An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.     

Analysis of the environmental sensitivities of a typical dynamic epikarst system at the Nongla monitoring site, Guangxi, China

Nongla, a typical karst dynamic system (KDS) monitoring site, is located at Nongla Village, Mashan County, Guangxi, China. The data from a Greenspan CTDP300 multichannel data logger indicates that the KDS is highly sensitive to environmental changes. Multi-day and diurnal physico-chemical composition of epikarst spring water is quite different under different climatic conditions. During a day with no rainfall, water temperature and air temperature have similar variations. Electrical conductivity (EC) has good positive correlation with pH value and water temperature. During rainstorms, the physico-chemical composition of the spring water is initially strongly effected by dilution, pH and EC drop rapidly. However, half to one hour later, EC returns to normal and the CO₂ effects will be the dominant physical effect. This is due to the high fissure rates and high permeability in the epikarst zone. Dilution effects were observed during the entire rainstorm event,whereas, it only acts during the earliest period of light rain. Therefore, it is necessary to examine the water–rock–CO₂ combination as a whole system to explain the hydrochemical behavior of epikarst processes.     

太湖表层沉积物多环芳烃的空间分布、来源及其风险

随着太湖流域社会与经济的发展,多环芳烃(PAHs)在各种环境介质中逐渐累积,污染日益严重,可能对太湖生态环境及周边人体健康构成威胁。为探究太湖沉积物PAHs的来源及生态风险,于2021年12月在太湖采集30个表层沉积物样品,利用气相色谱-质谱联用仪(GC-MS)检测样品中16种PAHs含量;利用受体模型和苯并[a]芘(BaP)毒性当量法进行来源解析及生态风险评估,并将各来源贡献与毒性当量浓度相结合,量化源风险。结果表明,太湖表层沉积物中16种PAHs总含量介于124~592 ng/g之间,平均值为294 ng/g,中值为279 ng/g;高环多环芳烃(HMW PAHs)为主要组分,占∑PAHs的67%。高含量区域位于竺山湾、梅梁湾、贡湖湾和西太湖,与国内外其他湖泊沉积物相比,太湖沉积物PAHs含量处于较低水平。源解析的结果表明,太湖表层沉积物中PAHs交通排放源贡献率为29.1%、煤炭燃烧源贡献率为26.7%、生物质燃烧源贡献率为28.7%、石油源贡献率为15.6%。生态风险评价结果表明,交通排放源、生物质燃烧源、煤炭燃烧源和石油源的BaP毒性当量含量(TEQ_BaP)均值分别为19.34、17.81、16.33和9.1 ng/g,均小于70 ng/g,几乎处于无风险水平。西太湖、贡湖湾和梅梁湾的部分区域ΣTEQ_BaP大于70 ng/g属于潜在风险区,具有一定潜在毒性。在后续的污染治理中应重点关注太湖西北部地区污染物的排放。本研究可为沉积物中PAHs污染的研究提供数据支撑,为地方政府精准、高效地管控PAHs污染提供理论依据。     

Cloning and characterization of glyceraldehyde-3-phosphate dehydrogenase encoding gene inGracilaria/Gracilariopsis lemaneiformis

Glyceraldehyde-3-phosphate dehydrogenase （GAPDH） plays important roles in various cellular processes. A cytosolic GAPDH encoding gene （gpd） of Gracilaria/Gracilariopsis lemaneiformis was cloned and characterized. Deduced amino acid sequence of the enzyme of G. lemaneiformis had high homology with those of seven red algae. The 5＇-untranslated regions of the GAPDHs encoding genes of these red algae varied greatly. GAPDHs of these red algae shared the highly conserved glyceraldehyde 3-phosphate dehydrogenase active site ASCTTNCL. However, such active site of Cyanidium caldarium was different from those of the other six algae at the last two residues （CL to LF）, thus the spatial structure of its GAPDH active center may be different from those of the other six. Phylogenetic analysis indicated that GAPDH of G. lemaneiformis might have undergone an evolution similar to those of Porphyra yezoensis, Chondrus crispus, and Gracilaria verrucosa. C. caldarium had a closer evolutionary relationship with Cyanidioschyzon merolae than with Cyanidium sp. Virtual Northern blot analysis revealed that gpd of G. lemaneiformis expressed constitutively, which suggested that it might be house-keeping and could be adapted as an inner control in gene expression analysis of G. lemaneiformis.     

