Seasonal variations in the speciation of dissolved iodine in the Chesapeake Bay

The speciation of dissolved iodine and the distributions of the iodine species in the deep Chesapeake Bay underwent seasonal variations in response to changes in the prevailing redox condition. In the deep water, the ratios of iodate to iodide and iodate to inorganic iodine decreased progressively from the Winter through the Summer as the deep water became more poorly oxygenated before they rebounded in the Fall when the deep water became re-oxygenated again. The composition of the surface water followed the same trend. However, in this case, the higher biological activities in the Spring and the Summer could also have enhanced the biologically mediated reduction of iodate to iodide by phytoplankton and contributed to the lower ratios found during those seasons. Superimposed on this redox cycle was a cycle of input and removal of dissolved iodine probably as a result of the interactions between the water column and the underlying sediments. Iodine was added to the Bay during the Summer when the deep water was more reducing and removed from the Bay in the Fall when the deep water became re-oxygenated. A third cycle was the inter-conversion between inorganic iodine and ‘dissolved organic iodine’, or ‘‘DOI’’. The conversion of inorganic iodine to ‘DOI’ was more prevalent in the Spring. As a result of these biogeochemical reactions in the Bay, during exchanges between the Bay and the North Atlantic, iodate-rich and ‘DOI’-poor water was imported into the Bay while iodide- and ‘DOI’-rich water was exported to the Atlantic. The export of iodide from these geochemically reactive systems along the land margins contributes to the enrichment of iodide in the surface open oceans.     

台湾海峡船舶交通管理系统（VTS）的研究

台湾海峡是南来北往的国内、国际海上运输主通道的重要组成部分,本文通过分析台湾海峡自然条件、船舶交通现状及发展、安全监督管理现状,提出建设台湾海峡船舶交通管理系统（ＶＴＳ）的必要性和迫切性。该系统的建设将改善海峡船舶通航条件,保障船舶航行安全,提高航运效益,保护水域环境,同时促进两岸海上直航的顺利发展。     

超声与振荡提取沉积物中松散结合态磷的比较

用超声技术提取沉积物样品中松散结合态磷,并与振荡提取结果进行比较。结果表明,超声提取结果与振荡提取结果大致相当。超声提取耗时短,操作简单易行,测试结果精密度为3.8%(RSD,n=7),可以替代振荡方法提取沉积物中的松散结合态磷。     

Pressure dependence of viscosity of rhyolitic melts

Viscosity of silicate melts is a critical property for understanding volcanic and igneous processes in the Earth. We investigate the pressure effect on the viscosity of rhyolitic melts using two methods: indirect viscosity inference from hydrous species reaction in melts using a piston cylinder at pressures up to 2.8 GPa and direct viscosity measurement by parallel-plate creep viscometer in an internally-heated pressure vessel at pressures up to 0.4 GPa. Comparison of viscosities of a rhyolitic melt with 0.8 wt% water at 0.4 GPa shows that both methods give consistent results. In the indirect method, viscosities of hydrous rhyolitic melts were inferred based on the kinetics of hydrous species reaction in the melt upon cooling (i.e., the equivalence of rheologically defined glass transition temperature and chemically defined apparent equilibrium temperature). The cooling experiments were carried out in a piston-cylinder apparatus using hydrous rhyolitic samples with 0.8-4 wt% water. Cooling rates of the kinetic experiments varied from 0.1 K/s to 100 K/s; hence the range of viscosity inferred from this method covers 3 orders of magnitude. The data from this method show that viscosity increases with increasing pressure from 1 GPa to 3 GPa for hydrous rhyolitic melts with water content ?0.8 wt% in the high viscosity range. We also measured viscosity of rhyolitic melt with 0.13 wt% water using the parallel-plate viscometer at pressures 0.2 and 0.4 GPa in an internally-heated pressure vessel. The data show that viscosity of rhyolitic melt with 0.13 wt% water decreases with increasing pressure. Combining our new data with literature data, we develop a viscosity model of rhyolitic melts as a function of temperature, pressure and water content.     

The effect of seafloor topography in the Southern Ocean on tabular iceberg drifting and grounding

Antarctic tabular icebergs are important active components in the ice sheet-ice shelf-ocean system. Seafloor topography is the key factor that affects the drifting and grounding of icebergs, but it has not been fully investigated. This study analyzes the impact of seafloor topography on the drifting and grounding of Antarctic tabular icebergs using Bedmap-2 datasets and iceberg route tracking data from Brigham Young University. The results highlight the following points. (1) The quantitative distributions of iceberg grounding events and the tracking points of grounded icebergs are mainly affected by iceberg draft and reach their peak values in sea water with depths between 200 m and 300 m. The peak tracking point number and linear velocity of free-drifting icebergs are found in the Antarctic Slope Front (water depth of approximately 500 m). (2) The area of possible grounding regions of small-scale icebergs calved from ice shelf fronts accounts for 28% of the sea area at water depths less than 2000 m outside the Antarctic coastline periphery (3.62 million km²). Their spatial distribution is mainly around East Antarctica and the Antarctic Peninsula. The area of possible grounding regions of large tabular icebergs with long axes larger than 18.5 km (in water depths of less than 800 m) accounts for 74% of the sea area. (3) The iceberg drifting velocity is positively correlated with ocean depth in areas where the depth is less than 2000 m (R=0.85, P<0.01). This result confirms the effect of water depth variations induced by seafloor topography fluctuations on iceberg drifting velocity.     

