能自动识别异常,排除人为主观影响,便于在其他震区进行预报效能检验。