Detection of a high-confidence quasi-periodic oscillation in radio light curve of the high redshift FSRQ PKS J0805–0111

In this work,we have searched for quasi-periodic oscillations(QPOs)in the 15 GHz light curve of the FSRQ PKS J0805-0111 monitored by the Owens Valley Radio Observatory(OVRO)40 m telescope during the period from 2008 January 9 to 2019 May 9,using the weighted wavelet Z-transform(WWZ)and the Lomb-Scargle Periodogram(LSP)techniques.This is the first time to search for a periodic radio signal in the FSRQ PKS J0805-0111 by these two methods.Both methods consistently reveal a repeating signal with a periodicity of 3.38±0.8 yr(>99.7%confidence level).In order to determine the significance of the periods,the false alarm probability method was applied,and a large number of Monte Carlo simulations were performed.As possible explanations,we discuss a number of scenarios including the thermal instability of thin disks scenario,the spiral jet scenario and the binary supermassive black hole scenario.We expect that the binary black hole scenario,where the QPO is caused by the precession of binary black holes,is the most likely explanation.FSRQ PKS J0805-0111 thus could be a good binary black hole candidate.In the binary black hole scenario,the distance between the primary black hole and the secondary black hole is about 1.71×10¹⁶ cm.     

山东省地震台网中心网站建设

主要介绍了山东省地震中心网站的页面栏目设计和页面具体内容,介绍了网站的具体功能,以及网站制作的技术与方法,通过访问该网站可以了解到山东省地震台网中心的各种信息,并且能够查询到山东省2002年以来大于2.0级的地震.     

Attribution of trends in meteorological drought during 1960–2016 over the Loess Plateau,China

This study uses two forms of the Palmer Drought Severity Index(PDSI), namely the PDSI_TH(potential evapotranspiration estimated-by the Thornthwaite equation) and the PDSI_PM(potential evapotranspiration estimated by the FAO Penman-Monteith equation), to characterize the meteorological drought trends during 1960–2016 in the Loess Plateau(LP) and its four subregions. By designing a series of numerical experiments, we mainly investigated various climatic factors' contributions to the drought trends at annual, summer, and autumn time scales. Overall, the drying trend in the PDSI_TH is much larger than that in the PDSI_PM. The former is more sensitive to air temperature than precipitation, while the latter is the most sensitive to precipitation among all meteorological factors. Increasing temperature results in a decreasing trend(drying) in the PDSI_TH, which is further aggravated by decreasing precipitation, jointly leading to a relatively severe drying trend. For the PDSI_PM that considers more comprehensive climatic factors, the drying trend is partly counteracted by the declining wind speed and solar radiation. Therefore, the PDSI_PM ultimately shows a much smaller drying trend in the past decades.     

宁阳县蒋集镇水库土坝非稳定性探析

宁阳县蒋集镇地处汶河南岸,黄淮分水岭北侧,最大海拔高程361m.全镇区域面积12．7万km^2,其中山区、丘陵占2／3,岩石类型以花岗片麻岩为主。20世纪50-60年代兴建了117座水库塘坝,其中小（一）型水库2座,小（二）型水库15座,塘坝100座,总库容1700余万m^2,坝体以土坝为主。由于当时施工机械落后,技术有限,经费不足,造成工程质量较低,因而不少土坝产生渗流、流土、管涌、滑坡等现象。     

西藏自治区昂仁县朱诺铜矿地质特征及找矿潜力远景评价

通过典型斑岩型铜矿模式对比,朱诺铜矿含矿斑岩体剥蚀程度为钾化带和黄铁绢英岩化上部,向深部及西部,具有较大的找矿潜力。     

Iron isotopic analyses of geological reference materials on MC-ICP-MS with instrumental mass bias corrected by three independent methods

Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and ⁵⁷Fe–⁵⁸Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ⁵⁶Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ⁵⁶Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ⁵⁷Fe?=?0.534?±?0.010, 2SE).