Measuring global energy-related sulfur oxides emissions embodied in trade: a multi-regional and multi-sectoral analysis

Sulfur oxides (SO_X) emissions embodied in trade (SEET) may play an important role in affecting national responsibilities toward pollutant emission reduction within the context of global greenhouse gas emission policy. This paper analyzes the change of the SEET associated with energy consumption from the perspective of a country and a sector between 1995 and 2011, exploring the evolution characteristic of the sources and flows of the SEET for 39 countries, as well as measuring the production-based and consumption-based global SO_X emissions’ inventory and investigating the impact of international trade on the allocation of national pollutant emissions’ reduction obligations. One important finding is that the volume of SO_X emissions embodied in global trade increased dramatically from 1995 to 2011, and the global SO_X emissions stemming from anthropogenic energy consumption are mostly from China and the USA. Another important finding is that, referring to specific sectors, whether seen from the total SEET or from the sources of SEET or from the total SO_X emissions occurring from economic consumption and production, energy sectors, like electricity, gas, and water supply and coke, refined petroleum, and nuclear fuel, are the main contributors to the increase in the global SO_X emissions. Notably, however, our results show that the sector of agriculture, hunting, forestry, and fishing should be allocated more SO_X emission reduction responsibilities under a consumption-based emissions’ accounting inventory.

     

Microbial D-amino acids and marine carbon storage

In nature, there are two conformational types of amino acids: L- and D-isomers. The L-amino acids are the predominant form and are used mainly for protein synthesis, while the D-amino acids are few in quantity but more diverse in terms of their biological functions. D-amino acids are produced by many marine microbes, which are important players in carbon and energy cycles in the ocean. As the major constituent of the marine organic carbon pool, D-amino acids can persist in the water column for a long time before being further transformed by chemical or biological processes or transported through physical processes (such as absorption and aggregation). This article reviews the microbial synthesis of D-amino acids, their physiological function and metabolism in microbes, and the contribution of D-amino acids as a carbon source to the oceanic carbon reservoir.     

依法保护矿权提高煤炭资源保障程度

分析了福建省的煤炭资源概况、地勘工作的干扰因素、产生的危害性及其产生的主要原因,论证了提高煤炭资源保障程度的重要性和必要性,并就如何依法保护矿权,提高煤炭资源保障程度方面,作了积极有益的探索.     

Numerical simulations of transport of non-ergodic solute plumes in heterogeneous aquifers

Transport of non-ergodic solute plumes by steady-state groundwater flow with a uniform mean velocity, μ, were simulated with Monte Carlo approach in a two-dimensional heterogeneous and statistically isotropic aquifer whose transmissivity, T, is log-normally distributed with an exponential covariance. The ensemble averages of the second spatial moments of the plume about its center of mass, <S _{i i} (t)>, and the plume centroid covariance, R _{i i} (t) (i=1,2), were simulated for the variance of Y=log T, σ _Y ²=0.1, 0.5 and 1.0 and line sources normal or parallel to μ of three dimensionless lengths, 1, 5, and 10. For σ _Y ²=0.1, all simulated <S _{i i} (t)>−S _{i i} (0) and R _{i i} (t) agree well with the first-order theoretical values, where S _{i i} (0) are the initial values of S _{i i} (t). For σ _Y ²=0.5 and 1.0 and the line sources normal to μ, the simulated longitudinal moments, <S ₁₁(t)>−S ₁₁(0) and R ₁₁(t), agree well with the first-order theoretical results but the simulated transverse moments <S ₂₂(t)>−S ₂₂(0) and R ₂₂(t) are significantly larger than the first-order values. For the same two larger values of σ _Y ² but the line sources parallel to μ, the simulated <S ₁₁(t)>−S ₁₁(0) are larger than but the simulated R ₁₁ are smaller than the first-order values, and both simulated <S ₂₂(t)>−S ₂₂(0) and R ₂₂(t) stay larger than the first-order values. For a fixed value of σ _Y ², the summations of <S _{i i} (t)>−S _{i i} (0) and R _{i i} , i.e., X _{i i} (i=1,2), remain almost the same no matter what kind of source simulated. The simulated X ₁₁ are in good agreement with the first-order theory but the simulated X ₂₂ are significantly larger than the first-order values. The simulated X ₂₂, however, are in excellent agreement with a previous modeling result and both of them are very close to the values derived using Corrsin's conjecture. It is found that the transverse moments may be significantly underestimated if less accurate hydraulic head solutions are used and that the decreasing of <S ₂₂(t)>−S ₂₂(0) with time or a negative effective dispersivity, defined as , may happen in the case of a line source parallel to μ where σ _Y ² is small.