微波消解—冷原子荧光光谱法测定植物样品中的汞

为了简化测量植物中汞含量的方法,提高灵敏度及结果的可信度,实验采用微波消解植物样品的办法,使样品经氯化亚锡还原,再用冷原子荧光测定出植物样品中汞的含量。确定了消解样品的方法和微波消解样品的条件,优化了仪器的最佳工作参数。方法检出限0.30×10-9(稀释因子100倍),精密度(n=12)在2.09%~6.05%,加标回收率94.1%~105.5%,方法经生物国家一级标准物质验证方法准确可靠。     

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山东数字地震台网定位子台网 选取对定位结果的影响

选取山东及邻区4个不同区域的地震,分析“定位子台网”分布对地震定位精度的影响,研究“定位子台网”的选取规则.探讨两种台站分布情况下定位偏差、水平误差、拟合残差随空隙角、近台距离、远台距离的变化;定位偏差及水平误差与拟合残差的关系.结果显示,速报时选择4-9个分布相对合理的“定位子台网”参加定位,结果较好,使用水平误差估...     

Improving performances of ITO/GaP contact on AlGaInP light-emitting diodes

In this paper AlGaInP light emitting diodes with different types of electrodes: Au/Zn/Au-ITO Au/Ti-ITO Au/Ge/Ni-ITO and Au-ITO are fabricated. The photoelectricity properties of those LEDs are studied. The results show that the Au/Zn/Au electrode greatly improves the performance of LEDs compared with the other electrodes. Because the Au/Zn/Au electrode not only forms a good Ohmic contact with indium tin oxide (ITO), but also reduces the specific contact resistances between ITO and GaP, which are 1.273×10^-6 Ω · cm² and 1.743×10^-3 Ω ·cm² between Au/Zn/Au-ITO and ITO-GaP respectively. Furthermore, the textured Zn/Au-ITO/Zn electrode is designed to improve the performances of LEDs, reduce the forward-voltage of the LED from 1.93 to 1.88 V, and increase the luminous intensity of the LEDs from 126 to 134 mcd when driven at 20 mA.     

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锰钾矿光催化降解苯酚及其影响因素研究

利用回流法合成隧道结构的锰钾矿,并研究其光化学降解苯酚的效果及影响因素。分别采用X射线衍射、原子吸收光谱、扫描电镜、透射电镜和BET氮气吸附法对锰钾矿的晶体结构(包括晶型、晶胞参数和结晶度)、化学组成、微观形貌和比表面积进行了表征。研究表明,非光照时锰钾矿对苯酚的降解效果较差,光照能显著促进锰钾矿对苯酚的降解;光照条件下,p H值减小能显著促进锰钾矿对苯酚的降解;锰钾矿用量增加至1.00 g/L时能显著促进锰钾矿降解苯酚,但继续增加矿物用量却显著降低苯酚降解率;非光照条件下,p H值减小和矿物用量增加不能显著促进锰钾矿降解苯酚。     

Comparison of magnetic parameters with vehicular Br levels in urban roadside soils

Chemical methods are generally chosen to monitor soil pollution but magnetic measurements proved to yield additional information at low cost and less time consumption. In this investigation, the novel use of rapid and non-destructive magnetic measurements to characterize Br levels in Xuzhou (China) urban roadside soils was reported. X-ray fluorescence spectrometry (XRF) was used to quantify Br in the soil samples. Data from 21 roadside soil samples confirm Br contamination, with a mean level of 4.36 mg kg⁻¹ and a range of 2.4–8.7 mg kg⁻¹. These values are higher than that of unpolluted soils in Xuzhou that averages 1.1 mg kg⁻¹. Hierarchical clustering analysis shows Br in Xuzhou roadside soils is mainly from road traffic. Clear correlations between Br levels and simple magnetic parameters [mass specific susceptibility (χ _LF), susceptibility of anhysteretic remanent magnetization (χ _ARM), saturation isothermal remanence (SIRM)] are observed. The present study shows that these three magnetic parameters can be used as a proxy for Br levels in Xuzhou urban roadside soils.     

Possible sources of forecast errors generated by the global/regional assimilation and prediction system for landfalling tropical cyclones. Part I: Initial uncertainties

This paper investigates the possible sources of errors associated with tropical cyclone (TC) tracks forecasted using the Global/Regional Assimilation and Prediction System (GRAPES). The GRAPES forecasts were made for 16 landfalling TCs in the western North Pacific basin during the 2008 and 2009 seasons, with a forecast length of 72 hours, and using the default initial conditions (“initials”, hereafter), which are from the NCEP-FNL dataset, as well as ECMWF initials. The forecasts are compared with ECMWF forecasts. The results show that in most TCs, the GRAPES forecasts are improved when using the ECMWF initials compared with the default initials. Compared with the ECMWF initials, the default initials produce lower intensity TCs and a lower intensity subtropical high, but a higher intensity South Asia high and monsoon trough, as well as a higher temperature but lower specific humidity at the TC center. Replacement of the geopotential height and wind fields with the ECMWF initials in and around the TC center at the initial time was found to be the most efficient way to improve the forecasts. In addition, TCs that showed the greatest improvement in forecast accuracy usually had the largest initial uncertainties in TC intensity and were usually in the intensifying phase. The results demonstrate the importance of the initial intensity for TC track forecasts made using GRAPES, and indicate the model is better in describing the intensifying phase than the decaying phase of TCs. Finally, the limit of the improvement indicates that the model error associated with GRAPES forecasts may be the main cause of poor forecasts of landfalling TCs. Thus, further examinations of the model errors are required.     

渤海湾北岸Bg10孔磁性地层研究及其构造意义

对渤海湾北岸孔深600m的Bg10孔进行了详细的沉积学和古地磁研究,划分了39个沉积单元;基于516个样品(60个交变样品,456个热退样品)分离出的特征剩磁,建立了钻孔的磁性地层,并与标准极性年表相对比,确定正极性N1、N2、N3、N4、N5、N6和N7分别对应C1n、C1r.1n、C2n、C2r.1n、C2An.1n、C2An.2n和C2An.3n,R1、R2、R3、R4、R5和R6分别对应C1r.1r、C1r.2r+C1r.3r、C2r.1r、C2r.2r、C2An.1r和C2An.2r。钻孔B/M界限埋深162.3m,M/G界限埋深为475.8m,钻孔底部位于C2An.3n内,其年龄应小于3.596Ma。Bg10孔包括3个沉积阶段:Ⅰ阶段为3.3~3.6Ma,沉积速率略大于130m/Ma,为构造活动期,唐县期夷平面结束后,盆地沉降和山体隆升的差异增大,并与西部地区的青藏运动A幕相对应;Ⅱ阶段为1.9~3.3Ma,沉积速率为112m/Ma,为盆地的填充过程,气候变化控制沉积过程,但沧县隆起和黄骅坳陷之间沉降仍有差异。Ⅲ阶段为0~1.9Ma,沉积速率为202m/Ma,约在1.0~1.2Ma发生一期构造活动,与西部地区的昆黄运动时代大体相当。1.0Ma以来,沉积过程受构造和气候变化双重影响,沧县隆起和黄骅坳陷之间仍有差异沉降。唐山-邢台断裂带可能在1.9Ma之后活动性增强,并和张家口-蓬莱断裂带在沧县隆起上的交汇区域形成一个次级凹陷。